Fabrication of Pebax/SAPO mixed matrix membranes for CO2/N2 separation

Mixed matrix membranes (MMMs) were prepared by solvent evaporation method using Pebax-1074 polymer as matrix and inorganic zeolite SAPO-23 as dopant. The morphology, surface functional groups, microstructure, thermal stability, and separation performance of MMMs were analyzed by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and gas permeation, respectively. The effects of dopant loading amount, permeation temperature, and permeation pressure on the structure and properties of MMMs were investigated. The results showed that the introduction of SAPO zeolite reduced the crystallinity of the MMMs and improved the CO₂/N₂ selectivity. Under the conditions of 30°C and 0.15 MPa, the MMMs prepared by incorporating with 5% SAPO zeolite in content exhibited the highest CO₂/N₂ selectivity of 72.0 together with the CO₂ permeability of 98.2 Barrer.     

Supercritical carbon dioxide assisted fabrication of biomimetic sodium alginate/silk fibroin nanofibrous scaffolds

In this study, biomimetic sodium alginate (SA)/silk fibroin (SF) scaffolds were successfully fabricated by supercritical CO₂ technology. The SA/SF scaffolds exhibited an interconnected porous and extracellular matrix (ECM)-like nanofibrous structures. Moreover, the SA microparticles were embedded in the SF scaffolds. Increasing the content of SA microparticles could improve tensile strength and compressive strength of the SF scaffolds and reduce the porosity of the SF scaffolds. The addition of the SA microparticles could also regulate the degradation rate of the SA/SF scaffolds. Furthermore, the results of in vitro biocompatibility evaluation, indicated that the SA/SF scaffolds exhibited no obvious cytotoxicity and higher cell adhesion ability and were more favorable for L929 fibroblasts proliferation than pure SF scaffolds. Therefore, the SA/SF scaffolds with ECM-like nanofibrous and interconnected porous structure have potential application in skin tissue engineering.     

Study on polyurethane-acrylate/cerium dioxide modified by 3-(Methylacryloxyl)propyltrimethoxy silane and its UV absorption property

Firstly, cerium dioxide(CeO₂) was modified by 3-(Methylacryloxyl)propyltrimethoxy silane (KH-570), and modified CeO₂ (mCeO₂) was prepared. Then poly (urethane-acrylate) was modified by mCeO₂, and poly (urethane-acrylate)/modified CeO₂ (PUA/mCeO₂) composites with ultraviolet absorption property were prepared. The morphology, thermal hydrophobicity, mechanical properties, optical properties, and UV-absorption properties of PUA/mCeO₂ composites were studied. XRD and SEM analysis showed that the modified CeO₂ had better dispersion in the matrix than that of pure CeO₂. Ultraviolet–visible spectrum and thermogravimetric analysis were used to characterize the optical properties and thermal stability of PUA/mCeO₂ composites. The results showed that with the increasing of the mCeO₂ content, the UV-absorption property of PUA/mCeO₂ composites was improved gradually. When the content of mCeO₂ is 3%, the absorption of ultraviolet of PUA/mCeO2 composites is about 5 times of pure PUA film, and the absorption band is mainly in the UVA section. The thermal stability of PUA/mCeO₂ composites was improved with the adding of mCeO₂. With the increasing of mCeO₂ content, the contact angle of PUA/mCeO₂ composites increased significantly. And the UV-absorption mechanism of PUA/mCeO₂ Composites was studied. UV-curable PUA/mCeO₂ composites have good UV absorption property and water resistance. They will be used in the sun screen and protect people's skin.     

永磁同步直线电机无模型电流控制

为改善永磁同步直线电机的动态响应性能,提高电机控制系统的鲁棒性,针对传统永磁同步直线电机PID控制方法中参数不确定性导致的控制不稳定问题,提出一种无模型电流控制方法.该文基于超局部模型设计永磁同步直线电机控制系统的无模型电流控制器,分别搭建PID控制和无模型电流控制系统,在此基础上进行稳态运行、负载突加减和电机参数摄动的仿真及实验对比.结果表明,所提方法改善了永磁同步直线电机控制系统的动态响应性能,对电机参数不确定性具有较强的鲁棒性.     

