Retention of SO2 Emission of Coal Combustion by Using Lime in Briquetting

In this study, the effect of lime on control of SO₂ emissions was investigated by briquetting of coal particles with various lime contents. The influence of the added lime was determined not only from the view of its contribution to environmental aspects but also in terms of effects on the thermal features and reaction kinetics of coal. The extent of improvement was determined by detailed sulfur analysis. Thermal qualification and reaction kinetics of the coal briquettes with varying lime contents were performed by evolved gas analysis and its complementing kinetic model based on Arrhenius principles. At the end of experiments, utilization of lime was seen to contribute considerably to desulfurization process. However, lime addition had an adverse effect both on the effectiveness of combustion and the liability of the coal briquettes to oxidize.     

Obtaining Butter Oil Triacylglycerols Free from β-Carotene and α-Tocopherol via Activated Carbon Adsorption and Alumina-Column Chromatography Treatments

It is difficult to remove β-carotene from oils with alumina-column chromatography, because β-carotene is even less-polar than triacylglycerols (TAGs) are. The objective of this study was to obtain butter oil TAGs free from β-carotene and antioxidants via sequential treatments with activated carbon (AC) adsorption and alumina column chromatography. The AC used was prepared from waste apricots. The effects of AC dosages, temperatures and time courses on β-carotene adsorption were studied. The Langmuir and Freundlich isotherms were used to describe the adsorption of β-carotene onto AC, and it was found to be more consistent with the Freundlich isotherm with a higher R ² value (0.9784). Adsorption kinetics of β-carotene was analyzed by pseudo-first order and pseudo-second order models. The pseudo-second order model was found to explain the kinetics of β-carotene adsorption more effectively (R ² = 0.9882). The highest β-carotene reduction was achieved (from 31.9 to 1.84 mg/kg) at an AC dosage of 10 wt%, temperature of 50 °C, and adsorption time of 240 min. A considerable amount of α-tocopherol was also adsorbed during the AC treatment. Remaining portions of α-tocopherol were completely removed with alumina adsorption chromatography. The method described may be used for purification of vegetable oil TAGs, which will be used as model compounds in model oxidation studies.     

Evaluating the Impact of Daily Net Radiation Models on Grass and Alfalfa-Reference Evapotranspiration Using the Penman-Monteith Equation in a Subhumid and Semiarid Climate

Net radiation (Rn) is the main driving force of evapotranspiration (ET) and is a key input variable to the Penman-type combination and energy balance equations. However, Rn is not commonly measured. This paper analyzes the impact of 19 net radiation models that differ in model structure and intricacy on estimated grass and alfalfa-reference ET (ETo and ETr, respectively) and investigates how climate, season and cloud cover influence the impact of the Rn models on ETo and ETr. Datasets from two locations (Clay Center, Nebraska, subhumid; and Davis, California, a Mediterranean-type semiarid climate) were used. Rn values computed from the 19 models were used in the standardized ASCE-EWRI Penman-Monteith equation to estimate ETo and ETr on a daily time step. The influence of seasons on the estimation of Rn and on estimated ETo and ETr was investigated in winter (November–March) and summer (May–September) months. To analyze the influence of clouds on the impact of Rn models, relative shortwave radiation (Rrs) was used as a means to express the cloudiness of the days as: 0 ≤ Rrs ≤ 0.35 for completely cloudy days; 0.35相似文献   

