MOF衍生的高选择性加氢芳香硝基化合物的石墨碳包覆镍催化剂

针对芳香硝基化合物的催化选择性加氢反应，开发可替代贵金属催化剂的低成本、高效非贵金属催化剂，对于芳香胺类化合物的绿色生产具有重要意义。利用简易、可规模化的制备方法，以镍—2,5-吡啶二羧酸金属有机框架为前驱体，热解制备了氮掺杂石墨碳包覆镍纳米催化材料（Ni@CN）。采用X射线衍射、扫描电镜、透射电镜、元素分析、N2吸脱附等检测手段对Ni@CN的物化性质进行了表征，并对其催化性能进行了评价。结果表明，Ni@CN可在温和条件下（85℃，1.0 MPa H2)高效加氢含取代官能团的芳香硝基化合物生成对应的芳香胺类化合物。对比试验表明，镍纳米颗粒是Ni@CN的加氢活性中心，而石墨碳壳的存在有利于优先吸附硝基官能团。此外，进一步考察了Ni@CN的循环使用性能以及抗硫化物中毒的特性。     

Feasibility study of large-scale mass customization 3D printing framework system with a case study on Nanjing Happy Valley East Gate

At present, the development and implementation of digital transformation are the keys to promoting high-quality industry development. The new digital fabrication method of robotic 3D printing is a research area being studied by many to tackle the issue of the declining productivity of traditional construction methods. Although many studies have been done, most of the current 3D printing projects are facing limitations in terms of scale. In order to bridge the gap, this article proposed a mass customization 3D printing framework system for large-scale projects. This article discusses how mass customization is made possible through the joint operation of the FUROBOT software and 3D printing hardware. By taking the east gate of Nanjing Happy Valley Plaza as a case study, the article demonstrates and studies the feasibility of the large-scale mass customization 3D printing framework system.     

行云流水 日本鹤冈文化馆

正作为当地文化和艺术活动的地标性场所,新建成的日本鹤冈文化馆备受瞩目。鹤冈位于日本本州北部,当地历史建筑众多,且学校、画廊云集,是一个充满了文化氛围的城市。当局为了配合当地民众对文化艺术越来越高的需求,决定将曾经是城市文化活动核心的旧文化馆进行重建,扩充建筑机能,以一个全新的多功能综合性文化空间来承接更多当地的文化艺术活动,更好地融入学生和当地的艺术团体中去。     

小波变换在多级传动齿轮箱缺齿故障诊断中的应用

针对缺齿故障的多级传动齿轮箱,由于幅值及相位调制现象带来的诊断问题,利用小波分析和包络谱分析,对直齿圆柱齿轮故障信号进行降噪和功率谱分析,准确的找到故障特征信号,诊断齿轮箱的故障。结果表明小波变换能够较好的诊断缺齿故障。     

房屋市政工程复工复产指南

1总则各参建单位(含建设、施工、监理等)项目负责人是疫情防控和复工复产的第一责任人,按照"谁用工、谁管理、谁负责"要求,严格落实各项防控措施,确保疫情防控和工程质量安全管控到位。2复工复产条件2.1防控机制组建疫情防控复工复产工作组,指定专人负责对接工程项目所在地的政府、街道、社区及定点医院。2.2专项方案编制疫情防控方案和复工复产组织方案,对现场管理、人员管控、物资储备和应急处置等作出安排,明确具体要求和措施。     

Amination of biochar surface from watermelon peel for toxic chromium removal enhancement

Watermelon peel residues were used to produce a new biochar by dehydration method. The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI) ions from aqueous solution has been investigated. Three biochars, Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, were made from watermelon peel via dehydration with 50% sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_2 or Triethylenetetramine(TETA) to give Melon-BO-TETA. The prepared biochars were characterized by BET, BJH,SEM, FT-IR, TGA, DSC and EDAX analyses. The highest removal percentage of Cr(VI) ions was 69% for Melon-B,98% for Melon-BO-NH_2 and 99% for Melon-BO-TETA biochars of 100 mg·L~(-1) Cr(VI) ions initial concentration and 1.0 g·L~(-1) adsorbents dose. The unmodified biochar(Melon-B) and modified biochars(Melon-BO-NH_2 and Melon-BO-TETA) had maximum adsorption capacities(Qm) of 72.46, 123.46, and 333.33 mg·g~(-1), respectively.The amination of biochar reduced the pore size of modified biochar, whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations. The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B, Melon-BO-NH_2 and Melon-BO-TETA, respectively. The adsorption rate was primarily controlled by pseudo-second–order rate model. Conclusively, the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process. The adsorption for the Melon-B, Melon-BO-NH_2 and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.     

工业和信息化部关于印发《2015年工业绿色发展专项行动实施方案》的通知

工信部节[2015]61号各省、自治区、直辖市及计划单列市、新疆生产建设兵团工业和信息化主管部门:为加快实施工业绿色发展战略,提高能源资源利用效率,减少污染物排放,促进工业可持续发展,我部决定2015年继续组织实施工业绿色发展专项行动。现将《2015年工业绿色发展专项行动实施方案》印发给你们,请结合实际,加强组织协调,认真贯彻落实。     

2021年1-2月互联网和相关服务业运行情况

1-2月,互联网和相关服务业开局良好,业务收入增速达到较高水平,利润延续上年下半年增长态势,研发费用较快增长.疫情防控常态化推动线上商品和服务消费活跃,网络销售业务收入增速大幅提高,生产、生活类服务平台恢复性增长.