Two-point constraint approximation in structural optimization

The use of constraint approximations is recognized as a primary means of achieving computational efficiency in structural optimization. Existing approximation methods are based upon the value of the constraint function and its derivatives at a single point. The present paper explores the use of approximations based upon the value of the constraint and its derivative at two points. Several candidate approximations are suggested and tested for randomly generated rational constraint functions. Several of the approximations prove to be superior to the single-point approximations.     

High productivity methanol carbonylation catalysis using iridium: The Cativa™ process for the manufacture of acetic acid

Methanol carbonylation to acetic acid is catalysed with high rates at low water concentrations using an iridium/iodide based catalyst. The catalyst system exhibits high stability allowing a wide range of process conditions and compositions to be accessed without catalyst precipitation. Two distinct classes of promoters have been identified for the reaction: simple iodide complexes of zinc, cadmium, mercury, indium and gallium and carbonyl complexes of tungsten, rhenium, ruthenium and osmium. The promoters exhibit a unique synergy with iodide salts, such as lithium iodide, under low water conditions. A rate maximum exists at commercially attractive low water conditions, and optimisation of the process parameters gives acetic acid with a selectivity in excess of 99% based upon methanol. The levels of liquid by-products formed are a significant improvement over that achieved with the conventional high water rhodium based catalyst system used in the Monsanto process and the quality of the product obtained under low water concentrations is exceptional. The Cativa™ process has now been successfully commercialised on three world scale plants.     

Rapid detection of oilfish and escolar in fish steaks: A tool to prevent keriorrhea episodes

The outbreak of keriorrhea caused by the wax ester-rich oilfish and escolar has become a frequent and worldwide concern. To help prevent such episodes, rapid detection of these fishes in the supply chain of the seafood industry and by food and health inspection agencies is essential. Through a combination of DNA, GC–MS and TLC analyses with reference to authentic samples, fish steaks of oilfish and escolar mislabeled as other species could be accurately identified. The TLC method developed is inexpensive and provides a reliable and importantly rapid identification within 30 min.     

Fatty acid analysis of blood serum, seminal plasma, and spermatozoa of normozoospermic vs. Asthernozoospermic males

Docosahexaenoic acid (DHA; 22∶6n−3) is found in extremely high levels in human ejaculate with the majority occurring in the spermatozoa. However, the relative concentration of DHA and other fatty acids, in blood serum, seminal plasma, and spermatozoa of asthenozoospermic vs. normozoospermic individuals is not known. We analyzed the phospholipid fatty acid composition of blood serum, seminal plasma, and spermatozoa of normozoospermic men and asthenozoospermic men in order to determine if DHA levels, as well as the levels of other fatty acids, differed. The serum phospholipid DHA levels were similar in the two groups, suggesting similar intakes of dietary DHA. On the other hand, seminal plasma levels of DHA (3.0 vs. 3.7%) and total polyunsaturated fatty acids (PUFA) (11.8 vs. 13.5%) were significantly lower in asthenozoospermic vs. normozoospermic men, respectively, while 18∶1 (19.0 vs. 16.8%) and monounsaturated fatty acids (MUFA) (24.2 vs. 21.7%) were significantly higher in the asthenozoospermic vs. the normozoospermic men. Spermatozoa from asthenozoospermic men had higher levels of 18∶1, 20∶0, 22∶0, 22∶1, and 24∶0 than sperm from normozoospermic men, and lower levels of 18∶0 and DHA (8.2 vs. 13.8%). Furthermore, total MUFA (19.3 vs. 16.5%) was higher and total PUFA (19.0 vs. 24.0%), n−3 fatty acids (9.3 vs. 14.6%), and the ratio of n−3 to n−6 fatty acids (1.0 vs. 1.6) were lower in the asthenozoospermic men. Therefore, in asthenozoospermic individuals, lower levels of DHA in the seminal plasma, but not in the blood serum, mimic the decreased concentrations of DHA in the spermatozoa. This suggests that the lower concentrations of spermatozoon DHA in these individuals are due not to dietary differences but to some type of metabolic difference in the asthenozoopermic men.     

