Unique role of non-mercapto groups in thiol-pinning-mediated Ag growth on Au nanoparticles

Owing to the strong affinity of thiols to Au and Ag, they are often employed to modify the surfaces of nanoparticles (NPs). Recently, these strong ligand-interface interactions have been employed to control NP growth, and this technique has emerged as a unique modulation strategy for creating unconventional plasmonic hybrid nanostructures. In these systems, the roles of the non-mercapto components of the thiol molecules and their structures are still unknown. Therefore, we herein present our investigation into this phenomenon. Primary amino (–NH₂) groups in thiols are found to play a key role in regulating growth kinetics, i.e., in accelerating Ag deposition on Au NPs. The–NH₂ groups are thought to bring Ag ions to the particle surface by coordinating to them, and thereby assist their reduction. The effect of molecular structure is non-trivial and thus provides the possibility of selective thiol detection. Based on the dependence of kinetic modulation on the non-mercapto components and molecular structures of molecules, we demonstrate the highly sensitive and specific detection of cysteine (limit of detection: 6 nM) in a mixture of 19 natural amino acids based on Ag growth on Au nanospheres. In addition, based on this modulation effect, we reveal the entrapping of chiral thiols within the growth layer through their plasmonic circular dichroism (PCD) responses. We believe that thiol-based growth regulation has great potential for creating plasmonic nanostructures with novel functionalities.

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Existence results for impulsive differential inclusions with nonlocal conditions

In this paper, we shall establish sufficient conditions for the existence of mild solutions for nonlocal impulsive differential inclusions. On the basis of the fixed point theorems for multivalued maps and the technique of approximate solutions, new results are obtained. Examples are also provided to illustrate our results.     

基于约简SVM的网络入侵检测模型

支持向量的数量越大,基于SVM的网络入侵检测系统速度越慢。针对该问题提出一种新的SVM约简方法,在特征空间中对支持向量进行聚类,寻找聚类质心在输入空间中的原像,将其作为约简向量,以实现支持向量削减目的。实验结果证明,该方法能提高SVM入侵检测引擎的速度,增强入侵检测系统的实时响应能力。     

Consensus of multiple Euler-Lagrange systems using one Euler-Lagrange System’s velocity measurements

International Journal of Control, Automation and Systems - This brief paper studies the stationary consensus of multiple Euler-Lagrange systems with nonlinear protocols. Two consensus protocols are...     

Parameterized complexity of coloring problems: Treewidth versus vertex cover

We compare the fixed parameter complexity of various variants of coloring problems (including List Coloring, Precoloring Extension, Equitable Coloring, L(p,1)-Labeling and Channel Assignment) when parameterized by treewidth and by vertex cover number. In most (but not all) cases we conclude that parametrization by the vertex cover number provides a significant drop in the complexity of the problems.     

大纯滞后过程的采样控制及其工程实现中的若干问题

提出了采样控制机制的新观点,介绍控制器参数确定的新方法,分析了采样控制的质量,指出了在工程实施应考虑的若干问题。     

PC机与多单片机组成串行通信的新尝试

以实际应用的小型集散变频调速系统为例 ,介绍一种PC机与多AT89C2 0 51单片机之间串行通信的接口电路 ,并提出一种新的通信方法 ,即采用QBASIC语言提供通信语句来编写多机通信程序。该方法硬件紧凑 ,软件编程简单可靠。     

Performance lower bounds in stochastic robust and adaptive control

The fundamental issues of capability of robust and adaptive control in dealing with uncertainty are investigated in stochastic systems. It is revealed that to capture the intrinsic limitations of adaptive control, it is necessary to use sup_t types of transient and persistent performance, rather than lim sup_t types which reflect only asymptotic behavior of a system. For clarity and technical tractability, a simple first-order linear time-varying system is employed as a vehicle to explore performance lower bounds of robust and adaptive control. Optimal performances of nominal, robust and adaptive control are explicitly derived and their implications are discussed in an information framework. An adaptive strategy is scrutinized for its achievable performance bounds. The results indicate that intimate interaction and inherent conflict between identification and control result in a certain performance lower bound which does not approach the nominal performance even when the system varies very slowly. Explicit lower bounds are obtained when disturbances are either normally or uniformly distributed     

Synthesis of Single-Crystalline Silicon Nitride Nanobelts Via Catalyst-Assisted Pyrolysis of a Polysilazane

Recently, one-dimensional nanostructures have attracted extensive attention since they are potentially important for both applications and fundamental research. In this paper, we report the synthesis of ultra-long single crystal Si₃N₄ nanobelts via catalyst-assisted pyrolysis of polymeric precursors. The obtained products contain both α- and β-Si₃N₄ nanobelts, which are 50–100 nm in thickness, 400–1000 nm in width, and a few hundreds of micrometers to several millimeters in length. Different from previous techniques for synthesizing one-dimensional structures, the current nanobelts are synthesized through confined crystallization of an amorphous phase. A solid–liquid–gas–solid reaction/crystallization growth mechanism is proposed. The formation of nanobelts instead of nanowires is attributed to the anisotropy growth at an earlier stage.