Influence of ring-type internals on the solids residence time distribution in the fuel reactor of a dual circulating fluidized bed system for chemical looping combustion

The intensification of gas-solids contact in the fuel reactor of a chemical looping combustion system is enhanced with the installation of ring-type internals. This can be a key issue for achieving the necessary fuel conversion rates. Wedged rings, previously designed and tested, were found to increase the particle concentration in the counter current section of the fuel reactor and hence, to achieve a more homogeneous particles concentration along this zone. The present work investigates the effect of the mentioned internals on the residence time distribution of particles in the fuel reactor of a dual circulating fluidized bed system for chemical looping. The study was carried out in a cold flow model especially designed for the fluid-dynamic analysis of the system equipped with a recently developed residence time measurement device based on the detection of ferromagnetic tracer particles through inductance measurement. Ring internals proved the positive effect on the particles residence time, the residence time distribution is more symmetric and shows lower dispersion, the flow pattern is more plug-flow-like, these effects are intensified with the reduction of the aperture ratio of the rings. On the other hand, the upward particle transport in the counter-current zone of the fuel reactor also increases with the installation of the rings, increasing the bypass flow of solids through the fuel reactor's return loop (internal circulation). For high internal circulation rates the solids residence time distribution of the fuel reactor is dominated by the bypass effect. The findings may be used for focused design improvement of the investigated fluidized bed system.     

Carrot cropping on organic soil is a hotspot for nitrous oxide emissions

The emissions of the greenhouse gas nitrous oxide (N₂O) were measured from a non nitrogen fertilized carrot (Daucus carota ssp. sativa) field on an organic soil in Sweden during one cropping and post-harvest season. The cumulative emission during the measuring period of 149?days was 41 (±2.8) kg N₂O ha^?1. Dividing the measuring period into a cropping and a post-harvest period revealed that the presence of carrots strongly stimulated N₂O emissions, as the emission during the cropping period was one order of magnitude higher compared to the post-harvest period. The N₂O emission from the carrot field were higher than fluxes reported from cereal crop and grass production, but in the same order as reported fluxes from vegetable cropping on organic soils. In conclusion, our results indicate that the cultivation of root vegetable, such as carrots, on organic soil can be a high point source for N₂O emissions.     

Managing incidents in a complex system: a railway case study

The authors of this paper review how complex entities, composed of many interdependent subsystems, such as international rail operators, can improve their ability to recover from incidents through the better management of key interfaces. The principles of Normal Accident Theory and resilience engineering are discussed, and the case study of the Eurostar incident of 18–19 December 2009 is considered in detail. Lessons learnt from resilience engineering are applied to the case study to extract recommendations by which incident management for open access international rail transport may be improved.     

Structure and motion in urban environments using upright panoramas

Image-based modeling of urban environments is a key component of enabling outdoor, vision-based augmented reality applications. The images used for modeling may come from off-line efforts, or online user contributions. Panoramas have been used extensively in mapping cities and can be captured quickly by an end-user with a mobile phone. In this paper, we describe and evaluate a reconstruction pipeline for upright panoramas taken in an urban environment. We first describe how panoramas can be aligned to a common vertical orientation using vertical vanishing point detection, which we show to be robust for a range of inputs. The orientation sensors in modern cameras can also be used to correct the vertical orientation. Secondly, we introduce a pose estimation algorithm, which uses knowledge of a common vertical orientation as a simplifying constraint. This procedure is shown to reduce pose estimation error in comparison with the state of the art. Finally, we evaluate our reconstruction pipeline with several real-world examples.     

Hybridization Networks of mRNA and Branched RNA Hybrids

Messenger RNA (mRNA) is emerging as an attractive biopolymer for therapy and vaccination. To become suitable for vaccination, mRNA is usually converted to a biomaterial, using cationic peptides, polymers or lipids. An alternative form of converting mRNA into a material is demonstrated that uses branched oligoribonucleotide hybrids with the ability to hybridize with one or more regions of the mRNA sequence. Two such hybrids with hexamer arms and adamantane tetraol as branching element were prepared by solution-phase synthesis. When a rabies mRNA was treated with the branched hybrids at 1 M NaCl concentration, biomaterials formed that contained both of the nucleic acids. These results show that branched oligoribonucleotides are an alternative to the often toxic reagents commonly used to formulate mRNA for medical applications.