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101.
Hao Yao Shigehito Isobe Yongming Wang Naoyuki Hashimoto Somei Ohnuki 《International Journal of Hydrogen Energy》2013
The thermal decomposition process of lithium alanate (LiAlH4) was investigated by TEM, TG-DTA and XRD. It was shown that LiAlH4 decomposes through a two-step reaction: a liquid-to-solid phase transition in the first step of the decomposition and a solid-to-solid reaction in the second step of the decomposition, both steps accompanied by hydrogen release. The particle size of the aluminum (Al), which formed in the first decomposition step, was much larger than that in the second decomposition step. In addition, Al particles formed in the liquid phase of LiAlH4 in the first decomposition step, while, they form in solid phase of Li3AlH6 in the second decomposition step, resulting in the kinetics of the first decomposition step being faster than that of the second decomposition step. The investigation clearly demonstrated the reaction model of the decomposition of LiAlH4 in the nano-scale, showing different diffusion processes of Al in each of the decomposition steps. 相似文献
102.
In phosphoric acid fuel cell (PAFC) stack, reduction of the phosphoric acid that is impregnated in the cell is a major factor to restrict the operating life. In this paper, the phosphoric acid reduction by the evaporative and condensational dissipation was evaluated by numerical analysis. The calculations that include the behavior of heat transfer, gas flow, and evaporation and condensation of phosphoric acid were conducted for the model cell with conditions that correspond to an on site stack. The phosphoric acid was considered as a composite of phosphorus pentoxide and water, and the evaporation and condensation rates were derived based on the nucleation theory for a two components system. The phosphoric acid distributions in the vapor phase and liquid phase at the process gas and electrode were calculated for the duration of 3300 h, and as a result of those, the exhausting and remaining amount of phosphoric acid for the cell were evaluated. The analysis results were compared with the experimental results for the model cell. 相似文献
103.
104.
Linhua Liu Toshihiro Isobe Kiyoshi Okada Akira Nakajima 《Materials Research Bulletin》2011,46(2):175-184
The respective influences of calcination, drying methods, and washing conditions on the morphologies, surface properties, and photocatalytic activities of TiO2 powders prepared from acid treatments of BaTiO3 were investigated. Rutile powder was obtained using the treatment under strong acid conditions. It possesses a bundle-like shape and comprises rutile nanorods. After calcination, characteristic voids were observed in the particles. Anatase powder was obtained by adjusting pH values of a BaTiO3 suspension to 2.5-3. Drying at 110 °C engendered the formation of spheroidal anatase, although freeze-dried anatase particles assembled into a flake-like shape. The freeze-dried samples show lower crystallinity. With grafting Cu ions, rutile exhibited better photocatalytic performance for the decomposition of gaseous 2-propanol (IPA) under visible light, although it did not work effectively for anatase. 相似文献
105.
Shigehito Isobe Somei OhnukiWilliam I.F. David Matthias GutmannMartin O. Jones Peter P. EdwardsTakayuki Ichikawa Yoshitsugu Kojima 《International Journal of Hydrogen Energy》2011,36(13):7909-7913
We have synthesized a single crystal of lithium amide (LiNH2, LiND2) by melting method, and performed neutron diffraction of the single crystal at variable temperature. LiND2 is tetragonal structure and I-4 space group. Lattice parameters and unit cell volume of LiND2 at room temperature, 50 °C, 100 °C, 150 °C and 200 °C were determined. Both of the lattice parameters and the unit cell volume increase with increase of temperature. From these results, we have estimated coefficient of volumetric thermal expansion αV of LiND2 to be 222 × 10−6/K. With increase of temperature, all thermal ellipsoids gradually expand because of thermal vibration. 相似文献
106.
M Ohta N Matsuno K Isobe J Kuyama Y Uchida K Nasu H Ikehira K Uno 《Canadian Metallurgical Quarterly》1997,22(7):494-496
An unusual case of dislocation of the midfoot through the calcaneocuboid and naviculocuneiform joints is presented. The prognosis is excellent for most midfoot dislocations, as long as they are recognized and treated early. 相似文献
107.
