IV. Referate

Ohne Zusammenfassung     

Referate

Ohne Zusammenfassung     

Prediction of Continuous Cooling Transformation Diagrams for Dual-Phase Steels from the Intercritical Region

The purpose of the present work is the implementation and validation of a model able to predict the microstructure changes and the mechanical properties in the modern high-strength dual-phase steels after the continuous annealing process line (CAPL) and galvanizing (Galv) process. Experimental continuous cooling transformation (CCT) diagrams for 13 differently alloying dual-phase steels were measured by dilatometry from the intercritical range and were used to tune the parameters of the microstructural prediction module of the model. Mechanical properties and microstructural features were measured for more than 400 dual-phase steels simulating the CAPL and Galv industrial process, and the results were used to construct the mechanical model that predicts mechanical properties from microstructural features, chemistry, and process parameters. The model was validated and proved its efficiency in reproducing the transformation kinetic and mechanical properties of dual-phase steels produced by typical industrial process. Although it is limited to the dual-phase grades and chemical compositions explored, this model will constitute a useful tool for the steel industry.     

Preparation and characterization of poly (butylene terephthalate)/graphene composites by in-situ polymerization of cyclic butylene terephthalate

The ultra-low viscosity of cyclic butylene terephthalate oligomers has been exploited to perform their in-situ ring-opening polymerization in the presence of graphene, to obtain homogeneously dispersed poly(butylene terephthalate)/graphene (PBT/G) composites containing 0.5 to 1.0 %wt of graphene. The results of gel permeation chromatography show that increasing amounts of graphene causes a decrease in the average molecular weight of PBT if the time of polymerization is kept constant, and morphological investigations performed by electron microscopy and x-rays diffraction show that high levels of dispersion of the G sheets are easily obtained by this method of composites processing. Thermal properties of the composites were studied by differential scanning calorimetry and thermogravimetric analysis; results indicate that increasing amounts of G do not strongly influence the degree of crystallinity and the crystallization temperature of PBT, while its thermal stability is significantly increased by the presence of G. All the PBT/G composites demonstrated to be electrically conductive; we found that the electric field assisted thermal annealing of the PBT/G composites induces an increase in conductivity.     

Mechanical behaviour of hazelnuts used for table consumption under compression loading

Nuts of four hazelnut varieties and five new selections used for table consumption were compressed at the moisture content of 6% wet basis to measure shell resistance to breakage. Rupture force, rupture energy and nut specific deformation were measured under three compression loading positions. Physical parameters of nuts were also evaluated to relate them to the data obtained by compression test measurements. Rupture force and nut specific deformation are the most discriminant parameters that can be used to describe the behaviour under compression, while rupture energy values show fewer differences among the considered varieties. The values of force required to break nut shell ranged from 322.2 to 769.3 N. The lowest values of force were generally obtained along the y‐axis, the transverse axis containing the major dimension at right angles to the longitudinal axis. Nut specific deformation ranged from 3.35 to 11.76%. Correlations between physical and texture parameters showed that values of force, energy and deformation were dependent on different parameters that varied in the three considered axis. The most used varieties, Ennis and Barcelona, showed high mean values of force rupture to break shell and low deformability, while Tonda Giffoni and Tonda Bianca were easy to break. Among the new selections, L35 and B6, with mean values of force rupture less than 428 N and values of nut specific deformation higher than 8%, were suitable for table consumption. Copyright © 2006 Society of Chemical Industry     

HRMAS-NMR spectroscopy and multivariate analysis meat characterisation

(1)H-high resolution magic angle spinning-nuclear magnetic resonance spectroscopy was employed to gain the metabolic profile of longissimus dorsi and semitendinosus muscles of four different breeds: Chianina, Holstein Friesian, Maremmana and Buffalo. Principal component analysis, partial least squares projection to latent structure - discriminant analysis and orthogonal partial least squares projection to latent structure - discriminant analysis were used to build models capable of discriminating the muscle type according to the breed. Data analysis led to an excellent classification for Buffalo and Chianina, while for Holstein Friesian the separation was lower. In the case of Maremmana the use of intelligent bucketing was necessary due to some resonances shifting allowed improvement of the discrimination ability. Finally, by using the Variable Importance in Projection values the metabolites relevant for the classification were identified.