Hydrolytic degradation of oligo(lactic acid): a kinetic and mechanistic study

This study shows that the degradation mechanism and kinetics of monodisperse oligo(lactic acid)s esterified with N-(2-hydroxypropyl)methacrylamide (HPMAm) are strongly influenced by the nature of the chain end. Oligomers with free hydroxyl chain ends degraded predominantly by chain end scission via a backbiting mechanism with a pseudo first-order rate constant k_bb=2.7 h⁻¹ in aqueous buffer (37 °C, pH 7.2). Once the hydroxyl groups were protected by acetylation, random chain scission became the rate limiting step with k_r=0.022 h⁻¹ under the same conditions. Using these rate constants, the theoretical time-resolved degradation profile was calculated for every (intermediate) degradation product and corresponded very well with the experimental results. The rate of formation of HPMAm was independent of the chain length for the acetylated oligomers, while the hydroxyl terminated oligomers with an even number of lactic acid units formed HPMAm more rapidly than oligomers with an odd number of units. The possibility to fine-tune the degradation rate is relevant when applied as e.g. hydrogels for controlled release or tissue engineering materials.     

A bottom-up assessment and review of global bio-energy potentials to 2050

In this article, a model for estimating bioenergy production potentials in 2050, called the Quickscan model, is presented. In addition, a review of existing studies is carried out, using results from the Quickscan model as a starting point. The Quickscan model uses a bottom-up approach and its development is based on an evaluation of data and studies on relevant factors such as population growth, per capita food consumption and the efficiency of food production. Three types of biomass energy sources are included: dedicated bioenergy crops, agricultural and forestry residues and waste, and forest growth. The bioenergy potential in a region is limited by various factors, such as the demand for food, industrial roundwood, traditional woodfuel, and the need to maintain existing forests for the protection of biodiversity. Special attention is given to the technical potential to reduce the area of land needed for food production by increasing the efficiency of food production. Thus, only the surplus area of agricultural land is included as a source for bioenergy crop production. A reference scenario was composed to analyze the demand for food. Four levels of advancement of agricultural technology in the year 2050 were assumed that vary with respect to the efficiency of food production. Results indicated that the application of very efficient agricultural systems combined with the geographic optimization of land use patterns could reduce the area of land needed to cover the global food demand in 2050 by as much as 72% of the present area. A key factor was the area of land suitable for crop production, but that is presently used for permanent grazing. Another key factor is the efficiency of the production of animal products. The bioenergy potential on surplus agricultural land (i.e. land not needed for the production of food and feed) equaled 215–1272 EJ yr⁻¹, depending on the level of advancement of agricultural technology. The bulk of this potential is found in South America and Caribbean (47–221 EJ yr⁻¹), sub-Saharan Africa (31–317 EJ yr⁻¹) and the C.I.S. and Baltic States (45–199 EJ yr⁻¹). Also Oceania and North America had considerable potentials: 20–174 and 38–102 EJ yr⁻¹, respectively. However, realization of these (technical) potentials requires significant increases in the efficiency of food production, whereby the most robust potential is found in the C.I.S. and Baltic States and East Europe. Existing scenario studies indicated that such increases in productivity may be unrealistically high, although these studies generally excluded the impact of large scale bioenergy crop production. The global potential of bioenergy production from agricultural and forestry residues and wastes was calculated to be 76–96 EJ yr⁻¹ in the year 2050. The potential of bioenergy production from surplus forest growth (forest growth not required for the production of industrial roundwood and traditional woodfuel) was calculated to be 74 EJ yr⁻¹ in the year 2050.     

