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人类居住健康的问题越来越受到全世界居住者和舆论的关注.长期以来人类过于不当的城市建设行为,人口的过于集中,城市建筑的高层化倾向,过分的人造环境造成土地失水性严重、热岛现象衍生.城市作为人类居住生活的功能区,在很大程度上被削弱,居住条件恶化、环境受到污染.让城市功能朝着人居、健康的目标发展,包括生理和心理的、社会的和人文的、近期的和长期的多层次的健康,是我们今天的历史责任.     

Highly Efficient Orange and Green Solid‐State Light‐Emitting Electrochemical Cells Based on Cationic IrIII Complexes with Enhanced Steric Hindrance

Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂ sb]PF₆ in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W^–1) at 2.5 V, and 7.1 % and 26.2 lm W^–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells.     

Effect of Synergistic Anticorrosion Treatments on Cycling Stability of Mg-Based Hydrogen Storage Electrode

In this paper, any two of the three anticorrosion agents, that is emulsifier (OP-10), soluble glass (Na2O·nSiO2) and glycerin (C3H8O3), were treated simultaneously on the surface of amorphous (a-) MgNi+5% Ml2Mg17 (Ml denotes the lanthanum-rich mish metal) electrode and the electrolyte. Effect of the synergistic anticorrosion treatment on charging/discharging cycle stability of the electrode was investigated. Contrasted with single treatment method, the cycling stability of the electrodes was further improved. The desirable synergistic anticorrosion method was that the electrode was treated by the soluble glass, and that OP-10 was added into the electrolyte. The cyclic voltammogram (CV) results of the electrode show clearly that the anticorrosion agent can change the electrochemical activity and mechanism of the electrode. The concentration of the anticorrosion agent in the electrolyte treated by the synergistic anticorrosion method was also investigated. The appropriate concentration of the anticorrosion agents in the electrolyte is 0.143%.     

A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry     

烯烃聚合单活性中心非茂催化剂的最新研究进展

综述了近几年来烯烃聚合用单活性中心非茂催化剂的研究进展。简要介绍了 2 3种由前、后过渡金属组成的配位化合物催化剂的结构与性能     

On exploring inter-iteration parallelism within rate-balanced multirate multidimensional DSP algorithms

Although the notion of the parallelism in multidimensional applications has existed for a long time, it is so far unknown what the bound (if any) of inter-iteration parallelism in multirate multidimensional digital signal processing (DSP) algorithms is, and whether the maximum inter-iteration parallelism can be achieved for arbitrary multirate data flow algorithms. This paper explores the bound of inter-iteration parallelism within rate-balanced multirate multidimensional DSP algorithms and proves that this parallelism can always be achieved in hardware system given the availability of a large number of processors and the interconnections between them.     

圆柱形破片形状系数研究

衰减系数直接关系到破片能否对目标进行有效的毁伤,而形状系数对衰减系数有很大的影响.当圆柱形破片在空中飞散时,迎风面积随机变化,导致圆柱形破片的形状系数不再是单一的值,而是一个范围,因此必须对已有的圆柱形破片的形状系数进行修正,才能更准确的预测圆柱形破片在空中的速度衰减.文中在试验的基础上,详细的对不同尺寸不同材质的圆柱形破片的形状系数进行了分析,并进行了修正,通过计算值与试验测得的数据进行比较,说明该修正系数可以应用于工程实践中.     

应用遗传神经网络研究低渗透储层成岩储集相—以胜利渤南油田三区沙河街组为例

以渤南油田三区沙河街组为例,应用遗传人工神经网络模式识别方法,开展了低渗透储层成岩储集相的研究。该工作是在储集层沉积相、成岩作用研究的基础上,选用流动层带指标、孔隙度、渗透率、粒度中值、泥质含量、孔喉半径均值和变异系数等7项参数,采用神经网络模式识别方法,通过建立遗传神经网络的学习及预测模型,对渤南油田三区沙河街组进行了成岩储集相识别,识别出4类成岩储集相:不稳定组分强溶解次生孔隙成岩储集相、碳酸盐胶结物溶解次生孔隙成岩储集相、强压实强胶结残余粒间孔成岩储集相和极强压实强胶结致密成岩储集相。Ⅰ类储集相的储集性能最好,Ⅳ类最差,为非储层或差储层。     

川西低渗气藏单井地应力计算方法综合研究

四川盆地新场气田是一个低孔低渗的裂缝性砂岩气田，储层物性差，自然产能低，需经压裂后才能投产，压裂后气井增加的产能与压裂的效果密切相关。提前认识储层当前地应力的特征，有助于压裂设计时确定裂缝产状、缝长、缝宽等参数，减少储层水力压裂改造的盲目性，降低中、低渗透油气田开发的风险。通过大量测井资料的计算，确定了新场气田储层地应力的大小和方向，并综合采用微地震测量、岩石声发射资料、古地磁等岩心测试资料和水力压裂等多种方法进行交互验证，各种方法求得的地应力特征十分相近，说明利用测井资料求取储集层地应力原理简单，计算结果符合实际的地应力特征，是一种低风险研究计算储层地应力特征的方法，可以用于指导低渗透油气田的井网部署和储层的单井压裂改造。     

Amorphous diffusion bonding of steel pipe and its impact toughness

An iron-based amorphous foil (FeNiCrSiB) was used as an interlayer for the amorphous diffusion bonding of low carbon steel pipes under argon flux. The microstructure and mechanical properties of the joint were analyzed using an electron probe micro-analyzer (EPMA), tensile test, bending test and impact test. The results show that the joint microstructure resembles that of the base metal and no precipitates form at the joint. Melting point depressants (B, Si) diffuse far away from the joint and the base metal element is homogenous across the joint. The joint impact toughness is greater than the base metal toughness and the mechanical properties of the joint are similar around the pipe.