A novel cyclic process using CaSO4/CaS pellets for converting sulfur dioxide to elemental sulfur without generating secondary pollutants: Part II. Hydrogen reduction of calcium-sulfate pellets to calcium sulfide

The reduction of calcium sulfate to produce calcium sulfide is a part of the cyclic process for converting sulfur dioxide to elemental sulfur that is described in Part I. The kinetics of the hydrogen reduction of nickel-catalyzed calcium-sulfate pellets were investigated using a thermogravimetric analysis (TGA) technique at reaction temperatures between 1023 and 1088 K and hydrogen partial pressures between 12.9 and 86.1 kPa. The reactivity of nickel-catalyzed calcium-sulfate pellets was demonstrated by the conversion of 70 pct fresh nickel-catalyzed calcium sulfate to calcium sulfide in 20 minutes at 1073 K under a hydrogen partial pressure of 86.1 kPa. Furthermore, the reactivity remained relatively intact after ten cycles of reactions and regenerations. This observed characteristic of the pellets is important because the solids must be reusable for repeated cycles to avoid generating secondary pollutants. The nucleation and growth rate expression was found to be useful in describing the kinetics of the reaction, which had an activation energy of about 167 kJ/mol (∼40 kcal/mol) in all reaction cycles except for the first regenerated samples that were lower at 146 kJ/mol (35 kcal/mol). The reaction order with respect to hydrogen partial pressure was 0.22 in all cycles with the exception of the first regenerated sample for which it was 0.37.     

45钢表面超音速电弧喷涂Ti-Al涂层的组织与性能研究

采用自行开发研制的超音速电弧喷设备，在45钢表面制成了钛铝合金复合涂层。并利用金相显微镜、X射线衍射仪、扫描电镜、电子探针，对涂层的成分、相结构、显微组织及其结合强度、显微硬度进行了研究。结果表明，利用超音速电弧喷涂设备，可以在45钢表面形成 度高、孔隙率低，结合强度较好和硬度高的Ti-Al合金涂层。     

金竹林隧道渗漏水治理技术

金竹林隧道是万梁高速公路上一座双跨连拱式隧道 ,隧道位于黄泥塘背斜北东倾伏端 ,岩层在隧道内呈单斜构造。隧道穿越北西向的山脊 ,脊顶狭窄 ,坡面顺直 ,自然坡度 2 0°～ 3 0° ,局部达 4 5°,相对高差约 1 2 0m。隧道东西口及洞身大多基岩裸露 ,植被稀少 ,仅在东洞口有小范围的粘土夹碎块石覆土层 ,厚2～ 8m ,隧道范围内孔隙水不发育 ,大气降水和地表水亦不发育 ,基岩裂隙水主要由大气降水补给。在隧道开挖过程中涌水量为 90m3 d。1　病害现状及成因分析在隧道建成后 ,但尚未正式投入运营时 ,发现中墙顶部以下多数地段 ,特别是洞口段存…     

信息网络对学风建设的影响与思考

针对当前学生因迷恋网络而影响学业的突出问题,透过现象,分析存在这些问题的根源.通过剖析信息网络对学风建设的利弊影响,针对性地提出了趋利避害的方法与措施,这为当前高职院校的学风建设提出了富有建设性的思考与探索.     

Effects of extended dislocations on charge distribution in GaN epilayer

We have investigated the effect of extended dislocations (0.5-3 μm) on charge distribution in GaN epilayer grown by metalorganic chemical vapor deposition on (0001) sapphire using atomic force microscopy (AFM) and scanning surface potential microscopy (SSPM). It has been observed for the surface at the extended dislocations present in undoped GaN film to be negatively charged showing 0.04-0.2 V higher potential relative to regions that contain no dislocations. In addition to the higher potential at the dislocation core, the surrounding surfaces, including the edge of the dislocations, are also negatively charged in a symmetric way around the dislocations revealing crater-shaped higher potential regions (∼0.04 V) relative to surrounding dislocation-free area. The experimental results show that the protrusion-type of dislocation is also negatively charged and its potential is dependent on the size of dislocation.     

基于公钥加密算法和PPCT动态图编码的软件指纹方案

提出了一种综合PPCT动态图编码方法和椭圆曲线加密算法的软件指纹方案,该方案将公钥加密技术和软件水印技术综合应用于软件版权的保护和验证过程中,充分利用两者的优势,具有安全性高和抗恶意篡改能力强的特点.     

在LabVIEW程序运行中实现控件的动态移动

通过两种在LabVIEW程序运行中实现控件移动的方法的对比,着重介绍了结合了VI Sever技术的动态注册事件结构的用法,从而总结出其具有优化程序、减少内存、提高CPU利用率等方面的优点.     

以创新实现云南文山斗南锰资源的有效利用

随着国民经济特别是钢铁工业的迅速发展，资源危机成为困扰资源型可持续发展的核心问题，只有坚持以创新为动力，才能实现锰矿等资源的有效利用。     

从业主角度如何对工程造价进行管理与控制

从业主的角度说明了对工程全过程的工程造价进行管理与控制,有效地降低成本,提高投资收益。