Sulfur capture for fluidized-bed combustion of high-sulfur content lignites

Sulfur release and capture behavior of lignites with highly combustible sulfur-contents were investigated by extending a previously-developed comprehensive model to incorporate sulfur retention. The predictive performance of the model was tested by comparing the model predictions with on-line concentration measurements of O₂, CO₂, CO and SO₂. Favorable comparisons are obtained between the predicted and measured concentrations of gaseous species along the combustor. Results show that freeboard sulfur-capture is enhanced significantly with recycling of elutriated sorbent particles as the sulfur release to the freeboard is significant for fuels rich in combustible sulfur.     

Growth and characterization of Ni:DLC composite films using pulsed laser deposition technique

The structure and surface morphology of Ni-incorporated diamond like carbon (Ni:DLC) films have been investigated. These films were deposited on Si substrates using pulsed laser deposition (PLD) technique. A KrF Excimer laser (λ = 248 nm) was used for co-ablation from multi component Ni–graphite target. The concentration of Ni was varied by ablating the Ni part of the target with various numbers of laser pulses. The SEM and AFM analysis reveals that the surface is composed of segregates of Ni which increases with the increase in Ni content during the growth process. The structural investigations by XRD and Raman spectroscopy provided information about the orientation of the incorporated constituent and the ordering of the carbon species. Maximum height of the nano structures which were observed on the surface was ∼50 nm. The G-peak of the graphite was shifted towards higher wave number due to enhancement in SP² sites which have been increased due to the increase in the Ni concentration. A small change in the surface roughness ranging from 7.78 nm to 13.1 nm due to increased Ni concentration was also observed.     

The effects of different greenhouse covering materials on energy requirement,growth and yield of aubergine

Effects of UV stabilised polyethylene (UV+PE), IR absorbers polyethylene (IR+PE), double layers of polyethylene (D-Poly) and single layer of polyethylene (PE), as greenhouse covers, on aubergine growth, productivity and energy requirement were investigated in a late autumn season (2001). The late and final yields of plants grown in D-Poly houses were higher than those grown in UV+PE, IR+PE and PE. Light transmission was the highest in PE, intermediate in UV+PE and IR+PE, and the lowest in D-Poly houses. Relative humidity was the highest in D-Poly, intermediate in IR+PE and UV+PE, and the lowest in PE houses. The plants in D-Poly houses grew and developed faster (more leaves and flowers) than those in IR+PE, UV+PE and PE houses. Plant growth and development in UV+PE and IR+PE houses was similar. Economic analyses showed that aubergine production was economically viable in D-Poly, UV+PE and IR+PE houses. For aubergine production in climatic conditions similar to Black Sea Region, the D-Poly greenhouse is strongly recommended, because there was a higher productivity and a lower heating requirement in comparison to UV+PE, IR+PE and PE houses.     

Electrical and photovoltaic properties of an organic-inorganic heterojunction based on a BODIPY dye

An organic-inorganic heterojunction based on a BODIPY dyes has been produced by forming dye thin film on n-Si. The electrical parameters of the structure have been investigated by current-voltage (I-V) and capacitance-voltage (C-V) measurements. The ideality factor, the barrier height and the series resistance values of the diode have been calculated as 2.43, 0.84 eV, and about 1.3 kΩ, respectively. The diode behaves as a non-ideal diode because of the series resistance and interface layer. The barrier height value obtained from I-V measurement has been compared with one from C-V measurement. Moreover, it has been seen that the diode is highly sensitive to the light and the reverse bias current increases about 1 × 10⁴ times at −1 V under 100 mW/cm² and AM1.5 illumination condition. The short photocurrent density (J_sc) and the open circuit voltage (V_oc), the fill factor (FF) and power conversion efficiency (η) have been determined as 3.78 mA/cm², 327 mV, 0.28 and 0.48 %, respectively.     

