Electrochemical properties of some cobalt antimonides as anode materi-als for lithium- ion batteries

Some cobalt antimonides have been prepared and studied as the candidate anode materials for lithium ion batter-ies. Reversible capacities of 424,423 and 546 mA·h·g-1 were measured at the first cycle for as-solidified CoSb2, CoSb3 and annealed CoSb3 respectively. A low lithium ions diffusion coefficient in the order of 10-16 m2·s-1 was estimated from the coulometric titration measurements in the annealed CoSb3 electrode. It was found that the electrochemical properties of fine powders are significantly better than coarse powders. However the SEM picture shows that the nano-sized CoSb3 powders gathered to larger granules, which worsens somewhat the capacity retention of the nano-sized materials, although the volume capacities of the annealed and ball milled CoSb3 remain near twice of that of graphite after 50 cycles.     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.     

IDEF0法建立模具CAD／CAM系统的功能模型

本文阐述了 IDEFO 法建立系统功能模型的步骤、方法和意义,IDEFO 法是一种结构化的系统分析方法,最后用一个简单实例加以说明。     

双端制动器惯性试验台的设计

随着我国汽车工业的迅猛发展,汽车产量不断增多,车速越来越高,对汽车制动性能要求也越来越高。汽车制动器是汽车上的重要设备,其质量的好坏影响着行车的安全。电惯量模拟是近几年兴起的一种比较先进的负载模拟方法,文章就制动器惯性试验台系统结构以及电惯量模拟的方法进行了比较详细的说明。     

Effect of grain size on high-temperature oxidation behavior of Cu-80Ni alloy

1　INTRODUCTIONTheoxidationofunalloyedcopperandnickelhasalreadybeenstudiedindetail.Whilethehigh tem peratureoxidationofCu Nialloys ,alsostudiedanumberoftimestodate[13] ,isanexampleofarela tivelysimpleclassofscalingofbinaryalloysbyasin gleoxidant,becausethemetalsformacontinuousse riesofsolidsolutions ,whiletheiroxides ,CuO ,Cu2 OandNiO ,exhibitsmallmutualsolubilitiesandshowsignificantdifferencesinthethermodynamicstabilityandparabolicgrowthrates .Thus ,copper richalloysformexternalscales…     

CA6140车床数控改造中机械装置设计技巧

介绍了普通车床数控改造中机械装置的几个独特设计，使得数控车床纵向进给系统结构更简单、性能更可靠、装拆更方便。     

钻柄温挤成形及模具设计

介绍了钻柄温挤成形工艺及其模具设计。     

汽车用磁性材料和磁性器件

汽车前灯装置用的磁性材料为了减少汽车夜间行驶的交通事故,一个重要的办法就是提高驾驶员的眼睛的夜间辨认能力,这就要在汽车上安装高亮度前灯（High Intensity Dischrge Lamp,简写为HID灯）,这种灯较传统用的卤灯省电且更亮,这样驾驶员就能借助它容易发现路面障碍物.HID灯是水银灯、金属卤化物灯、高压钠灯的统称.其中金属卤化物灯用作汽车前灯有2个缺点：①从点灯至达到规定亮度需数分至数十分钟;②一旦灯灭,再点着也必需数分至数十分钟.为克服这两点缺点在其点灯电路中必须设置变换器和触发器.     

一种基于RGV、AGV的柔性输送系统

随着现代制造业的迅速发展,我国的物流行业也随之崛起,并且逐渐受到全社会的广泛关注。早期的人工物流、机械化物流方式,已经远远不能满足现在大规模生产流水线的需求。本文提出了一种基于RGV、AGV的柔性输送系统,其中环形RGV输送系统通过成对的码头和码头之间的流水线与AGV输送系统、非环形往复式RGV输送系统相接驳;AGV输送系统和非环形往复式RGV输送系统用于将物流货品从环形RGV输送系统送入或送出指定物流系统。该系统有效地克服传统单一RGV输送系统对使用场所的适应性差、轨道占用空间大等缺点,同时避免使用单一AGV输送系统带来的输送效率较低、设备及维护成本较高等问题。