Strain mediated enhancement in magnetoelectric properties of sonochemically synthesized piezoelectric and piezomagnetic composites

Materials with magneto-electric (ME) properties are of great importance because of their demand in electronic industries. Three dimensional nano-particles of the ME-composites having the general formula (1-x)CoCr_0.3Fe_1.7O₄(CCFO)+(x)BaTiO₃(BTO) (x = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) were obtained by comprising the piezoelectric-BTO and piezomagnetic-CCFO phases. The individual phases of CCFO and BTO were synthesized separately by ultrasonic irradiation assisted sonochemical and sol-gel routs. X-ray diffraction patterns (XRD) confirmed the well-crystalline nature of both the phases. BTO and CCFO phases were under tensile strain as confirmed by the variation in lattice constants with varying proportion of BTO and CCFO. An energy-dispersive X-ray spectroscopy spectrum confirmed the phase purity of the samples and stoichiometric concentration of elements. Magnetic properties were investigated by M ? H loop measurements and dielectric properties by using RF impedance analyzer. Dielectric constant increased with the increasing percentage of BTO. The maximum value of ME coefficient (24.7 mV/cm?Oe) is observed for the 60%CCFO+40%BTO sample. The obtained results were discussed in the light of grain size, strain and the basic properties of the individual phases. The prepared materials can be applicable in electronic devices where high magneto-electric coefficient is desirable.     

Two-Dimensional Silicene–Stanene Heterostructures by Epitaxy

The synthesis of new Xenes and their potential applications prototypes have achieved significant milestones so far. However, to date the realization of Xene heterostructures in analogy with the well known van der Waals heterostructures remains an unresolved issue. Here, a Xene heterostructure concept based on the epitaxial combination of silicene and stanene on Ag(111) is introduced, and how one Xene layer enables another Xene layer of a different nature to grow on top is demonstrated. Single-phase (4 × 4) silicene is synthesized using stanene as a template, and stanene is grown on top of silicene on the other way around. In both heterostructures, in situ and ex situ probes confirm layer-by-layer growth without intercalations and intermixing. Modeling via density functional theory shows that the atomic layers in the heterostructures are strongly interacting, and hexagonal symmetry conservation in each individual layer is sequence selective. The results provide a substantial step toward currently missing Xene heterostructures and may inspire new paths for atomic-scale materials engineering.     

Microneedles for transdermal drug delivery: a systematic review

Transdermal route has been explored for various agents due to its advantage of bypassing the first pass effect and sustained release of drug. Due to strong barrier properties of the skin, mainly stratum corneum (SC), the delivery of many therapeutic agents across the skin has become challenging. Few drugs with specific physicochemical properties (molecular weight <500?Da, adequate lipophilicity, and low melting point) can be effectively administered via transdermal route. However, delivery of hydrophilic drugs and macromolecular agents including peptides, DNA and small interfering RNA is challenging. Drug penetration through the SC may involve bypass or reversible disruption of SC layer by various means. Recently, the use of micron-scale needles has been proposed in increasing skin permeability and shown to dramatically increase permeation, especially for macromolecules. Microneedles (MNs) can penetrate through the SC layer of the skin into the viable epidermis, avoiding contact with nerve fibers and blood vessels that reside primarily in the dermal layer. This review summarizes the types of MNs and fabrication techniques of different types of MNs. The safety aspects of the materials used for fabrication have been discussed in detail. Biological applications and relevant phase III clinical trials are also highlighted.     

Difference expansion based reversible data embedding and edge detection

Multimedia Tools and Applications - Difference Expansion (DE) based techniques are evolving in the last decade. The DE based techniques aims at reversibly embedding the data into cover content....     

A PC-based system integrating CMM and CAD for automated inspection and reverse engineering

A personal computer (PC)-based system integrating a manual CMM and a CAD system has been developed for on-line capture of 3D point data, resulting in the automation of the inspection process. The sequence of steps taken to measure a master component using the CMM is stored in a measurement program in teach mode and replayed for repetitive measurement of a batch of identical components in the replay mode. The measurement program guides the CMM operator regarding the geometric entity to be measured, the number of points to be input and the direction to be followed for taking the points on the CMM. The operator has simply to follow the sequence displayed on the computer screen. The program automatically computes the dimensions and the deviations from the corresponding dimensions of the master component. The 3D measurement data from the CMM are transferred to a CAD system in real time. Programs have been developed to create 3D cubic splines and surfaces from the 3D point data taken on the CMM. The full features of the CAD software can be used to manipulate the 3D point data for CAD applications.     