Preparation and properties of novel poly(urethane-imide)s 总被引:7,自引:0,他引:7
A series of poly(urethane-imide)s were prepared by a novel approach. Polyurethane (PU) prepolymer was prepared by the reaction of polyester polyol and 2,4-tolylenediisocyanate (2,4-TDI), and then end-capped with phenol. The PU prepolymer was blended with poly(amide acid) or oligo(amide acid) prepared from 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6FDA) and oxydianiline (ODA) at room temperature in various weight ratios. The blend films obtained by casting and then drying were not transparent, suggesting that phase separation occurred between the polyimide (PI) and PU components. The films became transparent, however, after thermal treatment at 100°C and then 200°C for 1 h each, irrespective of the ratio of the two components. The poly(urethane-imide) films showed good solvent-resistance. Dynamic mechanical analysis of the films showed that glass transition temperatures (Tg) shifted depending on the ratio of PI and PU components. This shift of Tg, along with the transparency of the films, suggests that the PU and PI components employed here are miscible to some extent and that domains of each phase by microphase separation are small. Tensile measurement of the blend films from poly(amide acid) showed that the films are plastic or elastic, depending on the ratio of the components. Thermal stability of the PU was found to increase by the incorporation of polyimide component. 相似文献
108.
Toshihiro Isobe Yoshikazu Kameshima Akira Nakajima Kiyoshi Okada Yuji Hotta 《Journal of Porous Materials》2006,13(3):269-273
The effect of additives on paste rheology was investigated for preparation of porous ceramics with unidirectionally aligned
cylindrical pores. Ammonium poly-carboxylic acid (APA) used as a dispersant and it was adsorbed on alumina powder surface.
The adsorption isotherm of APA was fitted by Langmuir equation. The saturated monolayer adsorption was 5.9 mg/g. The apparent
viscosity became a minimum at 0.8 mass % of APA corresponding to 71.2 mPa⋅s. This APA amount of 5.6 mg/g, is in good agreement
with the observed APA amount. Since the nylon 66 fibers (0–35 vol. %) mixed with the alumina powder have a strong interaction
with each other, they became twisted and agglomerated. This agglomeration increased with increasing fiber content but decreased
by adding oleic acid. The pastes with added oleic acid were capable of being extruded at higher pressure. The obtained porous
alumina ceramics showed highly oriented cylindrical pores parallel to the extrusion direction. The pore orientation was higher
in the oleic acid added pastes than those without oleic acid. The added nylon 66 fibers are mostly converted to pores while
maintaining the original shape after sintering. The pore size distribution of the obtained porous ceramics measured by mercury
porosimetry method showed a peak at about 4 μm which is apparently smaller than that observed in the SEM photographs and the
obtained result is considered to be corresponding to the necks formed by fiber contacts. 相似文献
109.
Tsutomu Momoi 《Journal of Low Temperature Physics》2002,126(1-2):731-736
We investigate quantum fluctuations of striped and honeycomb domain walls in 2D incommensurate states at T=0 near the commensurate-incommensurate transition point. It is revealed that stripes melt due to quantum fluctuations and become a soliton liquid for a large-wall-spacing region. Zero-point energies of striped and honeycomb phases are calculated using an elastic theory. As a consequence of these results, phase diagrams for soliton-lattice and liquid phases are discussed for various domain-wall masses. 相似文献
110.
Toshihiko Hirama Masashi Goto Toshiyasu Hasegawa Minoru Kanechika Takahiro Kei Tsutomu Mieda Hiroshi Abe Katsuki Takiguchi Hiroshi Akiyama 《Nuclear Engineering and Design》2005,235(13):1128
In Japan, the Nuclear Power Engineering Corporation (NUPEC), sponsored by the Ministry of Economy, Trade and Industry (METI), has been conducting a series of seismic reliability proving tests using full-scale or close to full-scale models to simulate actual important equipment that is critical for seismic safety of nuclear power plants. The tests are intended to validate the seismic design and reliability with a sufficient margin even under destructive earthquakes. A series of tests was carried out on a reinforced concrete containment vessel (RCCV) for advanced boiling water reactor (ABWR) from 1992 to 1999. A large-scale high-performance shaking table at Tadotsu Engineering Laboratory, the largest in the world, was used for this test. Part 1 reports the test model and the results of pressure and leak tests. Part 2 describes test procedures, input waves and the results of verification tests such as changes of stiffness, characteristic frequency and damping ratio, the failure of the model and the load deflection. Part 3 shows the seismic safety margin that was evaluated from the energy input during the failure test to a design basis earthquake. Part 4 reports simulation analysis results by a stick model with lumped masses. 相似文献