Direct measurement of the Cu oxidation number of cuprate superconductor ceramics

The Cu oxidation number in YBa₂Cu₃O₇ has been measured directly by soft X-ray fluorescent spectroscopy both at room temperature and at liquid N₂ temperature. The measurements are based on a calibration curve from different Ba-O compounds. The effect of changes in oxidation number above and below the transition temperature and its role in highT _c superconductivity are discussed.     

On the temporal stability of personality: Evidence for differential stability and the role of life experiences.

The authors investigated the stability of personality and trait affect in young adults. In Studies 1 and 2, young adults were retested on a Big Five personality measure and a trait affect inventory over a 2.5-year and a 2-month period, respectively. Results from Study 1 point to positive mean-level changes; participants scored higher on Extraversion, Openness, Agreeableness, and Conscientiousness at Time 2. Affectively, participants experienced less negative affect and more positive affect at Time 2. Results from both retests provide clear evidence of differential stability. Affective traits were consistently less stable than the Big Five. Other analyses suggest that life events influence the stability of affective traits more than the Big Five. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Recent developments in hot plate welding of thermoplastics

This paper considers the hot plate welding process applied to three injection molded thermoplastic materials: polypropylene, high impact polystyrene, and poly(phenylene oxide). Weld quality was assessed by tensile testing. The process was found to be suitable for all three materials, although tolerance to variations in process parameters varied. The parameters in the heating phase, i.e., hot plate temperature and time, were the most important for achieving good welds, whereas parameter variations in the consolidation phase were relatively unimportant.     

Estimating person-to-person variability in VOC emissions from personal care products used during showering

An increasing fraction of volatile organic compounds (VOC) emissions come from the domestic use of solvents, contained within myriad commonplace consumer products. Emission rates are often poorly characterized and depend significantly on individual behavior and specific product formulation and usage. Time-concentration profiles of volatile organic compounds (VOCs) arising from the use of a representative selection of personal care products (PCPs) during showering are generated, and person-to-person variability in emissions calculated. A panel of 18 participants used a standardized set of products, dosages, and application times during showering in a controlled indoor bathroom setting. Proton transfer mass spectrometry was used to measure the in-room VOC evolution of limonene (representing the sum of monoterpenes), benzyl alcohol, and ethanol. The release of VOCs had reproducible patterns between users, but noticeable variations in absolute peak concentrations, despite identical amounts of material being used. The amounts of VOC emitted to air for one showering activity were as follows: limonene (1.77 mg ± 42%), benzyl alcohol (1.07 mg ± 41%), and ethanol (0.33 mg ± 78%). Real-world emissions to air were between 1.3 and 11 times lower than bottom-up estimates based on dynamic headspace measurements of product emissions rates, likely a result of PCPs being washed away before VOC evaporation could occur.     

Exposure of birds to radionuclides and other contaminants in Special Protection Areas (SPAs) in North-West England

There has been a decline in the population of some bird species at Morecambe Bay and the Solway Firth Special Protected Areas in North-West England during the last fifty years. It was suggested that the declines were caused, in part, by contaminants in the food and environment, primarily from the radioactive effluent discharge from the Sellafield Ltd nuclear fuel reprocessing plant in Cumbria. This study analysed bird feathers and tissues, vegetation and sediment for radionuclides, metals and persistent organic compounds. The non-radionuclide results were all low compared to relevant action limits. The ERICA model was used with field data to estimate the radiological dose to birds from exposure to ¹³⁷Cs and ²⁴¹Am with results between 1.26 to 3.83 μGy h^− 1, below the ERICA screening level of 10 μGy h^− 1 and within the IAEA 40 μGy h^− 1 guideline value below which potential adverse impacts on biota are unlikely. The study showed no link between bird population decline and anthropogenic discharges to the SPAs.