两亲性无规共聚物MAA-SMA-PEGMA的表面活性研究

利用功能性单体甲基丙烯酸(MAA)、甲基丙烯酸十八烷基酯(SMA)和聚乙二醇甲基丙烯酸酯(PEG-MA)通过自由基共聚,合成了两亲性共聚物Poly(MAA-SMA-PEGMA)。研究了其结构、临界胶束浓度(CMC)和表面张力,探讨了由共聚物与低分子表面活性剂组成的复配体系。结果表明高低分子表面活性剂复配体系在质量比为5∶5后,体系的表面张力和临界胶束浓度都有所降低,接近于低分子表面活性剂。     

基于组件的大数据分析服务平台

随着数据规模的快速增长,单机的数据分析工具已经无法满足需求。针对大数据的分析问题,设计并实现了一种基于组件的大数据分析服务平台Haflow。Haflow自定义了业务流程模型和可扩展的组件接口,组件接口支持各种异构工具的集成。系统接收用户定义的业务流程,将其翻译成执行流程实例,提交到Hadoop分布式集群上执行。Haflow是一个可扩展的、分布式的、支持异构分析工具的、面向服务的大数据分析服务平台。提出该平台有两重意义:一方面平台将与数据分析业务无关的工作封装起来,支持各种异构组件,以加快分析应用的开发速度;另一方面,平台后端使用Hadoop分布式系统来实现多任务的并发,从而提高应用的平均执行速度。     

Silica Nanoboxes as New Nano-structured Materials: Their Secondary Synthesis from Alumina-Rich Zeolites

Novel silica nanoboxes were prepared by controlled dealumination of Na-X and Ca-A type zeolites using ammonium hexafluorosilicate (AHFS). The silica-richer the parent zeolite, the smaller the average pore size produced and the narrower the pore size distribution obtained. This was due to the specific reactivity of the extracting agent with the zeolite framework aluminum atoms. High temperature calcination of the dealuminated X-zeolite (ammonium form) resulted in mesoporous materials exhibiting an ink-bottle shape, a quite high surface area (330 m²/g, no micropores), an average pore diameter of 4.5 nm with a quite narrow pore size distribution (± 1.0 nm) and finally, a pore opening diameter of 3.9 nm. The latter was determined by using the nitrogen sorption isotherms (BET technique) and related pore volume data. The sorption behavior also suggested the interconnecting character of the newly created nanoboxes. The periodicity of these nanoboxes throughout the mesoporous material was clearly shown by X-ray powder diffraction at very small angles. These materials, herein called monomodal nanoboxes because of the absence of micropores in the structure, were also thermally stable. Incorporation of orthosilicate into the obtained silica nanoboxes, in accordance with the recently developed technique for pore size engineering in zeolites, led to materials with smaller pore openings but having almost the same textural properties. Solid superacidic materials were prepared by incorporating a liquid superacid (triflic acid or trifluoromethanesulfonic acid) into the silica nanoboxes using the wet impregnation technique. The maximum triflic acid loading which did not significantly affect the mesoporous framework of the materials was 24 wt%. As a reference, the maximum loading of less acidic sulfuric acid was slightly lower. All this showed the high chemical stability of the silica nanoboxes for supporting very acidic species. Temperature-programmed desorption using a combined DTA/TGA system allowed the identification of the bound phases and some liquid phase of the loaded triflic acid.     

Characterization of cationic water-soluble polyacrylamides

Copolymers of poly(acrylamide-co-acryloyloxyethyltrimethylammonium chloride or AM–CMA) and poly(acrylamide-co-methacryloyloxyethyltrimethylammonium chloride or AM–CMA) prepared by inverse emulsion polymerization were characterized by different analytical techniques. The chemical composition of the copolymers was estimated by elemental analysis and by nuclear magnetic resonance spectroscopy (NMR). NMR spectroscopy and computer simulation were further used for investigating the polymers' sequence distribution. The poly(AM–CMA) copolymers are chemically more homogeneous than are the poly(AM–CMA). The configurational propagation of dyads and triads for the homopolymers obeys Bernouilli's statistics. For the copolymers, the chemical sequences distribution is governed by Markov's first-order statistics.     

聚甲醛的光稳定化研究

采用了二苯甲酮类和苯并三唑类紫外线吸收剂(UVA)、位阻胺类光稳定剂(HALS)以及光屏蔽剂对聚甲醛进行光稳定化改性,对比了改性前后聚甲醛光降解后的物理力学性能及表面层分子量保持率。结果表明,0 5%的UVA可以显著提高POM的耐紫外光性能,苯并三唑类效果优于二苯甲酮类UVA。在酚类抗氧剂存在下,低含量的HALS(<0 25%)对聚甲醛没有光稳定化作用。     

基于复杂网络理论的连锁故障模型研究概述

在复杂网络中,由微小触动引发的网络连锁故障会导致网络崩溃的灾难性后果,对连锁故障的理论建模是研究复杂网络连锁故障的关键和基础。论文从复杂网络理论角度介绍和评述了几种连锁故障模型,分析了预防和控制连锁故障的可行途径;并指出了今后值得注意的研究方向。     

嵌入式可信计算平台测评系统的设计与实现磁

针对嵌入式平台功耗低、资源少等特点,设计了适用于嵌入式平台的可信芯片及嵌入式软件栈,构建了嵌入式可信计算平台。为使嵌入式可信计算平台能够有效地为嵌入式应用提供可信功能支持,论文设计并实现了嵌入式可信计算平台测评系统,从应用服务角度出发,保证嵌入式应用调用的可信功能的正确性。该测评系统支持多个平台的并行测试,并能根据不同需求定制测试方案,支持测试报表分析测试结果,且引起的平台额外开销较小。     

基于RFID技术的监所巡更系统

介绍一种基于射频卡及读卡器进行软件开发而成的方便实用的监所巡更系统。由PC微机、射频卡及其读卡器等部分组成,完成巡更资料的采集、传输、管理等功能。该统既可以加强对监所的管理,又可以省去管理人员检查的麻烦,同时也适应各监所逐步普及计算机管理、提高管理水平的要求,具有很好的实用和推广意义。     

基于Max-T模糊Hopfield网络的车型识别

在许多模式识别采样的过程中,由于环境噪声和设备误差,往往导致采集的数据与真实值有一定偏差,这种偏差会影响识别的效果。本文采用Max-T FHNN模型,提出一种应用于智能化交通管理的车型识别方法。并用实验证实相对于其他车型识别方法,该方法在待测样本含有噪声的情况下能得到更好的识别率。     

网络考试系统设计

文章研究了网络考试系统的需求,设计了试卷生成算法。