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991.
Polypropylene (PP)/layered silicate nanocomposites were prepared via simple melt mixing of three components, PP, layered silicates modified with octadecylamine (C18-MMT) and antioxidant, to investigate the role of antioxidant. TEM and X-ray scattering results confirmed the intercalated state of silicates in PP/layered silicate nanocomposites with antioxidant. In rheological and mechanical study, the nanocomposites with antioxidant showed higher properties than those of the unfilled PP. The nanocomposite with 5 wt% C18-MMT and 0.5 phr antioxidant exhibited about 1.4 times higher tensile modulus and 1.3 times higher storage modulus than the unfilled PP. However, PP/C18-MMT without antioxidant showed lower rheological values owing to the thermal decomposition of PP and the poor compatibility between PP and C18-MMT. It could be concluded that antioxidants played an important role in enhancing the compatibility between PP and C18-MMT. According to the real time X-ray diffraction, the nanocomposite showed the weak ordering of PP crystals than the unfilled PP in the load-extension plateau region of elongation. 相似文献
992.
Yehoon Kim Seungjoo Haam Woo-Sik Kim Kee-Kahb Koo 《Korean Journal of Chemical Engineering》2003,20(6):1111-1117
Crystallization of L-ornithine-L-aspartate (LOLA) by drowning out was performed for the production of the anhydrous form of
LOLA. The needle-like LOLA crystals were formed and spherically agglomerated during precipitation in a semibatch crystallizer.
The primary crystal size in the agglomerate remains unchanged after completion of the crystallization. Therefore, the agglomeration
process of primary crystals played an important role for controlling LOLA crystal size. The agglomeration of LOLA crystals
was governed by not only the physico-chemical parameters such as the temperature and feed concentration, but also the hydrodynamic
parameters such as agitation speed and feeding rate. The crystal size and the shape have been shown to be important factors
in product impurity and flowability. Thus, the optimum condition of LOLA crystallization process by drowning-out could be
obtained. 相似文献
993.
Jin Young Kim Hyun Suk Jung Kug Sun Hong 《Journal of the American Ceramic Society》2005,88(3):784-787
The influences of acetic acid addition to Mg-methoxide on the stability of the precursor and the crystallization behavior of sol–gel-derived MgO nano-powders and thin films were investigated using X-ray powder diffraction, transmission electron microscopy, Fourier-transformed infrared spectroscopy, and thermogravimetry. The addition of acetic acid enhanced the stability of the alkoxide against precipitation. Moreover, during postheat treatment of the gel powders treated with acetic acid, a significantly lowered crystallization temperature (250°C) was observed as compared to the untreated counterpart (350°C). The low-temperature crystallization of MgO, induced by the modification of Mg-methoxide with acetic acid, was related to the decomposition of organics at a lower temperature. These results could be explained in terms of the decrease of the O–R bond strength depending on the increase in the alkyl group size. MgO thin films having a high degree of crystallinity were successfully obtained from the Mg-methoxide treated with acetic acid at 300°C. The low-temperature crystallization of sol–gel-derived MgO thin films showed the feasibility for their application as a protective layer in alternative current plasma display panel cells. 相似文献
994.
Kee Man LeeTae Kwon Kim Won Jin KimSeung Gon Kim Jeong Park Sang In Keel 《Fuel》2002,81(17):2249-2255
A visualization study on the effect of forcing amplitude in tone-excited jet diffusion flames has been conducted. Visualization techniques are employed using optical schemes, which are a light scattering photography. Flame stability curve is attained according to Reynolds number and forcing amplitude at a fuel tube resonant frequency. Flame behavior is globally grouped into two from attached flame to blown-out flame according to forcing amplitude; one sticks the tradition flame behavior which has been observed in general jet diffusion flames and the other shows a variety of flame modes such as the flame of a feeble forcing amplitude where traditionally well-organized vortex motion evolves, a fat flame, an elongated flame, and an in-burning flame. Particular attention is focused on an elongation flame, which is associated with a turnabout phenomenon of vortex motion, and on a reversal of the direction of vortex roll-up. It is found that the flame length with forcing amplitude is the direct outcome of the evolution process of the formed inner flow structure. Especially the negative part of the acoustic cycle under the influence of a strong positive pressure gradient causes the shapes of the fuel stem and fuel branch part and even the direction of vortex roll-up to dramatically change. 相似文献
995.
