（Y－ZrO_2）－SiCw－Al_2O_3陶瓷复合材料的摩擦磨损

本文对Ａｌ２Ｏ３基陶瓷复合材料Ａｌ２Ｏ３－ＺｒＯ２－ＳｉＣｗ进行了干摩擦磨损试验，并运用了ＳＥＭ，ＴＥＭ和ＸＲＤ等手段对其显微结构、力学性能及它们与ＧＣｒ１５钢对摩时的摩擦磨损行为进行了系统分析，在此基础上深入探讨了ＳｉＣ晶须（ＳｉＣｗ）增韧补强作用对复合材料的摩擦磨损性能的影响。     

快速凝固/粉末冶金高硅铝合金微观组织及拉伸性能

采用快速凝固／粉末冶金法制备Al-17Si-6Fe-4.5Cu-0.5Mg合金,并进行T6处理。利用现代测试手段对挤压态及T6处理态合金微观组织及拉伸性能进行研究。结果表明：采用这种工艺可使合金组织中第二相得到显著细化,经T6处理后第二相有粗化趋势,同时也有新相沉淀析出;合金拉伸性能主要表现在高温、低塑性及良好耐热性。     

镁合金热化学反应热喷涂Al2O3基复相陶瓷涂层的性能

为了提高镁合金的耐磨、耐蚀等性能,以Al2O3+TiO2为陶瓷骨料,加入Al+B2O3+TiO2放热反应体系,采用氧乙炔火焰喷涂技术在AZ31B镬合金表面制备Al2O3基复相陶瓷涂层,研究了复合陶瓷涂层的形貌、致密性、相结构、热震性能、耐磨性和耐蚀性,并与普通热喷涂陶瓷涂层进行了比较.结果表明:热化学反应热喷涂层表面陶瓷粒子的熔化率较高,呈熔岩状;热化学反应热喷涂过程中发生热化学反应,涂层中有TiB2等新相生成;热化学反应热喷涂层的抗热震性、致密性、耐磨性、耐蚀性均优于普通热喷涂层,清漆封孔可使热化学反应热喷涂层的致密性大幅提高,几乎不发生腐蚀.     

多巴胺改性聚苯硫脲与聚偏氟乙烯共混复合材料的制备与性能

聚苯硫脲（ArPTU）是一种新型高击穿、低损耗的材料,为提高其储能密度,在与聚偏氟乙烯（PVDF）共混的过程中,如何提高其溶解性,降低界面问题,成为研究热点之一。利用多巴胺（DA）对其进行改性可以有效地改善其与PVDF的界面问题。采用溶液流延热压的方法制备出不同共混比的多巴胺改性聚苯硫脲共混聚偏氟乙烯（DA/ArPTU-PVDF）复合薄膜。并采用X射线衍射仪、扫描电子显微镜、核磁共振、凝胶渗透色谱、阻抗分析仪等对其进行表征。结果表明:当DA/ArPTU-PVDF中DA/ArPTU质量分数为10wt%~15wt%时,PVDF的β晶型相对含量显著增加,这是其介电性能增加的主要原因之一;100 Hz时,介电常数最大可以达到10.3（10wt% DA/ArPTU）,同时介电损耗降低,最低达到了0.008（25wt% DA/ArPTU）。复合材料的储能密度也有明显提高,最大可以达3.0 J/cm3（10wt% DA/ArPTU）,相对于纯PVDF提高了63.3%。此外,复合材料的击穿特性相比于纯PVDF具有很大的提高,最大可达556.4MV/m（15wt% DA/ArPTU）。而且,改性后的复合材料力学性能也有了很大的提高。最大断裂伸长率可以达到196.7%（5wt% DA/ArPTU）,展现出了柔性高击穿储能材料的潜力。      

硅压阻式微压力传感器的研制及性能测试

硅微压力传感器由于体积小、重量轻、精度高、成本低等特点应用很广泛,在某些领域已取代传统的传感器。进一步研制小体积高精度的传感器,扩大其应用范围已势在必行。本工作主要从提高传感器的性能角度来分析掩膜版设计中的重要问题,并对设计制作的传感器进行静态测试,取得了满意的实验结果。     

Toward a molecular design of porous carbon materials

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Single-walled carbon nanotubes modified carbon ionic liquid electrode for sensitive electrochemical detection of rutin

The single-walled carbon nanotubes (SWCNTs) modified carbon ionic liquid electrode (CILE) was designed and further used for the voltammetric detection of rutin in this paper. CILE was prepared by mixing graphite powder with ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate and liquid paraffin together. Based on the interaction of SWCNTs with IL present on the electrode surface, a stable SWCNTs film was formed on the CILE to get a modified electrode denoted as SWCNTs/CILE. The characteristics of SWCNTs/CILE were recorded by different methods including cyclic voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy. The electrochemical behaviors of rutin on the SWCNTs/CILE were investigated by cyclic voltammetry and differential pulse voltammetry. Due to the specific interface provided by the SWCNTs-IL film, the electrochemical response of rutin was greatly enhanced with a pair of well-defined redox peaks appeared in pH 2.5 phosphate buffer solution. The oxidation peak currents showed good linear relationship with the rutin concentration in the range from 1.0 × 10^− 7 to 8.0 × 10^− 4 mol/L with the detection limit as 7.0 × 10^− 8 mol/L (3σ). The SWCNTs/CILE showed the advantages such as excellent selectivity, improved performance, good stability and it was further applied to the rutin tablets sample detection with satisfactory results.