基于电压和电流特征的双馈风电变流器功率器件开路故障综合诊断

变流器功率器件开路故障监测与识别对提高双馈风电系统智能运维至关重要.针对现有基于变流器电压或电流单一特征以及固定阈值的方法难以同时实现功率器件故障诊断监测与识别问题,该文提出一种基于变流器直流母线电压的故障监测与基于转子电流故障识别的综合诊断方法.首先,理论分析变流器功率器件开路故障对直流母线电压的影响,基于累积和(CUSUM)算法,提出基于直流母线电压特征的故障监测方法;其次,针对转子输出电流非平稳特性和阈值固定问题,提出基于归一化输出电流平均值和绝对平均值为故障特征量及自适应阈值的故障识别方法;最后,仿真模拟不同功率器件先后开路,验证所提方法的有效性,以风速随机及电网电压跌落为场景验证所提方法的鲁棒性.同时,以功率器件典型开路故障实验数据验证仿真分析的准确性.仿真与实验结果表明,所提方法能准确实现变流器功率器件开路故障诊断.     

一种适用于配电网的新分布式潮流控制器拓扑

常规分布式潮流控制器(DPFC)需通过3次谐波电流以实现串联侧与系统的有功功率交换,串联侧所在支路首末端分别需△/YN、YN/△联结型变压器,因此在配电网中的安装地点受到一定限制.为此该文提出一种适用于配电网的新DPFC(NDPFC)拓扑;分析NDPFC工作原理,应用配电网典型系统验证其潮流调节范围与调控特性;此外,研究NDPFC串并联侧电磁暂态数学模型,为提高鲁棒性与控制精度,提出一种采用三环控制的串联侧Ⅰ、Ⅱ控制策略;最后,在不同配电网场景下,通过仿真验证了NDPFC可实现配电网综合潮流调控、补偿三相不平衡、促进新能源消纳,有效地提高了配电网电能质量.     

基于改进多入多出无模型自适应控制的二维直线电机迭代学习控制

二维直线电机在实际运行中存在强耦合、未知非线性等未建模动态控制问题,且易受外部干扰的影响.基于无模型自适应控制(MFAC)不依赖被控系统精确数学模型的特点及迭代学习控制(ILC)循序渐进的学习规律,提出一种改进多入多出无模型自适应控制(MIMO-MFAC)的二维直线电机迭代学习控制(ILC)复合控制方案.在无模型自适应控制输入准则函数中加入一阶差分单元,使改进多入多出(MIMO)无模型自适应反馈控制器具有很强的鲁棒性.迭代学习前馈控制器可以克服外部干扰,补偿系统非线性,前馈反馈优势互补,实现对期望输出的精度补偿,进一步减小位置跟踪误差.最后,将二维直线电机运动平台与LINKS-RT半实物仿真系统相结合,通过实验验证所提方案的有效性.     

适用于中压领域的V形钳位多电平变换器

多电平变换器在中高压大功率电能变换领域已得到广泛的应用.该文针对中压电能变换领域,提出V形钳位多电平变换器(VMC)拓扑族.在现有IGBT电压等级的条件下,该拓扑族采用较少数量的器件就可以实现中压大功率电能变换,结构简单;同时该拓扑族无需飞跨电容,降低了系统控制复杂度.首先提出VMC拓扑族的构成,包括拓展方式、一般形式以及演化类型;在此基础上研究VMC工作原理及控制方法,分析直接钳位机制和阻断电压分配问题.考虑目前商业主流功率器件电压等级,针对拓扑结构特点,揭示适宜VMC的电压等级;最后通过仿真和实验结果验证了所提拓扑族及控制方法的可行性,也进一步证明了该文理论分析的正确性.     

考虑备用共享的区域电力现货市场出清模型

在推进我国新一轮电力体制改革和建设全国统一电力市场的背景下,为了打破省间壁垒,缓解现行区域电力市场部分省份因备用容量不足和源荷逆向分布而存在的电力紧缺或“三弃”问题,引入备用共享机制和联络线协调优化的运行方式,构建了包括安全约束机组组合模型和安全约束经济调度模型在内的区域电力现货市场电能与备用联合出清模型。通过考虑备用共享的区域电力现货市场电能与备用联合出清,实现了电力资源在更大范围的优化配置,有效提高了系统运行的经济性和可靠性。以两个互联的IEEE 30节点系统模拟区域内两省间电力市场交易,验证了所提模型的正确性和有效性。     

单相五电平逆变器3次谐波自消除SHMPAM

为提升低开关频率单相五电平电压源型逆变器的输出电能质量,设计了一种改进的特定谐波缓解脉冲幅值调制(SHMPAM)策略.为单相五电平级联H桥逆变器的两个开关角建立了约束条件,从而推导出谐波幅值表达式,达到使3倍频谐波自消除的目标,同时还可以降低5次和7次谐波含量.利用一台单相五电平级联H桥逆变器样机开展了实验测试,结果表明新调制算法具有理想的3倍频谐波自消除能力,可作为单相多电平逆变器带线性和非线性负载的优化配置方案.