Peak loads and network investments in sustainable energy transitions

Current energy distribution networks are often not equipped for facilitating expected sustainable transitions. Major concerns for future electricity networks are the possibility of peak load increases and the expected growth of decentralized energy generation. In this article, we focus on peak load increases; the effects of possible future developments on peak loads are studied, together with the consequences for the network. The city of Eindhoven (the Netherlands) is used as reference city, for which a scenario is developed in which the assumed future developments adversely influence the maximum peak loads on the network. In this scenario, the total electricity peak load in Eindhoven is expected to increase from 198 MVA in 2009 to 591–633 MVA in 2040. The necessary investments for facilitating the expected increased peak loads are estimated at 305–375 million Euros. Based upon these projections, it is advocated that – contrary to current Dutch policy – choices regarding sustainable transitions should be made from the viewpoint of integral energy systems, evaluating economic implications of changes to generation, grid development, and consumption. Recently applied and finished policies on energy demand reduction showed to be effective; however, additional and connecting policies on energy generation and distribution should be considered on short term.     

A Fuel Economy Study in Heavy Duty Diesel Engine Lubricants

Internal combustion engines′ fuel economy is an important role for engine designers,engine manufacturers over the past 30 years,especially passenger car motor oils.In heavy duty diesel engine,over the past 20 years,fuel economy has in some cases been sacrificed for exhaust gas emission optimizations.Now,Heavy Duty Automotive and the related industries have strong interest in fuel economy and the lubricants.It is driven by competitive market forces as well as government mandates and new emission regulations.Japan was the first country in the world to establish and implement heavy duty trucks and buses fuel economy standards.Other countries also have followed either by establishing direct fuel economy standards or greenhouse gas(GHG) emissions standards which are directly tied to fuel economy.This paper is discussing that heavy duty diesel engine lubricants can contribute on fuel economy.The contribution of various aspects of engine oil formulations on fuel economy will be discussed such as lubricant viscosity grade,lubricant additives and friction modifiers.In this paper,the evaluation discussions are based on fuel economy measurements in some bench tests,standardized laboratory engine tests and field tests.     

Improved passive-matrix multiplexability with a modular display and UTCP technology

One of the major problems with PM displays is that, depending on the used display material, only a limited number of lines can be multiplexed. We developed a new driving technology and display setup that takes care of that problem. We divided the display into several independent parts or modules. Each module acts as an individual display and has its own display driver. With the use of the new ultra-thin chip package (UTCP), these driver chips can be embedded into the (flexible) display itself. This paper explains the setup of the fully modular display and describes the basic structure of the display drivers and its components.     

A longitudinal study of children’s performance on simple multiplication and division problems.

The authors investigated the performance on simple multiplication and division problems of 8-year-old children longitudinally to determine the developmental trajectories of both operations. Twice a year, during 2 consecutive school years, children performed a multiplication and division verification task and a number-matching task. All effects that were observed in multiplication performance (problem size, 5, and tie effect and Tie × Size interaction) were also observed in division performance. The developmental trajectories of these effects are described. The authors observed strong developmental parallels between both operations. These results are in line with strongly interconnected memory networks for multiplication and division facts, at least in young children. The results of the number-matching task showed that the interference effect developed differently for multiplication and division, indicating that automatic activation spreading from division operands to division answers is not at work in children of that age. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

In the eye of the beholder: Perceived, actual, and peer-rated similarity in personality, communication, and friendship intensity during the acquaintanceship process.

The authors examined associations of perceived similarity, actual similarity, and peer-rated similarity in personality with friendship intensity during the acquaintanceship process in a naturalistic setting. Self- and peer-rated personality data were gathered from undergraduates (mean age = 18.9) at 5 time points during the first year of university using a round-robin design. Whereas perceived similarity and peer-rated similarity in personality were concurrently associated with more friendship intensity for just-acquainted individuals, actual similarity in personality was not. Further, bidirectional cross-lagged associations between perceived similarity and friendship intensity were found. Peer-rated similarity was also associated with increases in friendship intensity, and this association was mediated by communication frequency. These results indicate that specific types of similarity in personality are differentially associated with friendship intensity during early phases of acquaintanceship in a real-life setting. Further, insight was provided in the direction of causality between similarity and attraction: Perceived and peer-rated similarity seem to breed friendship intensity, whereas friendship intensity seems to breed perceived similarity only. Finally, peers’ expectations seem to affect individuals’ communicative behaviors, which in turn affect friendship formation. (PsycINFO Database Record (c) 2010 APA, all rights reserved)