Removal of lead (II) and nickel (II) ions from aqueous solution using activated carbon prepared from rapeseed oil cake by Na<Subscript>2</Subscript>CO<Subscript>3</Subscript> activation

In this study, rapeseed oil cake as a precursor was used to prepare activated carbons by chemical activation with sodium carbonate (Na₂CO₃) at 600 and 800 °C. The activated carbon with the highest surface area of 850 m² g^?1 was produced at 800 °C. The prepared activated carbons were mainly microporous. The activated carbon having the highest surface area was used as an adsorbent for the removal of lead (II) and nickel (II) ions from aqueous solutions. The effects of pH, contact time, and initial ion concentration on the adsorption capacity of the activated carbon were investigated. The kinetic data of adsorption process were studied using pseudo-first-order, pseudo-second-order kinetic models and intraparticle diffusion model. The experimental data were well adapted to the pseudo-second-order model for both tested ions. The adsorption data for both ions were well correlated with Langmuir isotherm. The maximum monolayer adsorption capacities of the activated carbon for the removal of lead (II) and nickel (II) ions were determined as 129.87 and 133.33 mg g^?1, respectively.     

基于相控外差干涉技术的纳米定位方法的研究

针对工业领域和计量界对定位精度要求的提高,提出了一种基于迈克尔逊干涉仪反向特性的定位控制方法。该方法采用相位锁定控制和外差干涉技术来完成位置测量和控制。在严格控制实验环境条件下,得到了步距值为5 nm的双向步进位移。步距值的不确定度为8×10-9 nm,位移重复性误差小于1 nm。该定位方法的测量尺寸可直接溯源至长度标准,并且采用光电步进相移法可克服压电陶瓷的非线性和蠕变的机械缺陷。该方法在系统环境控制条件下适用于毫米行程位移,可应用于纳米计量和超精密加工等领域。     

Dynamics of Nocturnal, Daytime, and Sum-of-Hourly Evapotranspiration and Other Surface Energy Fluxes over Nonstressed Maize Canopy

The magnitude and driving forces of nocturnal evaporative losses, ETcnight, and the interactions of other surface energy fluxes and microclimatic variables under various climatic, soil, and management conditions are not well understood. Such relationships are important for ecophysiological studies. This research attempts to investigate such relationships. Furthermore, ETcnight can be a sizable portion of the daily total evaporative losses. Most empirical equations, especially ones that use solar or net radiation to estimate daily evapotranspiration (ET), either ignore or poorly treat the contribution of ETcnight to the daily total ET. Neglecting ETcnight can lead to errors in determining the daily or the sum-of-hourly ETc (i.e., ETcSOH) and can also cause cumulative errors when making long-term water balance analyses. In this paper, the magnitudes, trends, and contribution to the nocturnal surface energy balance of various microclimatic variables (air temperature, Ta; vapor pressure deficit, VPD; relative humidity, RH; and wind speed at 3?m, u3) and surface energy fluxes (ETcnight; soil heat flux, G; sensible heat flux, H; and net radiation, Rn); were quantified and interpreted for a nonstressed and subsurface-drip-irrigated maize canopy. The effect of microclimatic variables and surface energy flux components on the Bowen ratio energy balance system (BREBS)-measured ETcnight and daytime evaporative loss, ETcday, were investigated in the growing season of 2005 (i.e., April 22–September 30) and 2006 (May 12–September 27). The nighttime evaporative losses were high early in the season during partial canopy closure because of increased surface soil evaporation and were also high later in the season during and after leaf aging, physiological maturity, and leaf senescence. The seasonal average nighttime evaporative losses for 2005 and 2006 were 0.19 and 0.11??mm/night, respectively. Losses of 0.50?mm or more occurred in 2005 and 2006 on eight and seven nights, respectively. The seasonal total ETcnight, ETcday, and ETcSOH in 2005 were 31, 612, and 642?mm, respectively. The ETc values in 2006 were 16, 533, and 547?mm, respectively. In both years, the percent ratio of ETcday to ETcSOH usually was more than 80–85%. ETcnight was affected primarily by u3, VPD, and Ta. A strong relationship between ETcnight and nighttime sensible heat was observed. Some of the largest ratios of ETcnight to ETcSOH occurred on rainy nights with strong winds. Because of strong winds, the ETcnight was high owing to the clear coupling among all energy exchanges within and above the canopy as a result of the mixing of the lower boundary layer of the microclimate. The results of this study showed that the ETcnight can be up to 5% of the ETcSOH, even for a subsurface-drip-irrigated maize canopy in which the soil surface is usually dry, thus, less evaporative losses potential compared with the surface or sprinkler-irrigated surfaces in which ETcnight would be expected to be considerably higher because of wetter surface conditions. ETcnight needs to be quantified for different vegetation surfaces and management practices, surface wetting, and climatic conditions to better account for nighttime water losses and better understand nighttime energy balance mechanisms.     

The effect of aging treatments on wear behavior of aluminum matrix functionally graded material under wet and dry sliding conditions

This study investigated that the effect of aging treatments on wear behavior of functionally graded material (FGM) that was reinforced via being integrated with aluminum 2014 alloy (AlCu4SiMg) and 15 vol% SiC. The specimens were obtained via centrifugal casting technique, and then two different aging treatments were applied. Wear experiments were applied at 1.256 m/s constant sliding velocity, under two different loads and two different sliding distances for each condition via a pin‐on‐disc wear apparatus. The variations that occurred on wear behavior of cast and aged materials were analyzed. The results show that the minimum wear loss values were obtained under dry sliding conditions due to the aging processes. On the other hand, with increasing sliding distances under wet sliding conditions, the aging processes' effect was decreased on wear resistance.     

