Novel blood-compatible waterborne polyurethane using chitosan as an extender

A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, M_n = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (M_n = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Preparation of branched polyacrylonitrile through self‐condensing vinyl copolymerization

Branched polyacrylonitrile (PAN) was prepared through a self‐condensing vinyl copolymerization of acrylonitrile and 2‐(2‐bromopropionyloxy)ethyl acrylate (BPEA). The branched architecture of the product was confirmed by NMR spectra and the average degree of branching (DB ) was estimated. Through a comparison of the intrinsic viscosity of the product with that of its linear analogue, the contraction factor g′ was calculated. It was found that the viscosity of the branched PAN was obviously lower that that of linear PAN. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Viscoelastic properties of polyarylene ether nitriles/thermotropic liquid crystalline polymer blend

Polyarylene ether nitriles (PEN)/thermotropic liquid crystalline polymer (TLCP) blend was prepared via melt mixing. The immiscible phase morphologies, linear and nonlinear, as well as transient viscoelastic properties of the blend were studied using SEM, rheometer, and DMA. The linear dynamic viscoelastic behavior of the blend shows temperature dependence due to further evolution of the immiscible morphology and, as a result, the principle of time‐temperature superposition (TTS) is invalid. In the steady shear flow, the discrete TLCP phase is difficult to be broken up because of the high viscosity ratio of the blend systems, while is easy to be coarsened and followed by elongation, and finally, to form fibrous morphology at high TLCP content and high shear level. During this morphological evolution process, the transient stress response presents step increase and nonzero residual relaxation behavior, leading to increase of the dynamic viscoelastic responses after steady preshear. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

管线油电损耗的灰色模型及预测

对于管道运输来说，影响输油成本变化的因素有很多，但是对总成本影响最大的是油电损耗费用。由于来自现场的输量和相关参数样本数据不足，只知道连续几年的流量、油电损耗，要预测将来每年的油电损耗，经典经济数学不能满足这样的研究。然而灰色系统理论要求的研究样本较少，只要知道连续几年的流量、油电损耗，就能预测将来每年的油电损耗，估算其输油成本，且模型精度较高。利用灰色系统理论，以输油管线每年的输量、相应的电耗和油耗为时间序列，建立了三元素非等间距GM(1，1)模型，该模型为预测管线年输油成本提供了可靠的依据。     

CO毒化AB5型合金分形特征研究

研究了三种贮氢合金 L a Ni5、L a Ni4 .7Al0 .3、Ml Ni4 .5Al0 .5被 10 0× 10 - 6 CO毒化后的分形特征 ,求出这三种合金在含 10 0× 10 - 6 CO的氢中循环 ,分维分别为 0 .2 5 4 7、0 .170 9、0 .0 72 5。可以较好的解释合金被毒化的宏观现象。     

二次电池电极基板用复合多孔金属材料的研究

介绍了一种复合金属多孔体的制备及其方法，首先以泡沫塑料为芯膜，经过导电化处理使其具有导电性，其次进行电沉积金属铁，再进行电沉积金属镍，经过热处理后可制备出复合金属多孔体。该复合金属多孔体用铁取代金属镍，其抗拉性能优于单质泡沫镍，同时可以降低制造成本，主要用于载体如电池电极。     

水平管路清管过程流动参数变化规律模拟研究

混输管路清管技术的研究对混输管道的运行管理具有非常重要的意义。在分析清管器清管物理模型的基础上 ,建立清管器的特征参数计算模型、动态数学模型和数值计算方法 ,并进行数值模拟 ,计算出测压点压力随时间变化的数据 ,并把它们与试验数据进行比较 ,得到清管过程中压力的变化规律。通过数学模拟 ,可以计算清管过程中管道的压力分布状况 ,利用压力分布状况就可跟踪清管球在管道内的运行情况     

Water bamboo husk reinforced poly(lactic acid) green composites

The water bamboo husk is one of major agricultural wastes in Taiwan. In this study, the powder obtained from the water bamboo husk was added to poly(lactic acid) (PLA) to form novel reinforced biodegradable composites. Morphologies, mechanical properties, and heat resistance of these water bamboo powder reinforced composites were investigated. The results indicate that the char yields were increased as plant powder was incorporated to PLA. In addition, the mechanical properties were also enhanced due to the addition of powders. The increments of storage moduli of PLA were about 50–200%. Moreover, the increments of loss moduli of PLA were about 70–200%. On the other hand, the T_g of PLA was slightly decreased by the addition of powder, and this may improve the brittle characteristics of PLA. Furthermore, this type of reinforced PLA would be more environmental friendly than the artificial additive‐reinforced one. POLYM. ENG. SCI., 2008. © 2008 Society of Plastics Engineers     

略谈政府垄断土地一级市场的问题和对策

政府垄断土地一级市场要强化对土地市场的监管、规范和垄断 ;完善土地市场机制 ,发挥市场配置土地资源的基础性作用     

地方热电联产企业发展对策的探讨

介绍了泰州热电企业的运行情况，分析了各热电厂在技术改造、扩大热用户和强化内部考核管理方面的措施，探讨了地方热电企业应采取的对策和发展思路。