熔融-固相缩聚法中固相聚合对聚乳酸合成的影响

以L 乳酸单体为原料 ,熔融 -固相缩聚法合成了聚乳酸 ,重点研究了固相聚合的工艺条件。结果表明 ,绝对压力 60Pa ,氯化亚锡为催化剂 ,分段控温 ,可使聚乳酸的粘均分子量提高到固相聚合反应前的 5 3倍。通过对固相聚合产物的结晶度和熔点的分析 ,探讨了固相聚合的机理。     

Dy3+激活的几种硼酸盐在VUV-VIS范围的光谱性质

本文报道了SrAl2B2o7:Dy^3 、BaAl2B2O7:Dy^3 、SrAl3BO7:Dy^3 、La2CaB10O19:Dy^3 的紫外－真空紫外（UV－VUV）激发光谱和UV激发下的发射光谱。根据发射光谱讨论了Dy^3 离子在这几种基质中发光的黄蓝比（Y／B）。在VUV激发光谱中推测了Dy^3 的f-d跃迁及电荷迁移态（CTS）和基质吸收的位置。     

45钢表面超音速电弧喷涂Ti-Al涂层的组织与性能研究

采用自行开发研制的超音速电弧喷设备，在45钢表面制成了钛铝合金复合涂层。并利用金相显微镜、X射线衍射仪、扫描电镜、电子探针，对涂层的成分、相结构、显微组织及其结合强度、显微硬度进行了研究。结果表明，利用超音速电弧喷涂设备，可以在45钢表面形成 度高、孔隙率低，结合强度较好和硬度高的Ti-Al合金涂层。     

温度计量技术进展近况

近年来，在把ITS－90更方便地传递到工作用温度计，温度测量仪表采用信息技术和特殊工业场合测温应用方面均取得了一些进展。本文介绍了国内外温度技术在这些方面进展的状况。对温度定点，校验器，热电偶和热电阻测温，辐射测温，光纤测温和信息时代自动化系统中的温度检测仪表的重要进展分别作了介绍。     

TP130TT高抗挤套管研究与应用

为了提高盐层段固井质量 ,中原油田研究开发了 TP130 TT高抗挤套管 ,性能试验评价表明 ,其抗挤强度超过 16 0 MPa,并给出了其固井质量评价标准。在中原油 346口井中的应用表明 ,该套管有效地解决了盐层段套管损坏问题 ,延长了油气水井寿命 ,经济效益和社会效益显著。     

金竹林隧道渗漏水治理技术

金竹林隧道是万梁高速公路上一座双跨连拱式隧道 ,隧道位于黄泥塘背斜北东倾伏端 ,岩层在隧道内呈单斜构造。隧道穿越北西向的山脊 ,脊顶狭窄 ,坡面顺直 ,自然坡度 2 0°～ 3 0° ,局部达 4 5°,相对高差约 1 2 0m。隧道东西口及洞身大多基岩裸露 ,植被稀少 ,仅在东洞口有小范围的粘土夹碎块石覆土层 ,厚2～ 8m ,隧道范围内孔隙水不发育 ,大气降水和地表水亦不发育 ,基岩裂隙水主要由大气降水补给。在隧道开挖过程中涌水量为 90m3 d。1　病害现状及成因分析在隧道建成后 ,但尚未正式投入运营时 ,发现中墙顶部以下多数地段 ,特别是洞口段存…     

信息网络对学风建设的影响与思考

针对当前学生因迷恋网络而影响学业的突出问题,透过现象,分析存在这些问题的根源.通过剖析信息网络对学风建设的利弊影响,针对性地提出了趋利避害的方法与措施,这为当前高职院校的学风建设提出了富有建设性的思考与探索.     

Preparation and Application of Active Composite Antibacterial Material Containing Ag~ and Zn~(2 )

1Introduction Harmfulbacteriaexistanywhereintheworldsuchas soil,air,water,surfacesofobjectsandourskins,etc.Thenumberofbacteriumisenormous,withmanydiffer entspecies.Theyhavethreatenedthehealthofhuman beingsseriously.Withthedevelopmentofeconomyand environme…     

Failure analysis used for remanufacturing of steel rolling components

The guide-pieces, used in the process line of steel rolling, were the important components. The guidepieces, which were slide contacting with the rolled-piece, had a high temperature and high speed. The wear was very serious. The results from failure analysis showed that there were three failure forms in the guide-pieces: the first was the wear during heat friction, the second was the heat fatigue under the cycle of deep heating and deep cooling, and the third was the impact rupture. Among them, the wear was the main reason. To the wear of guidepieces, there were four mechanisms, namely abrasive wear, adhesive wear, fatigue wear and corrosion wear. The failure analysis to the guide-piece laid the foundation for its remanufacturing. Foundation item: Project(50235030) supported by the National Natural Science Foundation of China     

Viscosity estimation for slags containing calcium fluoride

Based on recently published experimental data, the Riboud model was modified for viscosity estimation of the slags containing calcium fluoride. The estimated values were in good agreement with measured data. Reasonable estimation can be achieved using the modified Riboud model for mould fluxes and ESR (eletro slag remelting) slags. Especially for ESR slags, the modified Riboud model can provide much more precise values than the original Riboud model.