On the mixed sensitivity minimization for systems with infinitely many unstable modes

In this note we consider a class of linear time invariant systems with infinitely many unstable modes. By using the parameterization of all stabilizing controllers and a data transformation, we show that controllers for such systems can be computed using the techniques developed earlier for infinite dimensional plants with finitely many unstable modes.     

Supramolecular assembled C60-containing carboxylated poly(dimethylsiloxane) composites

Supramolecular assembled nanocomposites were prepared through the solution casting of the complexing mixtures from the side chain carboxylated poly(dimethylsiloxane) (PDMS) with the 1-(4-methyl)-piperazinylfullerene (MPF). FT-IR and XPS analyses reveal that there are strong ionic interactions between the two components. Small-angle X-ray scattering study shows the formation of MPF fullerene nanodomains dispersed in the PDMS matrix, but no highly ordered structures, which is confirmed with TEM images. Compared to its polymeric precursor, the MPF crosslinked composites exhibit superior thermal mechanical stability and dramatic increase in the storage and loss moduli. Moreover, elastic response exceeds viscous response in the composites due to the formation of crosslinking structures. The increase of the MPF content in the composites leads to a denser packing of MPF nanodomains, resulting in better thermal, mechanical, and viscoelastic properties. The decrease in the carboxylic acid groups along the PDMS chains reduces the crosslinking density of the PDMS/MPF composites. The composites show a combined dielectric property from both PDMS and MPF components.     

Structure-property relationship in polyethylene reinforced by polyethylene-grafted multi-walled carbon nanotubes

Polyethylene-grafted multiwalled carbon nanotubes (PE-g-MWNT) were used to reinforce polyethylene (PE). The nanocomposites possessed not only improved stiffness and strength, but also increased ductility and toughness. The effects on the structure and morphology of composites due to pristine multiwalled carbon nanotubes (MWNT) and PE-g-MWNT were studied and compared using small angle X-ray scattering (SAXS), wide angle X-ray diffraction (WAXD) and differential scanning calorimetry (DSC). The SAXS long period, crystalline layer thickness and crystallinity of polymer lamellar stacks were found to decrease significantly in MWNT composites, while the decreases were much smaller in PE-g-MWNT composites. PE-g-MWNT allowed a more efficient and unhindered crystallization at a lamellar level, while MWNT disrupted the order of lamellar stacks, probably because of their tendency to aggregate. The SAXS crystallinity and the mechanical properties of the composites showed similar trends as a function of MWNT content. This suggested that the improvement of the interfacial strength between polymer and carbon nanotubes was a result of synergistic effects of better dispersion of the filler, better stress transfer, due to the grafting of polymer and MWNT, and the nucleation of a crystalline phase around MWNT. The latter effect was confirmed by measurements of kinetics of non-isothermal crystallization.     

Life cycle assessment of power generation alternatives for a stand-alone mobile house

This paper presents comparative life cycle assessment of nine different hybrid power generation solutions that meet the energy demand of a prototypical mobile home. In these nine solutions, photovoltaic panels and a wind turbine are used as the main energy source. Fuel cell and diesel generator are utilized as backup systems. Batteries, compressed H₂, and H₂ in metal hydrides are employed as backup energy storage. The findings of the study shows that renewable energy sources, although they are carbon-free, are not as environmentally friendly as may generally be thought. The comparative findings of this study indicate that a hybrid system with a wind turbine as a main power source and a diesel engine as backup power system is the most environmentally sound solution among the alternatives.     

Electrochemical hydrogen storage characteristics of Mg1.5Al0.5−xZrxNi (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) alloys synthesized by mechanical alloying

Mg_1.5Al_0.5−xZr_xNi (x = 0, 0.1, 0.2, 0.3, 0.4, 0.5) type alloys were synthesized by mechanical alloying and their electrochemical hydrogen storage characteristics were investigated. X-ray diffraction studies showed that Zr facilitated the amorphization of Mg₂Ni phase, while Al retarded the amorphization of this phase. The increase in the Zr content was observed to bring about significant improvement in the discharge capacities at all the ball milling durations. The stepwise replacement of Al with Zr, however, caused considerable reduction in the initial discharge capacities of the alloys. Despite the adverse effect of Al on the initial discharge capacity, it prevented the rapid degradation of Mg₂Ni phase with the charge/discharge cycles. When the beneficial effects of Zr and Al were combined by designing Mg_1.5Al_0.5−xZr_xNi type alloys, Mg_1.5Al_0.2Zr_0.3Ni alloy was found to have the highest discharge capacity at almost all the charge/discharge cycle steps. Among the obtained capacity retaining rates, Mg_1.5Al_0.4Zr_0.1Ni alloy had the best performance. This alloy has kept at least 50% of its initial discharge capacity at 20th cycle. The analysis by the electrochemical impedance spectroscopy revealed that the charge transfer resistances of Al-rich alloys were low at high depth of discharges. This observation was attributed to the formation of the porous unstable Mg(OH)₂ layer due to the intercalation of Al₂O₃ layers, which have the high rate of solubility in strongly basic solutions, and thus the exposition of the underlying electrocatalytically active Ni sites.