Fabrication and testing of Al-SiCp composite valve seat inserts

In the present work Al-SiC_p composite valve seat inserts with 10, 15, 20, and 25 wt?% of SiC_p were fabricated through die compaction of powders and subsequent sintering at 580 °C. Valve seat inserts were also fabricated through the gravity die casting process. The Rockwell hardness, density, radial crushing load and surface roughness of the Al-SiC_p composites (with different wt % of SiC_p) and steel valve seat inserts presently used in engines were measured and compared. The Rockwell hardness and radial crushing load for Al-15, 20, and 25wt% of SiC_p composite valve seat inserts were higher than that of the steel valve seat inserts presently used in engines. The microstructure of the cast and powder metal Al-SiC_p composites was also studied.     

Development of abrasive cut-off wheel having side grooves

The abrasive cut-off wheel fails prematurely during the routine sectioning of workpiece, which may cause injury to the operator. One of the major reasons of premature failure is the improper mixing of the abrasive mixture. In order to provide strength to the wheel, it was reinforced by woven roving type glass fiber and the abrasive mixture was ball milled. Cutting zone temperature becomes high during the cutting operation, which may cause thermal damage to the workpiece and debonding of abrasive from the wheel. It is very difficult to supply the cutting fluid to the cutting zone in order to reduce the temperature. New types of abrasive cut-off wheels were developed, which have radial passages on their surfaces to supply the cutting fluid to the cutting zone. Performance of the wheels was compared and the mechanical strength of the wheel material was tested.     

High Performance Lithium‐Ion Batteries Using Layered 2H‐MoTe2 as Anode

The major challenges faced by candidate electrode materials in lithium‐ion batteries (LIBs) include their low electronic and ionic conductivities. 2D van der Waals materials with good electronic conductivity and weak interlayer interaction have been intensively studied in the electrochemical processes involving ion migrations. In particular, molybdenum ditelluride (MoTe₂) has emerged as a new material for energy storage applications. Though 2H‐MoTe₂ with hexagonal semiconducting phase is expected to facilitate more efficient ion insertion/deinsertion than the monoclinic semi‐metallic phase, its application as an anode in LIB has been elusive. Here, 2H‐MoTe₂, prepared by a solid‐state synthesis route, has been employed as an efficient anode with remarkable Li⁺ storage capacity. The as‐prepared 2H‐MoTe₂ electrodes exhibit an initial specific capacity of 432 mAh g^?1 and retain a high reversible specific capacity of 291 mAh g^?1 after 260 cycles at 1.0 A g^?1. Further, a full‐cell prototype is demonstrated by using 2H‐MoTe₂ anode with lithium cobalt oxide cathode, showing a high energy density of 454 Wh kg^?1 (based on the MoTe₂ mass) and capacity retention of 80% over 100 cycles. Synchrotron‐based in situ X‐ray absorption near‐edge structures have revealed the unique lithium reaction pathway and storage mechanism, which is supported by density functional theory based calculations.     

Numerical Modeling of Exit-Ply Delamination During Drilling of CFRPs Considering Thermal Effects

Abstract

A finite element (FE) model for exit-ply delamination during drilling carbon fiber reinforced polymers (CFRPs) laminates is presented. The current FE model is developed to predict critical thrust force at the onset of delamination for 1 and 2 plies under the twist drill for various cutting temperatures. The interface behavior for delamination onset is modeled using surface based cohesive zone model (CZM). The numerical predictions for critical thrust force are compared with experimental thrust forces for various number of plies under the twist drill over a range of cutting temperature. Thrust force predictions were found to match with experimental data.     

Quaternary 2D Transition Metal Dichalcogenides (TMDs) with Tunable Bandgap

Alloying/doping in 2D material is important due to wide range bandgap tunability. Increasing the number of components would increase the degree of freedom which can provide more flexibility in tuning the bandgap and also reduces the growth temperature. Here, synthesis of quaternary alloys Mo_x W_1?x S_2y Se_{2(1?y )} is reported using chemical vapor deposition. The composition of alloys is tuned by changing the growth temperatures. As a result, the bandgap can be tuned which varies from 1.61 to 1.85 eV. The detailed theoretical calculation supports the experimental observation and shows a possibility of wide tunability of bandgap.