Effects of α‐form or β‐form nuclei on polymorphic crystalline morphology of poly(butylene adipate)

The effects of α‐form and β‐form nuclei on polymorphic morphology of poly(butylene adipate) (PBA) upon recrystallization from the molten state up to various T_max values were examined by differential scanning calorimetry (DSC), wide‐angle X‐ray diffraction (WAXD) and polarized light microscopy (PLM). In this study, PBA with complex melting and polymorphism behaviour was used as a model for examining different types and extents of residual nuclei. As the PBA initially containing the sole α‐crystal was brought to a molten state of various T_max, the extents of trace α‐form crystal nuclei varied and were dependent on T_max. Furthermore, it did not matter whether, initially, the PBA contained α‐ or β‐form crystals (or both) because only a single type of α‐nuclei could be left upon treatment to the molten liquid state at T_max. Therefore, only the α‐crystal in PBA had ‘memory capacity’ in the molten liquid state while the β‐crystal did not. This was so because the latter had been completely transformed into the solid state prior to being heated into a liquid. PBA crystallized before α‐nuclei could be packed into α‐crystal, regardless of the crystallization temperature (T_c). For recrystallization from molten PBA without any nuclei, the crystalline polymorphism was correspondingly influenced by T_c. Copyright © 2005 Society of Chemical Industry     

德国大型设备的出口包装

一、前言德国作为全球几大工业国之一,是世界上有名的机械电子设备出口国。这些年来大量的德国大型设备和生产线成套设备漂洋过海出口到了中国,这些设备涉及到汽车、石油、化工、钢铁、机械、电子等行业。怎样保证这些大型设备和成套设备安全抵达中国或其它国家用户所在地,是摆在德国有关生产企业与运输包装企业面前的重要课题。本文结合作者在德国汉堡出口包装有限责任公司——塞库瑞塔斯公司(Securitas)看到的情况,介绍一下有关德国大型设备出口包装的方法。     

光纤码分多址技术在城域接入网中的应用

分析了光纤码分多址技术O -CDMA在城域接入网中的应用。回顾了O -CDMA技术的发展历史 ,详细地介绍了O -CDMA技术的特点 ,其具有的公平性、灵活性、网络控制管理、对服务区处理能力以及高的安全性使O -CDMA技术成为较好的城域接入网技术。阐述了目前在应用中O -CDMA存在的一些技术方面的问题     

建筑涂料电脑调色系统的建立

分别从市场及技术方面讨论了建立电脑调色系统的主要程序、方法和技术要求等,讨论了建立调色系统所需的主要设备和仪器。     

HRP-12型负载杂多酸催化剂的失活原因及预防措施

采用XRD、NMR、IR、MS等手段对长链烷基苯合成中失活负载型杂多酸催化剂进行了表征,结果表明,催化剂的失活主要是由于表面结焦引起的,原料中的双烯、烷基芳烃杂质以及反应生成的副产物重烷基苯是引起催化剂结焦的主要原因,对原料进行脱双烯和脱芳烃精制、提高苯烯比以及用苯洗涤催化剂等措施能够有效抑制催化剂的失活。     

MX345芯片及单片机控制

MX345芯片用于产生模拟信令—CTCSS单音.本文在介绍MX345编码/解码器工作原理的基础上,设计出MX345芯片与单片机的接口电路.最后给出控制软件.     

Structure evolution of conductive polymer composites revealed by solvent vapor induced time-dependent percolation

The authors of this paper synthesized a series of amphiphilic triblock copolymers of polystyrene-b-poly(ethylene glycol)-b-polystyrene (PS-PEG-PS) having different PEG/PS ratios with nearly identical molecular weights of the entire copolymers. The interfacial interactions in the composites consisting of carbon black and the copolymers can thus be tailored. When these conducting composites are exposed to certain solvent vapors, their electrical resistances greatly increase, showing the gas sensitivity. The present work indicated that this switching behavior is controlled by the structural relaxation of the composites because matrix swelling acts as the main mechanism. The response time has been correlated with absolute temperature by Arrhenius equation, and the estimated activation energy reflects mobility of the fillers involved in the solvent induced expansion of the surrounding polymer. Therefore, by using the gas sensibility of the conductive composites, the structure evolution of the composite materials in solid state and the effect of filler/matrix interfacial interaction on the relaxation property of the matrix polymer has been inspected. It was found that lower activation energy represents stronger interfacial interaction in case good solvent of the matrix was used for the test.     

A Study of AlN Films Prepared by Arc Ion Plating

Hexagonal AlN films have been obtained by arc ion plating at different negative biases ,X-ray diffraction and scanning electron microscopy results show that AlN films with smooth surfaces and (002) preferred orientation are obtained at low biases ,whereas those with coarse surfaces and (100) preferred orientation are obtained at high biases,The formation mechanism of AlN is analyzed and the experiment results are discussed,The effect of bias on adhesion strength has also been examined.     

油气输导体系的类型及配置关系

将输导体系划分为储集层输导体系、断裂输导体系和不整合输导体系3大类，8种类型，指出输导体系的时空配置关系是决定油气藏的重要因素；着重阐明了输导层在空间和时间上的配置关系，认为这些配置关系是影响输导体系有效性的重要因素；提出了运移级次性的概念，讨论了划分运移级次对油气运移研究的意义，指出准噶尔盆地西北缘邻近玛湖以储集层输导体系和不整合输导体系为主．边缘地区以断层输导体系为主。浅层油气成藏期主要取决于断层的活动期。