Effect of AlN addition on the electrical resistivity of pressureless sintered SiC ceramics with B4C and C

The effect of 0–12 wt% AlN addition on the electrical resistivity of SiC ceramics pressureless sintered with 0.7 wt% B₄C and 2.5 wt% C additives was investigated. The elemental analysis of SiC grains revealed a codoping of Al and N in the SiC lattice with a higher N concentration with 1 wt% AlN addition and a higher Al concentration with 12 wt% AlN addition. The electrical resistivity decreased by four orders of magnitude (1.7 × 10⁵ → 8.3 × 10¹ Ω cm) with 1 wt% AlN addition due to the increased carrier density (1.7 × 10¹⁰ → 2.3 × 10¹⁵ cm⁻³) caused by excess N-derived donors. However, subsequent AlN addition (4 → 12 wt%) led to an increase (2.9 × 10³ → 1.2 × 10⁴ Ω‧cm) in electrical resistivity due to (1) increased Al dopants which act as deep acceptors for trapping N-derived carriers causing a decrease in carrier density (2.3 × 10¹⁵ → 5.9 × 10¹³ cm⁻³), (2) the formation of electrically insulating SiC-AlN solid solution, and (3) the presence of electrically insulating AlN grains at the grain boundaries.     

Determination of stability constants of mercury(II) by garlic organosulfur ligands with differential pulse voltammetry

Journal of Applied Electrochemistry - In this work, interactions of mercury with di allyl disulfide (DADS), dimethyl disulfide (DMDS), and diallyl sulfide (DAS) were studied by differential pulse...     

UV-shielding by a polyurethane/f-Oil fly ash-CeO2 protective coating

A waste material called oil fly ash (OFA) was acid-functionalized, yielding f-OFA-COOH, which was then reacted with cerium oxide (CeO₂) to make CeO₂-functionalized OFA, or f-OFA-CeO₂. Pristine OFA and f-OFA-CeO₂ were used to make waterborne polyurethane (WBPU) dispersions, referred to as WBPU/OFA and WBPU/f-OFA-CeO₂, respectively, with defined OFA and f-OFA-CeO₂ content. All the dispersions were applied to mild steel as organic coatings to evaluate their protective properties, such as their hydrophobicity, adhesive strength and UV-shielding resistance. These protective properties varied based on the OFA and f-OFA-CeO₂ content. The highest water contact angle, minimum water swelling and maximum adhesive strength were found using WBPU/f-OFA-CeO₂-20 coating (using 2.00 wt% f-OFA-CeO₂), which also showed the maximum ultraviolet (UV) absorption via UV–vis spectroscopy analysis. This UV shielding result also matched field test results, as that coating was found to exhibit the lowest UV degradation near a marine atmosphere, as shown by X-ray photoelectron spectroscopy (XPS) analysis. The least affected hydrophobicity was also recorded for the sample with the WBPU/f-OFA-CeO₂-20 coating.     

Progress and challenges in sustainability,compatibility, and production of eco-composites: A state-of-art review

Owing to economic and environmental benefits, new generations of materials/commodities follow “from waste to wealth” strategy. Recently, there has been a huge upsurge in research on the development of eco-composites using recycled plastic polymers and agro-residues because the eco-composites satisfy the stringent environment regulations and are cost-effective. Herein, we present a detailed review on the potential use of several types of natural fillers as an efficient reinforcement for recycled plastic polymers. In particular, the characterization of different categories of eco-composites according to their morphological, physical, thermal, and mechanical properties is extensively reviewed and their results are analyzed, compared, and highlighted. Furthermore, a framework to produce functional eco-composites, which includes functionalization of ingredients, critical issues on microstructural parameters, processing, and fabrication methods, is outlined and supported with sufficient data from the literature. Finally, the review outlines the emerging challenges and future prospects of eco-composites to be addressed by interested researchers to bridge the gap between research and commercialization of such a class of material. Overall, the acquired knowledge will guide researchers, scientists, and manufacturers to plan, select, and develop various forms of eco-composites with enhanced properties and optimized production processes.     

Fourier transform infrared (FTIR) authentication and batch-to-batch consistency for different types of paints using benchtop and handheld FTIR spectrophotometers for oil and gas industry

Standardization of Fourier transform infrared (FTIR) fingerprint region for paints and assessment on the reproducibility using different spectrophotometers were investigated. While selective fingerprint regions may be confusing for technicians/analysts who are non-chemists, we attempt to generalize these regions (e.g., 1300–1000 cm⁻¹ for Epoxy part A and 1400–1000 cm⁻¹ for Epoxy part B) by choosing a universal region (2000–900 cm⁻¹) that works for different paints. Comparison result using a paired student t-test shows that the degree of similarity (r) values from the studied regions are not statistically different. The paint fails the screening analysis occasionally on-site when analyzed using handheld FTIR due to the higher level of noise that gives low r values (r < 0.900 ± 0.002). The same samples were analyzed using a benchtop FTIR and the r values are above 0.900 ± 0.002. While the screening may lead to a false rejection of the sample on-site, there could be occurrence of false acceptance. The on-site screening of EPZ part A with different formulations, for instance, shows that the r values over the entire IR spectrum are above 0.900 ± 0.002 when analyzed using handheld FTIR. After the samples were analyzed using the benchtop, the r values fall below 0.900 ± 0.002.     

