一种新型4自由度高速并联机械手动力尺度综合

研究一种可实现SCARA运动的新型4自由度高速并联机械手动力尺度综合方法。简要阐述该机构中由可变菱形动平台和齿轮增速机构生成绕z轴转动的传动原理。在建立运动学和刚体动力学模型基础上,利用直接和间接雅可比代数特征构造出两类可用于描述运动/力在链内和链间传递能力的压力角,并提出一种基于单轴最大驱动力矩全域最大值最小的动力学性能评价指标。在满足工作空间与机构尺度比、可装配条件等几何约束和运动学性能约束下,综合出一组可使得系统刚体动力学性能全域最优的尺度参数,并利用Adept拓展轨迹预估出电动机参数。     

硅质岩钒矿中提取钒的无污染焙烧工艺研究

采用氧化焙烧法研究了无污染的焙烧添加剂碳酸钠、氧化钙、红泥和苛化泥从硅质岩钒矿中提取钒的焙烧工艺。考察了焙烧温度、焙烧时间、添加剂用量、入炉温度、焙烧气氛对钒浸出率的影响。实验表明，硅质岩钒矿适宜的添加剂为苛化泥，当苛化泥添加量为6％、入炉温度低于200℃、焙烧温度为850℃、通空气焙烧3h时，钒的浸出率达70．53％。与传统的钠化焙烧相比，采用苛化泥焙烧添加剂既解决了废气污染问题，又能综合利用资源，具有成本低、污染少等优点。     

苏州市枫桥工业园区非点源污染特性研究

对苏州市枫桥工业园区湘江路段的14场有效降雨事件径流污染特性进行了研究.结果表明,该工业区降雨径流水质较差,COD、SS、NH3-N、TN和TP的事件平均浓度(EMC)中值分别达到了119、188、2.30、6.35、0.80 mg/L,超过了<地表水环境质量标准>(GB 3838--2002)的V类水体标准;COD、SS、NH3-N、TN和TP的污染负荷分别为846、1 337、16、45、6 kg/(hm2·a),是国外工业用地的2～7倍,与我国其他类型用地相比,SS负荷高是其主要特点;该工业区雨水径流的初期效应不明显,且主要污染物指标之间具有较好的相关性,可通过减少SS污染源来削减其他污染负荷.     

Recyclable Carbon Supported Copper‐Manganese Oxide for Selective Aerobic Oxidation of Alcohols in Combination with 2,2,6,6‐Tetramethylpiperidyl‐1‐oxyl under Neutral Condition

Due to the promotion of the surface area and the dispersion of active components upon supporting mixed metal oxides on the porous material active carbon, the copper‐manganese oxide on carbon system has been proven to be much more efficient than the co‐precipitation prepared Cu‐Mn oxide in mediating the 2,2,6,6‐tetramethylpiperidyl‐1‐oxyl (TEMPO)‐catalyzed aerobic oxidation of alcohols. Even at 30 °C and with a 0.1 mol% load of TEMPO, the oxidations proceeded smoothly. Upon catalysis with the Cu‐Mn oxide/C (10 wt%) and TEMPO (0.5–5 mol%), various alcohols were oxidized selectively to the corresponding aldehydes or ketones with molecular oxygen at 80 °C. Such a stable, recyclable heterogeneous cocatalyst permits alcohols to be oxidized under neutral and mild conditions.     

Niobium doped lithium titanate as a high rate anode material for Li-ion batteries

Niobium doped lithium titanate with the composition of Li₄Ti_4.95Nb_0.05O₁₂ has been prepared by a sol-gel method. X-ray diffraction (XRD) and scanning electron microscope (SEM) are employed to characterize the structure and morphology of Li₄Ti_4.95Nb_0.05O₁₂. The Li₄Ti_4.95Nb_0.05O₁₂ electrode presents a higher specific capacity and better cycling performance than the Li₄Ti₅O₁₂ electrode prepared by the similar process. The Li₄Ti_4.95Nb_0.05O₁₂ exhibits an excellent rate capability with a reversible capacity of 135 mAh g⁻¹ at 10 C, 127 mAh g⁻¹ at 20 C and even 80 mAh g⁻¹ at 40 C. Electrical resistance measurement and electrochemical impedance spectra (EIS) reveal that the Li₄Ti_4.95Nb_0.05O₁₂ exhibits a higher electronic conductivity and faster lithium-ion diffusivity than the Li₄Ti₅O₁₂, which indicates that niobium doped lithium titanate (Li₄Ti_4.95Nb_0.05O₁₂) is promising as a high rate anode for the lithium-ion batteries.     

