Effect of pressure on the structural and elastic properties of ZnS and MgS alloys in the B3 and B1 phases

From the first-principles calculations, we have investigated the elastic stiffness coefficients C₁₁, C₁₂, C₄₄ and the bulk modulus B of the II-VI semiconductors ZnS and MgS under hydrostatic pressure. The calculations are based on the density functional theory within the generalized gradient approximation (GGA) for exchange-correlation interaction. For the structural properties we have shown that ZnS adopt the rocksalt (NaCl or B1) structure over 11.87 GPa pressure, the same character is adopted by MgS over 0.8 GPa. The elastic coefficients have the same behavior for the different structures of alloys; they increase with increasing pressure values. Our results for the structural parameters and equilibrium phase elastic constants are in good agreement with the available theoretical and experimental data.     

Impedance studies on plasticized PMMA-LiX [X: CF3SO3, N(CF3SO2)2−] polymer electrolytes

Plasticized polymer electrolytes composed of poly(methylmethacrylate) (PMMA) as the host, propylene carbonate (PC) or ethylene carbonate (EC) as a plasticizer and LiX (X: CF₃SO₃⁻ or N(CF₃SO₂)₂⁻) as a salt were prepared by the solution cast technique. Impedance spectroscopy was performed in the temperature range between 303 and 383 K. In this paper, we report the electrical properties of polymer electrolytes with different lithium salts and plasticizers. The polymer electrolytes investigated exhibited high ionic conductivity at room temperature in the range of 10^− 6 to 10^− 4 S cm^− 1. The temperature dependence studies showed that the samples were ionic conductors and seemed to obey the Vogel-Tamman-Fulcher (VTF) rule. FTIR spectroscopy studies confirmed the polymer-salt interaction.     

Genetic Algorithm for the Multiple-Query Optimization Problem

Producing answers to a set of queries with common tasks efficiently is known as the multiple-query optimization (MQO) problem. Each query can have several alternative evaluation plans, each with a different set of tasks. Therefore, the goal of MQO is to choose the right set of plans for queries which minimizes the total execution time by performing common tasks only once. Since MQO is an NP-hard problem, several, mostly heuristics based, solutions have been proposed for solving it. To the best of our knowledge, this correspondence is the first attempt to solve MQO using an evolutionary technique, genetic algorithms     

Observation of coupling between zero- and two-dimensional semiconductor systems based on anomalous diamagnetic effects

We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectroscopy. An extremely large positive diamagnetic coefficient is observed when an electron in the wetting layer combines with a hole in the quantum dot; the coefficient is nearly one order of magnitude larger than that of the exciton states confined in the quantum dots. Recombination of electrons with holes in a quantum dot of the coupled system leads to an unusual negative diamagnetic effect, which is five times stronger than that in a pure quantum dot system. This effect can be attributed to the expansion of the wavefunction of remaining electrons in the wetting layer or the spread of electrons in the excited states of the quantum dot to the wetting layer after recombination. In this case, the wavefunction extent of the final states in the quantum dot plane is much larger than that of the initial states because of the absence of holes in the quantum dot to attract electrons. The properties of emitted photons that depend on the large electron wavefunction extents in the wetting layer indicate that the coupling occurs between systems of different dimensionality, which is also verified from the results obtained by applying a magnetic field in different configurations. This study paves a new way to observe hybrid states with zero- and two-dimensional structures, which could be useful for investigating the Kondo physics and implementing spin-based solid-state quantum information processing.

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Study on novel poly (vinyl pyrrolidone) doped MWCNTs/polyrhodanine nanocomposites: Synthesis,characterization, and thermal performance

In this paper, poly (vinyl pyrrolidone) (PVP) doped multiwall carbon nanotubes (MWCNTs/polyrhodanine), were synthesized through one-step chemical oxidative polymerization of rhodanine monomers on the surface-modified carbon nanotubes. Characterization of MWCNTs/polyrhodanine was conducted by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transforms infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and EDX spectrum analyses in which the results confirmed the successful formation of MWCNTs/polyrhodanine. In addition, to investigate the thermal properties of samples, thermogravimetric analysis (TGA) was employed, and results exhibited significant improvement in the nanocomposite thermal stability due to the addition of MWCNTs with reinforcement effect in polymer matrix.     

