双柱塞砂浆泵中工作机构的设计和仿真研究

本文介绍了双柱塞砂浆泵的工作原理，根据机构替代原理建立起双柱塞砂浆泵工作机构的运动分析模型，然后在MatLab环境下，详细介绍了工作凸轮曲线的设计程序，利用计算机设计程序可以方便地分析工作缸活塞以及工作凸轮机构的位移、速度、加速度，利用SIMULINK仿真工具箱进行运动学仿真，为工作机构设计提供相应的理论分析依据。     

回转窑供电装置改造

本阐述了回转窑供电装置存在的缺陷，亦即改造过程和改造后的效果。     

Electronic properties of dehydrogenated nanodiamonds: A first-principles study

First-principles calculations using quantum-mechanical density functional theory (DFT) are carried out to study the geometric structure and electronic properties of dehydrogenated nanodiamonds with diameters varying from 0.8 nm to 1.6 nm. The results show that the electronic properties of dehydrogenated nanodiamond are quite different from those of bulk diamond or hydrogenated nanodiamond. Surface atoms play an important role in the electronic structure, especially the states near the Fermi level, for dehydrogenated nanodiamond. In addition, it has been revealed that the size-dependent feature in the electronic properties for dehydrogenated diamonds is also contributed by the surface effect, in addition to the quantum confinement effect.     

Nanoscale Hybrid Langmuir－Blodgett Films Based on Cerium－Substituted Heteropolymolybdate and Polyquinoline

Nanoscale hybrid organic/inorganic Langmuir-Blodgett films of cerium-substituted heteropolymolybdates (CeHPMo) and π-conjugated macromolecule poly(1,2-dihydro-2,2,4-trimethyl) quinoline (PQ) were obtained with auxiliary film-forming material stearic acid(SA) or octadecylamine(ODA). The surface pressure-area isotherms illuminate the formation of the hybrid LB films of PQ/ODA/Ce-HPMo and PQ/SA/Ce-HPMo. The different film-forming mechanism was discussed when the different auxiliary film-forming materials were used in the system. The absorption spectra indicate that the molecules of PQ and Ce-HPMo are incorporated into the LB films. Tapping-mode AFM image reveals a granular surface texture of nanosized Ce-substituted heteropolymolybdate. STM image shows that the conductivity is greatly improved after Ce-substituted heteropolymolybdates are incorporated in the films.     

固体超强酸S_2O_8~(2-)/SnO_2-SiO_2催化合成环己酮1,2-丙二醇缩酮

采用沉淀-浸渍法制备了固体超强酸S2O28-/SnO2-SiO2,以它为催化剂催化环己酮和1,2-丙二醇合成了环己酮1,2-丙二醇缩酮;考察了带水剂种类及用量、酮醇摩尔比、催化剂用量、反应时间对产品收率的影响,并用正交实验对反应条件进行了优化。实验结果表明,适宜的反应条件为:n(环己酮)∶n(1,2-丙二醇)=1∶1.6、催化剂用量为反应物料总质量的2.0%、带水剂环己烷用量5.0mL、反应时间50min。在此条件下,环己酮1,2-丙二醇缩酮收率达到91.47%;催化剂的稳定性良好,在重复使用5次后环己酮1,2-丙二醇缩酮收率为82.20%,活性下降的主要原因为催化剂表面积碳和吸附了有机物;经傅里叶变换红外光谱和气相色谱质谱分析表明,产物为环己酮1,2-丙二醇缩酮,纯度为100%。     

六通道瞬态光学高温计

六通道瞬态光学高温计是在可见光和近红外光谱范围内 ,把光源的热辐射取出六个波段进行测量。每个波段信号通过各自的光纤传输、光电倍增管探测和记录仪器记录。系统的时间分辨率小于 30 ns,冲击温度测量范围为 2 30 0～ 90 0 0 K,测量误差小于 5 % ,给出了以碘化钠、硝基甲烷和空气为样品的若干实验结果     

贝氏体铁素体片条的超微亚结构研究

首次采用扫描隧道显微镜(STM)在大气环境下直接观察了Fe-1.0C-2.0Si-4.0Cr钢中下贝氏体铁素体片条的组织结构,在下贝氏体亚单元内部首次观察到以前从未发现的,尺寸更小、形状规则、排列整齐的结构单元——超亚单元,并初步提出下贝氏体铁素体由以下四个结构层次组成:即下贝氏体铁素体片条由亚片条组成,亚片条由亚单元组成,亚单元由超亚单元组成。