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排序方式: 共有1610条查询结果,搜索用时 31 毫秒
11.
Auguste Commeyras Hlne Collet Laurent Boiteau Jacques Taillades Odile Vandenabeele‐Trambouze Herv Cottet Jean‐Philippe Biron Raphaël Plasson Louis Mion Olivier Lagrille Herv Martin Franck Selsis Michel Dobrijevic 《Polymer International》2002,51(7):661-665
Addressing the still open question of the prebiotic origin of sequential macromolecules (peptides, nucleic acids) on the primitive Earth, we describe a molecular engine (the primary pump), which works at ambient temperature and continuously generates, elongates and complexifies sequential peptides. This new scenario is based on a cyclic reaction sequence, whose keystep is the activation of amino acids into their N‐carboxyanhydrides (NCA) through nitrosation by NOx. This process could have taken place on tidal beaches; it requires a buffered ocean, emerged land and a nitrosating atmosphere. With the help of geochemical studies and computer simulations of atmosphere photochemistry, we show that the primitive Earth during the Hadean may have satisfied all these requirements. © 2001 Society of Chemical Industry. 相似文献
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The in vitro effect of citric acid application on periodontally involved root surfaces was investigated using scanning electron microscopy. Teeth were selected following specific criteria. The specimens were prepared for observation, and the features of the root surface were studied. The results demonstrated that a 3-minute application of citric acid (pH = 1.0) to the root surface after scaling and root planing demineralized the outer root surface, opened the dentinal tubules, and exposed collagen fibers. Scaling and root planing alone left the surface with a smear layer, scattered islands of cementum, and no collagen fibers or exposed dentinal tubules. 相似文献
14.
Which signals are important in gaining attention in science? For a group of 1,371 scientific articles published in 17 demography
journals in the years 1990-1992 we track their influence and discern which signals are important in receiving citations. Three
types of signals are examined: the author's reputation (as producer of the idea), the journal (as the broker of the idea),
and the state of uncitedness (as an indication of the assessment by the scientific community of an idea). The empirical analysis
points out that, first, the reputation of journals plays an overriding role in gaining attention in science. Second, in contrast
to common wisdom, the state of uncitedness does not affect the future probability of being cited. And third, the reputation
of a journal may help to get late recognition (so-called sleeping beauties) as well as generate 'flash-in-the-pans': immediately
noted articles but apparently not very influential in the long run. 相似文献
15.
Raphaëlle Savoire Jean‐Louis Lanoisellé Hélène Ducatel Eugène Vorobiev 《European Journal of Lipid Science and Technology》2008,110(8):725-734
Seven linseed varieties were harvested at seven times before complete maturity. Microscale oilseed expressions were subsequently carried out on it. A pressure of 10 MPa was applied for 1 h under uniaxial stress. The results were characterized in terms of oil, water and mucilage content, harvest date and oil yield. The piston displacement versus time (creep curves) was described by a four‐Kelvin‐Voigt elements viscoelastic model. Parameters were derived from the model, such as the mechanical properties of seeds (compressibility moduli), showing that the viscoelastic model fits well the experimental data (R² ≈ 0.999). The modeling parameters were combined with some biochemical data in order to predict the kinetics of oil extraction. 相似文献
16.
Friedrich Schne Gerhard Jahreis Gerhard Richter Reinhard Lange 《Journal of the science of food and agriculture》1993,61(2):245-252
In rapeseed meals (RSM) of a conventional (c) or a newly bred (n) variety 117 or 44 mmol glucosinolates and glucosinolate degradation products per kg dry matter were detected. Soaking meals in aqueous myrosinase or copper sulphate solution and subsequent drying reduced the content of antinutrients by more than 90%. Broiler chickens were fed (i) a glucosinolate-free diet, or this diet in which half the soybean meal was replaced by RSM of various origins and treatment; (ii) untreated cRSM; (iii) cRSM treated with myrosinase: (iv) cRSM treated with Cu (v) untreated nRSM; or (vi) nRSM treated with myrosinase. These diets were administered with or without supplementary iodine. Chickens receiving the iodine-deficient diets with myrosinase-treated RSM showed growth depression, incomplete feathering, leg injuries and severe goitre. In the serum T4 could not be detected. Giving myrosinase-treated RSM plus iodine, or giving other RSM diets irrespective of iodine administration, no growth depression was observed. RSM diets without iodine dosage markedly increased thyroid weight: there were no differences between the RSM variants. In contrast to the treatment with myrosinase, in the sera of the chickens fed on untreated RSM or RSM treated with copper T4 could be detected, suggesting that in iodine-deficient conditions differences in serum T4 concentration between RSM groups indicate a differing anti-thyroid activity. With iodine supplementation the RSM had a significant effect on thyroid weight. The largest thyroids (five-fold heavier) were in the animals with myrosinase-treated cRSM. The untreated cRSM and the nRSM trebled or doubled the thyroid weight, and the myrosinase-treated nRSM trebled it. The thyroid weight of chicks fed cRSM treated with copper did not differ significantly from the glucosinolate-free control. There was evidence that heating the myrosinase-treated RMS produced anti-thyroid compounds; these should be identified in further investigations. 相似文献
17.
Zakaria Chajar Michel Primet Hélène Praliaud Michèle Chevrier Catherine Gauthier Frédéric Mathis 《Catalysis Letters》1994,28(1):33-40
The role of nitrogen dioxide in the selective reduction of NO by propane over a Cu-MFI zeolite is investigated. NO2 and NO reductions were carried out under similar conditions of reaction. In the presence of oxygen, the reduction of NO by C3H8 does not differ significantly from that of NO2. In the absence of oxygen, the reduction of NO2 by propane occurs with a partial decomposition of the nitric dioxide molecule. Such a decomposition leads to the formation of oxygen, which is responsible for the increase in catalytic activity by comparison with the same reaction performed with NO. NO2 formed and released in the gas phase during the reduction of NO by propane in the presence of oxygen does not play a predominant role in the catalytic process. 相似文献
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B Weisser S Grüne R Burger H Blickenstorfer J Iseli SH Michelsen R Opravil S Rageth ER Sturzenegger P Walker 《Canadian Metallurgical Quarterly》1994,8(4):227-231
In a retrospective study of 50 consecutive children with posterior fossa tumors treated at Texas Children's Hospital, Houston, Tex., in 1989-1992, we evaluated perioperative factors which might influence the development of postoperative cerebrospinal fluid leaks. Factors analyzed included the presence of preoperative hydrocephalus, the institution of cerebrospinal fluid diversion, and the method of dural closure. No statistically significant impact on subsequent cerebrospinal fluid leakage was demonstrated. 相似文献