自由场地液化响应特性的离心机振动台试验

利用ZJU-400土工离心机振动台,对相对密度为40%的福建中细砂自由场地模型,进行5次动态加载的液化试验.分析试验中土的动力特性和地震动特性,得到土体不同深度范围内加速度、超静孔隙水压力随时间的发展规律,以及土体加速度、沉降与超静孔隙水压力增长之间的关系,增强了对地震过程中土体加速度、沉降与孔隙水之间相互作用的理解.结果表明：场地放大作用受超静孔隙水压力增长和土体软化的共同作用,液化破坏了土颗粒的联结强度和结构稳定性,再次沉积形成的结构不稳定易再次液化|峰值过后切应力对超静孔隙水压力增长仍起到不可忽视的作用;土体超静孔隙水压力增长和土体沉降是外荷由土颗粒到孔隙水再到土颗粒传递的结果|液化后固结完成,场地土体自振频率增加;基于剪切波速确定CRR曲线的方法是合理的.     

基于Pro／E＋VC＋ADO＋Access的角钢参数化设计

以VC＋＋6.0为开发工具, Access 2003为数据库管理系统,采用ADO数据库访问技术,在Pro/E环境下实现了采用ADO接口技术访问Access ,以等边角钢参数化设计为例,介绍了其实现过程。     

AP1000稳压器波动管竖直管段空气-水CCFL实验研究

使用竖直管代替波动管模型开展稳压器波动管竖直管段内空气-水两相逆流限制(CCFL)特性可视化实验研究。实验现象表明:竖直管与上容器接口处的局部CCFL决定了进入竖直管内的液相流量;竖直管内的局部CCFL决定了从竖直管流出的液相流量;两处局部CCFL均随空气流量的增大而增强。在较低气量情况,进入竖直管内的液相能够完全或大部分流出,竖直管内的局部CCFL较弱,上容器和竖直管接口处的局部CCFL在整体CCFL中占主导地位,整体CCFL程度随着上容器液位升高而略有增强。在高气量情况,从上容器进入竖直管的液相大部分或者完全被限制而不能向下流出,竖直管内的局部CCFL强烈,在整体CCFL中占主导地位,整体CCFL特性不受上容器液位变化的影响。通过实验数据拟合得到了新的稳压器竖直管CCFL模型。稳压器波动管CCFL数据和稳压器竖直管CCFL数据基本重合,表明波动管CCFL主要由CCFL-U决定。     

海水铝-空气燃料电池

叙述了海水－铝空气燃料电池的特性及影响电池功率输出的主要因素，如海水的电导、盐度、温度、铝材料的选择等。试验结果表明，电池工作时正负极之间的液相电阻比海水本身的电阻小得多，但是其液相电阻仍然偏大。海水盐度和温度的变化引起电极电势波动，盐度影响占１０％左右。高纯铝合金电极工作电势比工业铝合金电极的工作电势高２００ｍＶ以上。     

Effect of different pressure-soaking treatments on color,texture, morphology and retrogradation properties of cooked rice

The hydration of rice grain and the quality of cooked rice with the different pressure soaking treatments were estimated using Chroma meter (CM), Texture Profile Analysis (TPA), Scanning electron microscopy (SEM), and Differential Scanning Calorimetry (DSC). The results showed that the vacuum soaking and the high hydrostatic pressure (HHP) soaking increased the hydration degree of normal rice, while the hydration effect in waxy rice was increased only by the HHP treatment. The lightness (L*) and the color intensity (B) of cooked normal rice and waxy rice were significantly improved by the two treatments. The HHP soaking also generated the lower hardness, while the higher springiness and cohesiveness for cooked normal and waxy rice samples. These highlights were mainly attributed to the less amylose leaching and the smaller network channels formed between starch granules and other connection parts. Furthermore, the retrogradation of cooked normal and waxy rice was reduced by the HHP treatment. These findings suggest that the HHP soaking could be used for producing high-quality of cooked rice.