Performance evaluation of endrills

This paper evaluates the performance of a relatively new type of drill called an endrill which is a cross between a drill and an endmill. Investigations into the effects of its cutting conditions on the drilling forces, surface finish, drill wear and hole oversize were carried out. It was found that endrills produced better quality holes than conventional twist drills, better surface finish and less oversize of the holes. Hence, with proper feed, speed and flow rate of the pressurized flushing coolant, a good finish of about R_a = 1 μm can be attained without reaming. Thus, the productivity of finished holes can be remarkably improved. Compared to twist drills, lower torque and thrust were observed which yielded improved tool life and reduced power consumption. No “walking phenomenon” was observed when this kind of drill was used and the amount of hole oversize was found to average about 0.7% of the drill diameter as compared to 1.6% when twist drills were used. Finally, general equations for the drill torque and thrust were derived from the experimental results.     

Investigation into the evolution of corrosion product layer (CPL) of 1018 C-steel exposed to multiphase environment using FIB and EIS techniques

This communication reports into the effects of flow, fluid composition and the effectiveness of imidazoline inhibitors on the evolution and distribution of corrosion products on 1018 C-steel exposed to CO₂ corrosion. Focused ion beam technique was used to measure the thickness of the corrosion product layer (CPL), in contrast to the conventional techniques used to observe the cross-section of specimens. Morphological analysis using scanning electron microscopy revealed topographical variations on the surface with the change in the multiphase environment. The CPL was found to be more porous in nature with the presence of oil in the multiphase environment. Electrochemical impedance spectroscopy was also used in the present study to measure the corrosion rates and was subsequently correlated to the CPL evolution for 1018 C-steel in multiphase environment.     

Oxidation and sulfidation behavior of Fe-20Cr-16Ni-4Al-1Y2O3 oxide-dispersion-strengthened alloy

High-temperature oxidation and sulfidation studies were conducted on an oxide-dispersion-strengthened alloy of composition Fe-20Cr-16Ni-4Al-1Y₂O₃. The oxidation studies were conducted in air and low-PO₂ environments over a temperature range of 650–1200°C. Results are also reported on the sulfidation resistance of preformed oxide scales and the influence of reoxidation of preformed sulfide scales. Detailed microstructural results and x-ray diffraction analysis data are presented to substantiate the corrosion behavior of the alloy over the wide range of conditions anticipated in fossil-energy systems. Data are also presented on the corrosion behavior of the alloy in oxygen/sulfur mixed gas atmospheres, and the results are used to compare the corrosion behavior of the present alloy with other chromia- and alumina-forming alloys.     

Investigation of micro-EDM material removal characteristics using single RC-pulse discharges

Similar to EDM, in micro-EDM, intense heat is generated between the workpiece and tool electrode by the discharge through a dielectric medium to result in the formation of a microcrater that is much smaller in size. In this study, a single-spark generator has been developed to study the erosion characteristics from the microcrater size. Using a simple heat transfer model, the efficiency at different discharge condition is also deduced. It is found that at lower-energy (<50 μJ) discharges, the energy required to remove the unit volume of material, defined as the specific energy, is found to be much less than that at higher-energy discharges. Additionally, the ratio of the standard deviation to the measured microcrater size is found to be lower at lower discharge energy, indicating greater consistency in shape and size when the discharge occurs at lower energy. The fundamental erosion mechanism of material is discussed by considering melting and evaporation phenomena using theoretical modeling. The average efficiency of erosion, when estimated to be due primarily to melting or evaporation alone, is found to be up to an order of magnitude higher at lower-energy discharges than that at higher-energy discharges.     

Crack initiation in relation to the tool edge radius and cutting conditions in nanoscale cutting of silicon

In cutting of brittle materials, experimentally it was observed that there is a ductile–brittle transition when the undeformed chip thickness is increased from smaller to larger than the tool cutting edge radius of the zero rake angle. However, how the crack is initiated in the ductile–brittle mode transition as the undeformed chip thickness is increased from smaller to larger than the tool cutting edge radius has not been fully understood. In this study, the crack initiation in the ductile–brittle mode transition as the undeformed chip thickness is increased from smaller to larger than the tool cutting edge radius has been simulated using the Molecular Dynamics (MD) method on nanoscale cutting of monocrystalline silicon with a non-zero edge radius tool, from which, for the first time, a peak deformation zone in the chip formation zone has been found in the transition from ductile mode to brittle mode cutting. The results show that as the undeformed chip thickness is larger than the cutting edge radius, in the chip formation zone there is a peak deformation depth in association with the connecting point of tool edge arc and the rake face, and there is a crack initiation zone in the undeformed workpiece next to the peak deformation zone, in which the material is tensile stressed and the tensile stress is perpendicular to the direction from the connecting point to the peak. As the undeformed chip thickness is smaller than the cutting edge radius, there is no deformation peak in the chip formation zone, and thus there is no crack initiation zone formed in the undeformed workpiece. This finding explains well the ductile–brittle transition as the undeformed chip thickness increases from smaller to larger than the tool cutting edge radius.