Preparation and photochromism of nanocomposite thin film based on polyoxometalate and polyethyleneglycol

A photochromic nanocomposite based on Keggin structure phosphomolybdic acid (PMoA) well dispersed in polyethyleneglycol (PEG) was fabricated. TEM image showed that PMoA nanoparticles with narrow size distribution were finely dispersed in polymer matrix. FT-IR results showed that the Keggin geometry of polyoxometalates was still preserved inside the composites and strong coulombic interaction was built between PMoA and polymer matrix. Under UV irradiation, the film was reduced photochemically to yield a blue species, which was in accordance with a charge-transfer mechanism.     

浅议铵梯炸药质量检验中的三个问题

文章探讨了GB 12437-2000标准规定的产品检验项目中,中包浸水试验的科学性问题和对批产品进行抽样时的样本代表性问题以及使用多段爆速仪测试爆速时应注意的样本量问题.     

恒定水深拖拉铺管管线的三维大挠度静态应力分析

海洋管线具有复杂的工程结构,在恶劣的海洋环境中,承受着比陆地管线更为复杂的载荷。为了保证管线安全工作,需对其进行准确的应力分析。本文应用有限元法对恒定水深拖拉铺管的管线内力、应力及位移进行了计算,并将结果与已有的计算结果进行对比,进一步分析了各种海洋环境因素对管线弯曲效应的影响,取得了有一定实用性的成果,可供海洋拖拉铺管施工时参考。     

Optimal diagonal precoder for multiantenna communication systems

In this paper, we examine a multiantenna single-user wireless communication system fitted with a QR-based successive cancellation receiver (QR receiver). Initially, our consideration is confined to uncoded binary phase shift keying (BPSK) signals transmitted through independent and identically distributed (IID) Rayleigh fading channels and to the design of an optimum precoder for the transmitter. For minimum feeding back of the channel state information (CSI) to the transmitter from the receiver, we stipulate the precoder to be in the form of a power loading square diagonal matrix. We proceed to develop the theory for the design of this diagonal matrix based on the minimization of the lower bound of the average bit error rate (BER) of transmission. The design obtained provides substantially lower error rates than most of other existing schemes under the same environment. The corresponding gain in signal-to-noise ratio (SNR) can be several decibels. To further improve the performance, we extend the design to include an optimal detection order of the received bits using an iterative approach. This iterative process proves to have fast convergence and results in a design providing significant SNR gain. We also propose a subchannel dropping scheme for cases in which SNR is low, and when the minimum BER precoder is equipped with this scheme, its average performance can be substantially superior to the Vertical Bell Laboratories Layered Space-Time (V-BLAST) detection. We extend our design of the optimum precoder to quadrature amplitude modulation (QAM) modulation scheme and similar performance gain has been observed.     

台州市"20020913"特大暴雨洪水分析及思考

2002年9月13-14日，台州市受18号强热带风暴“黑格比”减弱后的低压环流的外围影响，台州温岭-路桥-黄岩-杜桥-线普降大到特大暴雨，灾情严重。这场暴雨的特征是历时短、强度高、笼罩面积小，是台州历史上罕见的平原大暴雨。通过对这场暴雨洪水特性和水利工程所发挥作用的分析，揭示暴雨的成因和特性，提出几点思考。     

未增塑聚氯乙烯(PVC-U)异型材配方基础

PVC-U异型材配方十分复杂,常用原料通常在10种以上。根据大连实德集团实际生产情况,这10多种原料通常以7大组分的方式进行配料和生产。文中就该配方中7大组分的分类、特点及应用情况分别进行了详细介绍。