Tuning of Dielectric Parameters of (NiFe<Subscript>2</Subscript>O<Subscript>4</Subscript>)<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>/CuTl-1223 Nano-superconductor Composites by Temperature and Frequency

Nickel ferrite (NiFe₂O₄) nanoparticles and Cu_0.5Tl_0.5Ba₂Ca₂Cu₃O_10?δ (CuTl-1223) superconductor were prepared separately and then mixed in an appropriate ratios at the final stage to obtain (NiFe₂O₄) _x /CuTl-1223 (x = 0, 0.5, and 1.0 wt%) nano-superconductor composites. There was no significant change observed in crystal structure of the host CuTl-1223 superconducting matrix after the addition of NiFe₂O₄ nanoparticles. The value of zero-resistivity critical temperature { T _{c(R = 0)} (K)} was decreased with increasing content of these nanoparticles in these composites. Maximum values of dielectric loss tangent (tanδ) at lowest possible frequency of 40 Hz were increased with the increase of operating temperature, while its values were decreased and become almost zero at higher frequencies for all these samples at all operating temperatures. A peak in dielectric loss tangent was shifted towards lower frequency values with the addition of these nanoparticles in CuTl-1223 superconducting matrix. The dielectric loss tangent peak was also shifted towards lower frequency values in all these samples with increasing operating temperature, which shows the relaxator-like behavior in these samples. The dielectric parameters of these composites can be tuned by frequency, operating temperatures, and nature and content of these nanoparticles.     

Nanoelectromechanical Chip (NELMEC) Combination of Nanoelectronics and Microfluidics to Diagnose Epithelial and Mesenchymal Circulating Tumor Cells from Leukocytes

An integrated nano‐electromechanical chip (NELMEC) has been developed for the label‐free distinguishing of both epithelial and mesenchymal circulating tumor cells (ECTCs and MCTCs, respectively) from white blood cells (WBCs). This nanoelectronic microfluidic chip fabricated by silicon micromachining can trap large single cells (>12 µm) at the opening of the analysis microchannel arrays. The nature of the captured cells is detected using silicon nanograss (SiNG) electrodes patterned at the entrance of the channels. There is an observable difference between the membrane capacitance of the ECTCs and MCTCs and that of WBCs (measured using SiNG electrodes), which is the key indication for our diagnosis. The NELMEC chip not only solves the problem of the size overlap between CTCs and WBCs but also detects MCTCs without the need for any markers or tagging processes, which has been an important problem in previously reported CTC detection systems. The great conductivity of the gold‐coated SiNG nanocontacts as well as their safe penetration into the membrane of captured cells, facilitate a precise and direct signal extraction to distinguish the type of captured cell. The results achieved from epithelial (MCF‐7) and mesenchymal (MDA‐MB231) breast cancer cells circulated in unprocessed blood suggest the significant applications for these diagnostic abilities of NELMEC.     

Minimizing ordered weighted averaging of rational functions with applications to continuous location

This paper considers the problem of minimizing the ordered weighted average (or ordered median) function of finitely many rational functions over compact semi-algebraic sets. Ordered weighted averages of rational functions are, in general, neither rational functions nor the supremum of rational functions so current results available for the minimization of rational functions cannot be applied to handle these problems. We prove that the problem can be transformed into a new problem embedded in a higher dimensional space where it admits a convenient polynomial optimization representation. This reformulation allows a hierarchy of SDP relaxations that approximates, up to any degree of accuracy, the optimal value of those problems. We apply this general framework to a broad family of continuous location problems showing that some difficult problems (convex and non-convex) that up to date could only be solved on the plane and with Euclidean distance can be reasonably solved with different _?p-norms${?}_p\mathrm{-}\mathrm{norms}$ in finite dimensional spaces. We illustrate this methodology with some extensive computational results on constrained and unconstrained location problems.     

An Empirical Study of Factors Affecting e-Commerce Adoption among Small- and Medium-Sized Enterprises in a Developing Country: Evidence from Malaysia

The purpose of this paper is to empirically examine determinants of e-commerce adoption among Malaysian small- and medium-sized enterprises (SMEs). This study tested eight hypotheses on determinants affecting e-commerce adoption with empirical data from several survey instruments: an online questionnaire-based survey, mailed survey and questionnaire collected in-person from a sample of 307 SMEs in Malaysia. The findings show that e-commerce adoption within Malaysian SMEs is affected by perceived relative advantage, perceived compatibility, managers/owner's knowledge and expertise, management characteristics and external change agents. This study contributes to enhancing the understanding of the determinants of adopting e-commerce in SMEs and provides some interesting perspective from Malaysia. Those parties interested in promoting their business online may find these results helpful in guiding their efforts.