Scaled 3-D model studies of immiscible CO2 flooding using horizontal wells

In this study, a comprehensive laboratory investigation was conducted for the recovery of heavy oil from a scaled three-dimensional (3-D) physical model, packed with 18° API gravity crude oil, brine and crushed limestone. A total of 20 experiments were conducted using the scaled 3-D physical model with 30×30×6 cm³ dimensions. Basically, four different immiscible CO₂–water displacement processes were used for recovering heavy oil: (i) continuous CO₂ injection, (ii) waterflooding, (iii) simultaneous injection of CO₂ and water, and (iv) water alternating gas (WAG) process. Three groups of well configurations were mainly used: (1) vertical injection and vertical production wells, (2) vertical injection and horizontal production wells, and (3) horizontal injection and horizontal production wells. Base experiments were run with water only and carbon dioxide alone and optimum rates for WAG and simultaneous water–CO₂ injection were determined. In continuous CO₂ injection, highest recovery was obtained by vertical injection–horizontal production (VI–HP), followed by vertical injection–vertical production (VI–VP) and the least by horizontal injection–horizontal production (HI–HP). In VI–HP configuration, the best recovery was obtained as 15.1% OOIP. Higher oil recovery was obtained with a VI–HP wells than with a pair of vertical wells and horizontal wells. The WAG 1:5 ratio yielded a final recovery of 34.5% OOIP with VI–VP well configuration and 17.0% OOIP of additional recovery over waterflooding. In turn, the WAG 1:10 ratio was the best with a final recovery of 20.9% of OOIP with VI–HP well configuration. Oil production from WAG injection is higher than that obtained from the injection of continuous CO₂ or waterflooding alone.     

Synthesis and properties of fluoro‐polyetherimides

A series of amorphous fluoro‐polyetherimides based on 2,2′‐bis(3,4‐dicarboxyphenyl) hexafluropropane dianhydride (6FDA) and di‐ether‐containing diamines 4,4′‐bis(3‐aminophenoxy)diphenyl sulfone (m‐SED), 4,4′‐bis(4‐aminophenoxy)diphenyl sulfone (p‐SED), 4,4′‐bis(4‐aminophenoxy)diphenyl propane (BPADE) were synthesized. These melt processable polyetherimide polymers from p‐SED and BPADE showed excellent electrical properties. The dielectric constants, 2.74 and 2.65 at 10 MHz respectively, are lower than commercially available polyetherimide ULTEM® 1000, and polyimide Kapton® H films. In addition, we found that trifluoromethyl groups‐containing polyimides not only show extraordinary electrical properties, but they also exhibit excellent long‐term thermo‐oxidative stability and reduced water absorption relative to non‐fluorinated polyimides. The weight retention of these fluoro‐polyetherimides at 315°C for 300 h in air varies from 93% to 98%. Whereas, their moisture absorption at 100 RH at 50°C was in the range of 0.3% to 1.05%, which is much lower than those of Ultem 1000 and Kapton H. In the case of fluoro‐polyetherimides from p‐SED and m‐SED (para and meta isomers) diamines with ‘ether’ and sulfonyl (‐SO₂‐) spacer groups, the d‐spacing and T_g values decreased from 4.72Å to 4.56Å and 293°C to 244°C respectively. Similarly, the transparency of these polymer films (in the range of 80% to 90%) at 500 nm solar wavelength was higher than Ultem 1000 and Kapton H.     

Computer aided frequency planning for the radio and TV broadcasts

The frequency planning of the VHF and UHF broadcasts in Turkey is described. This planning is done with the aid of computer databases and digital terrain map. The frequency offset is applied whenever applicable to increase the channel capacity. The offset assignment is done through simulated annealing algorithm. The international rules and regulations concerning Turkey are also considered     

A systematic approach to integral snap-fit attachment design

Traditional integral snap-fit attachment design focuses almost exclusively on the individual locking features, such as cantilever hooks, bayonet-fingers, compressive hooks and others. The positioning and orientation of other significant features on parts, such as those that facilitate or enhance engagement and eliminate unwanted degrees of freedom left by locking features, i.e. locating features and enhancements, are not considered. This paper builds on relatively new methodologies and guidelines for arranging all attachment features on plastic parts comprising snap-fit assembly. Classification of features into categories of locking features, locating features and enhancements of these is used as the basis for discussion. A systematic approach to attachment design is presented.