Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopic studies on the ferroelectric behavior of poly(vinylidene fluoride–trifluoroethylene) ultrathin films

Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm⁻¹ band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF₂ dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm⁻¹ band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF₂ dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm⁻¹ band after removing the applied voltage during corona poling.     

Dynamic vulcanisation of EPDM/PE-based thermoplastic vulcanisates studied along the extruder axis

Simple blending and dynamic vulcanisation of EPDM/PE blends using the resol/SnCl₂ system was studied in an extruder using a series of sampling devices. The melting of the PE pellets occurs just in front of and in the first kneading zone. Upon complete melting of the PE phase, the EPDM/PE blends reach very quickly their final morphology. Crosslinking of the EPDM phase to high levels occurs already when the PE phase is not yet fully molten. The higher the EPDM content, the higher the viscous dissipation, the higher the melt temperature and, consequently, the higher the crosslinking rate. For the EPDM/PE (50/50; w/w) TPV a transition from continuous via co-continuous to fully dispersed EPDM is observed, which is driven by crosslinking. Although the degree of crosslinking of the EPDM rubber is very high, this does not prevent phase inversion of the blend. The EPDM/PE interface is rather blurred, because PE crystalline lamellae are growing into the EPDM domains, probably because of the high compatibility between PE and EPDM (60 wt% of ethene). This study shows that dynamic vulcanisation in extruders proceeds quite differently from that in batch kneaders, where melting, mixing and crosslinking are separated in time. In extruders mass and heat transport, melting of the thermoplastic, morphology development (including dispersion and phase inversion), distribution and dissolution of (crosslinking) chemicals and crosslinking of the rubber do not occur as independent phenomena, but mutually and/or continuously interact.     

Dynamics of plastic polygonal plates with rounded corners

A method of calculating the dynamic deflection of rigidly plastic plates resting on a viscoelastic bed with complex piecewise-smooth support contours composed of sections of straight lines and circles under impact and explosion loading is presented. The general solution, which includes previously known partial solutions for circular and polygonal plates, is obtained. The results of calculation of the deflection of a square hinge-supported plate with rounded corners are presented for the case of the presence and absence of a plastic base.Translated from Problemy Prochnosti, No. 9, pp. 62–66, September, 1991.     

The state of stress and strain of an elastic cylindrical shell under acoustic action

The article investigates the state of stress and strain of the surface of an elastic cylindrical shell whose outer part is subjected to the effect of an incident acoustic wave. A qualitative and quantitative analysis of the state of strain of the surface is carried out and recommendations are given for optimizing the functional purpose of the shell and minimizing the arising stresses.Translated from Problemy Prochnosti, No. 4, pp. 43–47, April, 1991.     

Ductile-to-brittle transition temperature of high-strength steel for fastners of power equipment under pressure

The influence of the level of defectiveness of design and service origin (grooves and cracks) of a fastener and an impact specimen on the accuracy of determination of the allowable values of the ductile-to-brittle transition temperature is investigated. An evaluation of the allowable ductile-to-brittle transition temperatures making it possible to impose more soundly based requirements for effectiveness of the material in the stages of design, production, and service in relation to the production condition of the steel, the level of defectiveness of the fastener, and the specified operating life of the threaded joint is proposed.Translated from Problemy Prochnosti, No. 5, pp. 35–37, May, 1991.     

Stimulation of negative magnetoresistance by an electric field and light in silicon doped with boron and manganese

It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established.     

Interband light absorption in size-confined systems in uniform electric fields

A simple approach to calculation of the interband absorption coefficient in a uniform electric field is developed. This approach provides a means for studying the special features of electroabsorption in a wide class of semiconductor systems on the basis of the most general relationships. The approach is used to study the electroabsorption in two-dimensional systems with different profiles of their one-dimensional potential, quantum wells, and superlattices in magnetic fields.     

Cross-layer design: a survey and the road ahead

Of late, there has been an avalanche of cross-layer design proposals for wireless networks. A number of researchers have looked at specific aspects of network performance and, approaching cross-layer design via their interpretation of what it implies, have presented several cross-layer design proposals. These proposals involve different layers of the protocol stack, and address both cellular and ad hoc networks. There has also been work relating to the implementation of cross-layer interactions. It is high time that these various individual efforts be put into perspective and a more holistic view be taken. In this article, we take a step in that direction by presenting a survey of the literature in the area of cross-layer design, and by taking stock of the ongoing work. We suggest a definition for cross-layer design, discuss the basic types of cross-layer design with examples drawn from the literature, and categorize the initial proposals on how cross-layer interactions may be implemented. We then highlight some open challenges and new opportunities for cross-layer design. Designers presenting cross-layer design proposals can start addressing these as they move ahead.     

Current and future water issues in the Oldman River Basin of Alberta, Canada.

Long-term trends in alpine and prairie snow pack accumulation and melt are affecting streamflow within the Oldman River Basin in southern Alberta, Canada. Unchecked rural and urban development also has contributed to changes in water quality, including enhanced microbial populations and increased waterborne pathogen occurrence. In this study we look at changing environment within the Oldman River Basin and its impact on water quality and quantity. The cumulative effects include a decline in net water supplies, and declining quality resulting in increased risk of disease. Our data indicates that decreases in the rate of flow of water can result in sedimentation of bacterial contaminants within the water column. Water for ecosystems, urban consumption, recreation and distribution through irrigation is often drawn from waterholding facilities such as dams and weirs, and concern must be expressed over the potential for contaminate build-up and disproportionate potential of these structures to pose a risk to human and animal health. With disruption of natural flow rates for water resulting from environmental change such as global warming and/or human intervention, increased attention needs to be paid to use of best management practices to protect source water supplies.