Ranging Accuracy in Dynamic Spectrum Access Networks

Theoretical analysis of time-of-arrival (TOA)-based high-precision ranging algorithm for the dynamic spectrum access networks (DSANs) is performed. The asymptotic frequency-domain Cramer-Rao bound (CRB) of the ranging algorithm that takes the frequency-dependent feature (FDF) and phase of multipath components (MPCs) into account is derived through Whittle formula. The effects of FDF-MPCs and related parameters such as absolute bandwidth and operating center frequency on the ranging accuracy are investigated. The results show that the impacts of the FDF-MPCs on the ranging accuracy can be significant and it is recommended utilizing as large absolute bandwidth as possible at low operating center frequencies to obtain high-precision distance information of the users in the DSANs     

Virtual CNC system. Part II. High speed contouring application

This paper presents a trajectory planning strategy for maintaining the tool positioning accuracy in high speed cornering applications. A 3D contour error estimation algorithm is presented for determining the geometric deviation from arbitrarily shaped toolpaths. Two spline fitting strategies are developed for smoothening sharp corners. The under-corner approach reduces the toolpath length, and therefore the cornering time. This technique yields successful results when used with a high bandwidth servo controller (such as sliding mode control), capable of accurately tracking the commanded toolpath. The over-corner approach is based on stretching out the sharp corner with a smooth curve, which counteracts the ‘undercut’ caused by the large phase lag in low bandwidth servo controllers (such as P–PI control). The cornering feedrate is adjusted in the Virtual CNC platform, developed in the first part of this article, to ensure that contour error violation does not occur. The achieved cornering accuracy is verified in experiments, which are in close agreement with predictions obtained with the Virtual CNC.     

Power Doppler findings in nasopharingeal angiofibroma

Three fractions of polysaccharides that have high biological activity were extracted from Chinese bamboo leaves (Indocalamus Tesselatus) with 0.9% sodium chloride, 1% ammonium oxalate and 85% ethanol. Their component sugars were investigated by paper chromatography developed with n-butanol-pyridine-water (6:4:3 by vol), and by gas chromatography with crown ester stationary-phase-fused silica capillary column. Their monosaccharide compositions are different from each other with glucuronic acid, galactose, arabinose, mannose, glucose, and xylose (52, 18, 9, 7 and 6%, respectively) in one fraction, only glucuronic acid in another and glucuronic acid, fucose, arabinose and xylose (36, 31, 24 and 9%, respectively) in the third fraction. The protection effect of two polysaccharides against experimental hepatitis was studied in mice.     

The effect of etomidate induction on plasma cortisol levels in children undergoing cardiac surgery

Loyalty to one's extended family, a well-known Japanese tradition, has broken down following World War II. Child rearing in Japan, therefore, has been changing gradually and clearly. Traditionally, child rearing was taught to young mothers by the grandmothers. However, recently young couples are no longer living with their parents. Therefore, there are no advisers nor consultants available at home for their child rearing. Commercialism has certainly invaded the field of child rearing, including too many guidebooks and even baby-sitting companies. Children's lives have become much more competitive, busy and unnatural in comparison with those of 20-30 years ago. This might be one cause of the increased incidence of bullying, school phobia and psychological disorders in children.     

Ozonation of synthetic versus natural textile tannins: recalcitrance and toxicity towards Phaeodactylum tricornutum.

A sound in-plant pollution control strategy can only be defined by paying due attention to bio-recalcitrance and toxicity. In this context the levels of toxicity and inert COD introduced to textile dyebath discharges by two alternative auxiliary chemicals, namely natural tannin (NT) and synthetic tannin (ST), were investigated. The effect of 40 minutes ozonation at 1,000 mg h(-1) at pH 3.5 on the segregated effluent streams containing the above-mentioned tannin formulations was evaluated in terms of changes in toxicity and recalcitrance. The effect of ozonation on the COD distribution of raw and ozonated NT and ST samples according to their molecular weight cut-offs was also assessed. Both untreated tannin formulations exerted high acute toxicity towards marine microalgae Phaeodactylum tricornutum. Moderate decrease in the toxicity levels of both tannins was observed upon ozonation. The raw NT formulation with a COD content more than twice that of its alternative raw ST had an initially inert soluble COD content of only 25 mg/L, while the initially inert COD was 135 mg/L for ST. As the initially inert soluble COD content of NT was considerably lower, this textile auxiliary did not need chemical pretreatment to improve its biodegradability. On the other hand, the initially inert soluble COD content of ST was reduced by 70% by ozone pretreatment. In terms of residual COD contents achievable after passing through a biological treatment system, raw NT and pretreated ST formulations yielded 100 and 95 mg/L COD, respectively. The highest proportion of COD (46% for NT and 88% for ST) was found in the <1 kDa range. The same fraction increased to 93% for NT after ozonation, while for ST no significant change was observed in the COD distribution of the molecular weight cut-offs after ozonation.