Facile solvothermal synthesis and photoconductivity of one-dimensional organic Cd(Ⅱ)-Schiff-base nanoribbons

One-dimensional (1D) organic nanoribbons built on N-p-nitrophenylsalicylaldimine cadmium complex were synthesized via a facile solvothermal route. Scanning electron microscope images revealed that the as-synthesized products were ribbon like with widths of 500 nm,thicknesses of about 50nm, and lengthes up to several hundred micrometers. Fourier transform infrared spectrum was employed to characterize the structure. The conductivity of a bundle of nanoribbons was also measured,which showed that Schiff base cadmium nanoribbons had good photoconductive property. This work might enrich organic photoconductive materials and be applicable in nano photoswitch devices in the future.     

指向标识设置间距及设置位置对路效率影响的虚拟研究

为研究在有岔道口的通道上标识设置对行人寻路效率的影响,本文利用Quest3D软件构建虚拟空间,在虚拟空间中对上述问题展开实验研究.通过分组实验的方式,让不同组的实验者在不同标识设置参数的虚拟空间中行走,并采集实验者的实验数据,实验数据显示当标识间距大于50m时或者标识缺失而不远处有类似标识影响时寻路效率会明显下降.因此在有岔道口的通道上标识的设置距离应当小于50m,同时合理设置标识位置,防止与寻路无关的类似标识进入行人视线.     

基于轨迹模式空间解耦及模式能量序列的振荡分析(三)时变性分辨率从摆次细化到时间断面

系列文章的前两篇以振荡模式的空间解耦代替频域解耦,并通过互补群模式的摆次能量演化来反映复杂振荡行为的特征。由于其对时变性的分辨率较低,也不利于讨论多模式之间的交互作用,故文中提出在每个积分步末端所对应的时间断面处,按实际变量值重新冻结映象系统的非哈密顿因素,按虚构的哈密顿系统来估计该断面后的不平衡功率-转角的曲线。进而评估各互补群模式的振荡总能量(或其裕度)的时间序列,将轨迹振荡能量序列分析方法的时间分辨率从按模式摆次细化为按积分步长,更好地反映振荡的局部时变性。针对分别计及调速器或计及机械功率周期性扰动的两个算例,揭示了系统“反常”振荡行为的机理。     

Recrystallization Behavior of Deformed Austenite in High Strength Microalloyed Pipeline Steel

 Using methods of single hit hot compression and stress relaxation after deformation on a Gleeble 1500D thermomechanical simulator, the curves of flow stress and stress relaxation, the microstructure and the recrystallization behavior of Nb V Ti high strength microalloyed low carbon pipeline steel were studied, and the influence of the thermomechanical treatment parameters on dynamic and static recrystallization of the steel was investigated. It was found that microalloying elements improved the deformation activation energy and produced a retardation of the recrystallization due to the solid solution and precipitation pinning. The deformation conditions such as deformation temperature, strain, and strain rate influenced the recrystallization kinetics and the microstructure respectively. Equations obtained can be used to valuate and predict the dynamic and static recrystallizations.     

看谱定性分析技术在铜合金中的应用

看谱定性分析与摄谱定性分析相比,其优点是简单而迅速,分析灵敏度约为0.01%～0.1%,对样品损伤小,具有设备轻便,便于搬运等特点,适用于确定某种合金的某种元素有否,对试样进行初步分析和按牌号把金属及合金进行分类分析,特别是适用于对大型工件或精密机件进行非破坏的现场分析。     

Separation of Particles From Molten Aluminum With High Frequency Electromagnetic Field

The currentstudy is to investigate the separation of non-metallic inclusions from molten aluminum with 53-63kHz high frequency electromagnetic filed.In the experiments,aAl-SiC composite material-pure aluminum with a certain amount of dispersed SiC particles with 10-20μm diameter-was used.Both laboratory experiments and numerical simulation were performed.It was observed that SiC particles were pushed to the boundary layer of the aluminum close to the wall of the crucible,and the thickness of the particle layer was approximately 1.0-1.5 mm and the area fraction of the particle layer was 9-15%of the entire horizontal cross section area.With separation time going on,the accumulation layer became thinner,and the accumulation layer density became higher.The numerical simulation indicated that the magnetic flux density is larger at top and bottom than other locations and very small at the center of the crucible,and the EM force mainly acted on the outside 0.004 m layer of the melt due to the effect of the skin effect.There were recirculation eddies at the top and bottom and close to the corner where the EM force was the largest.The speed of the flow was 11-13 mm/s at the corner of the top and bottom and was as small as 1 mm/s at the center of the crucible.Both the numerical simulation and the experimental observation showed that the top free surface was not flat,approximately 1.0 mm high at the center of the top surface by numerical simulation and 4.0 mm by the experimental observation.More particles were entrapped at the lower part of the crucible.     

国产HW2000型高频红外碳硫仪分析精度探讨

对国产HW2000型高频红外碳硫仪的分析精度进行了测定,并与进口EMIA-620型高频红外碳硫仪进行了比较,结果表明,HW2000型红外仪的检出限低(0.000 03％).对3种标准样品的分析,HW2000型红外仪分析的碳的RSD为0.000 59％～ 1.630 25％,硫的RSD为0.012 67％ ～ 0.513 20％:而EMIA-620型分析的碳的RSD为0.206 64％～ 1.724 17％,硫的RSD为0.025 30％～0.939 15％.而且HW2000型红外仪有较好的分析线性.     

人来人往此处非驿站

近几个月国内国际经济形势沉闷,大家都在打听这种局面何时可以结束,未来经济发展的方向在哪里,但似乎谁又都难以回答这个问题。而由许多失望的人们正在主要资本主义国家发起的＂占领华盛顿＂、＂占领伦敦＂、     

悬挂式接管焊接机器人机电系统

针对接管相贯线处的焊接特点,研发了悬挂式接管焊接机器人,介绍了机械结构特点和适用性.控制系统采用工业PC作为主控计算机和PMAC多轴控制卡进行多轴控制,利用二级控制结构实现作业管理,协调各轴运动完成焊接作业.进行了在筒体上外接管和内接管的焊接试验与在椭球体上外接管与内接管的焊接试验.结果表明,机器人的机械本体结构和控制系统能够实现多种接管的焊接需求,能够很好地完成接管相贯线处的焊接,提高了工作效率和焊接质量.