Blends of poly(ethylene 2,6-naphthalate) (PEN) and a liquid crystalline copolyester (LCP), poly(benzoate-naphthoate), were prepared in a twin-screw extruder. Specimens for mechanical testing were prepared by injection molding. The morphology and mechanical properties were investigated by scanning electron microscopy (SEM) and an Instron tensile tester. SEM studies revealed that finely dispersed spherical domains of the liquid crystalline polymer (LCP) were formed in the PEN matrix, and the inclusions were deformed into fibrils from the spherical droplets with increasing LCP content. The morphology of the blends was found to be affected by their composition and a distinct skin-core morphology was found to develop in the injection molded samples of these blends. Mechanical properties were improved with increasing LCP content, and synergistic effects have been observed at 70 wt% LCP content whereas the elongation at break was found to be reduced drastically above 10 wt% of LCP content. This is a characteristic typical of chopped-fiber-filled composites. The improvement in mechanical properties is likely due to the reinforcement of the PEN matrix by the fibrous LCP phase as observed by scanning electron microscopy. The tensile and modulus mechanical behavior of the LCP/PEN blends was very similar to those of the polymeric composite, and the tensile strength and flexural modulus of the LCP/PEN 70/30 blend were two times the value of PEN homopolymer and exceeded those of pure LCP, suggesting LCP acts as a reinforcing agent in the blends. 相似文献
996.
Kwang Ho Kim Soo Won Lee Dong Won Shin Chan Gyung Park 《Journal of the American Ceramic Society》1994,77(4):915-921
Antimony-doped tin oxide films were prepared on Corning glass substrate by chemical vapor deposition from a gas mixture of SnCl4 –SbCl5 –H2 O. The electrical conductivity and optical transmission of tin oxide films were studied with antimony doping. The film conductivity increased largely without losing optical transparency with a small addition of antimony. The increase of the conductivity was attributed mainly to more electrons donated by pentavalent Sb ions in the SnO2 lattice. Large additions of antimony, however, diminished the conductivity, optical transparency, and crystallinity of the film. The diminution was found to be caused by fine Sb2 O5 phases codeposited with SnO2 . 相似文献
997.
The photodegradation of polyesters prepared by the reaction of o-phthalic, adipic, and “dimer” acids with ethylene glycol has been studied. The polyesters softened at temperatures in the range of 25–50°C. Polymer films were irradiated in air by means of a medium pressure mercury lamp and the extent of formation of COOH groups determined by infrared spectroscopy. The films were also irradiated in vacuo and in air by means of a high-pressure mercury lamp, and the volatile products, consisting mainly of carbon monoxide and carbon dioxide, were determined by gas chromatography. The results are interpreted in terms of simultaneous Norrish type I and type II decompositions of the polyesters. The type I process accounts for the formation of carbon monoxide and carbon dioxide in the absence of air. The enhanced yield of carbon dioxide in irradiations performed in air is ascribed to the formation of hydroperoxide which undergoes further photolysis. The type II process accounts for the formation of COOH groups. The photodegradation of these glassy polyesters parallels that of crystalline poly(ethylene terephthalate) and is relatively unaffected by changes in composition of the aromatic polyester. 相似文献
998.
Z. A. Mohd Ishak P. Y. Wan P. L. Wong Z. Ahmad U. S. Ishiaku J. Karger‐Kocsis 《应用聚合物科学杂志》2002,84(12):2265-2276
Hygrothermally decomposed polyurethane (HD‐PUR) was mixed up to 20 phr in epoxidized natural rubber (with 50 mol % epoxidation; ENR50) recipes, and the curing and mechanical behaviors were studied. Mechanical testing of the ENR50/HD‐PUR vulcanizates determined the tensile, tear, compression‐set, hardness, abrasion, hysteresis, and resilience properties. No significant changes were observed in the tensile properties with the incorporation of HD‐PUR. The ENR50 compounds showed an increase in compression set with increasing HD‐PUR content. Rubbers cured by a semi‐efficient vulcanization system gave the best overall performance. A further improvement in curing and mechanical properties was achieved by the carbon black grade N330 being replaced with a more active grade (N375). © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 2265–2276, 2002 相似文献
999.
Composites of silicon carbide (SiC) with up to 30 vol% of dysprosia (Dy2 O3 ) were fabricated by hot pressing and hot isostatic pressing. The effects of Dy2 O3 dispersions on the microstructure and on selected mechanical properties of the composites were investigated. When 10-15 vol% of Dy2 O3 was dispersed in the SiC matrix, the fracture toughness increased by ∼40%, whereas the flexural strength was comparable to that of unreinforced SiC. The increased fracture toughness was due to crack deflection, in conjunction with crack-interface grain bridging, and was not related to a phase transformation of Dy2 O3 in the matrix. 相似文献
1000.
Hydrogen sulfide gas was removed in a 2-dimensional gas-lift reactor by the photosynthetic microorganismChlorobium thiosulfatophilum using light emitting diodes (LEDs) as a light source. LEDs saved light energy by 99% compared with the incandescent light
source. The plate-type gas-lift reactor removed hydrogen sulfide five times better per unit mg of protein, and performed two
times better in the maximum performance per unit luminous flux, compared with cylindrical fermentors. 相似文献