全文获取类型
收费全文 | 931篇 |
免费 | 48篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 13篇 |
化学工业 | 263篇 |
金属工艺 | 9篇 |
机械仪表 | 18篇 |
建筑科学 | 20篇 |
矿业工程 | 2篇 |
能源动力 | 39篇 |
轻工业 | 166篇 |
水利工程 | 8篇 |
石油天然气 | 6篇 |
无线电 | 61篇 |
一般工业技术 | 133篇 |
冶金工业 | 75篇 |
原子能技术 | 6篇 |
自动化技术 | 161篇 |
出版年
2023年 | 7篇 |
2022年 | 22篇 |
2021年 | 52篇 |
2020年 | 20篇 |
2019年 | 37篇 |
2018年 | 23篇 |
2017年 | 32篇 |
2016年 | 27篇 |
2015年 | 35篇 |
2014年 | 39篇 |
2013年 | 75篇 |
2012年 | 51篇 |
2011年 | 70篇 |
2010年 | 44篇 |
2009年 | 52篇 |
2008年 | 51篇 |
2007年 | 39篇 |
2006年 | 31篇 |
2005年 | 29篇 |
2004年 | 29篇 |
2003年 | 19篇 |
2002年 | 16篇 |
2001年 | 23篇 |
2000年 | 16篇 |
1999年 | 8篇 |
1998年 | 28篇 |
1997年 | 15篇 |
1996年 | 15篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1973年 | 3篇 |
1964年 | 1篇 |
1960年 | 2篇 |
1956年 | 1篇 |
排序方式: 共有980条查询结果,搜索用时 708 毫秒
11.
Miguel Martínez-Espronceda Jesús D. Trigo Santiago Led H. Gilberto Barrón-González Javier Redondo Alfonso Baquero Luis Serrano 《Computer methods and programs in biomedicine》2014
Experiences applying standards in personal health devices (PHDs) show an inherent trade-off between interoperability and costs (in terms of processing load and development time). Therefore, reducing hardware and software costs as well as time-to-market is crucial for standards adoption. The ISO/IEEE11073 PHD family of standards (also referred to as X73PHD) provides interoperable communication between PHDs and aggregators. Nevertheless, the responsibility of achieving inexpensive implementations of X73PHD in limited resource microcontrollers falls directly on the developer. Hence, the authors previously presented a methodology based on patterns to implement X73-compliant PHDs into devices with low-voltage low-power constraints. That version was based on multitasking, which required additional features and resources. This paper therefore presents an event-driven evolution of the patterns-based methodology for cost-effective development of standardized PHDs. The results of comparing between the two versions showed that the mean values of decrease in memory consumption and cycles of latency are 11.59% and 45.95%, respectively. In addition, several enhancements in terms of cost-effectiveness and development time can be derived from the new version of the methodology. Therefore, the new approach could help in producing cost-effective X73-compliant PHDs, which in turn could foster the adoption of standards. 相似文献
12.
Zdena Tvarůžková Magda Tupá Pavel Jírů Alfonso Nastro Giorgio Giordano Ferruccio Trifiró 《Catalysis Letters》1989,2(6):369-374
The small pore zeolite HLZ 132 exhibits, in comparison with other zeolites, an increased selectivity for the transformation of methanol to ethylene in the reaction temperature range 350–500 °C: the weight ratio of C2H4 to C3H6 in the products ranges between 1 and 4 at WHSV=2 h–1. Besides the effect of the reactant shape selectivity this fact may be interpreted by the participation of the asymmetrical methoxy groups in the surface as well as by proton-donor centres of lower acidity which do not catalyze the oligomerization of ethylene but which do the more basic molecule of propylene, thereby generating polyene-type coke. 相似文献
13.
Thomas Uchida Alfonso Callejo Javier García de Jalón John McPhee 《Multibody System Dynamics》2014,31(3):371-392
Efficient dynamic simulation code is essential in many situations (including hardware-in-the-loop and model-predictive control applications), and highly beneficial in others (such as design optimization, sensitivity analysis, parameter identification, and controller tuning tasks). When the number of modeling coordinates n exceeds the degrees-of-freedom of the system f, as is often the case when closed kinematic chains are present, the governing dynamic equations consist of n second-order ordinary differential equations (ODEs) coupled with m=n?f algebraic constraint equations. This set of n+m index-3 differential-algebraic equations can be difficult to solve in an efficient yet accurate manner. Embedding (or generalized coordinate partitioning) can be used to obtain f ODEs (one for each independent acceleration), which are generally more amenable to numerical integration; however, the dependent positions are typically computed from the independent positions at each time step. Newton–Raphson iteration is often used for solving the position-level kinematics, but only provides solutions to within a specified tolerance, and can require several iterations to converge. In this work, Gröbner bases are used to obtain recursively solvable symbolic solutions for the dependent positions, which can then be evaluated to within machine precision using a fixed number of arithmetic operations. Natural coordinates are particularly attractive in this context, since the resulting constraint equations are maximally quadratic polynomials and are, therefore, easily triangularized. The proposed approach is suitable for use in an automated formulation procedure and, as demonstrated by three examples, is capable of generating highly efficient simulation code with minimal additional effort required at the formulation stage. 相似文献
14.
Alfonso Ranalli Luciano Pollastri Stefania Contento Emilia Iannucci Lucia Lucera 《European Journal of Lipid Science and Technology》2003,105(2):57-67
The influence of the olive paste malaxation time on the composition and the industrial output of oil was investigated. To this purpose, three Italian olive varieties (Leccino, Dritta, Caroleo) were processed with a centrifugal system for six malaxation periods (0, 15, 30, 45, 60 and 75 min). The concentrations of the majority of the oil constituents changed during the malaxation. However, these changes were not significant for all of them: the contents of β‐carotene, the major xanthophylls, chlorophylls a and b, pheophytins a and b in the oils increased progressively with increasing malaxing times, whereas the contents of simple and hydrolysable phenols (secoiridoid derivatives), o‐diphenols and total phenols decreased. A significant increase in total volatiles and green volatiles of the lipoxygenase cascade (C6 aldehydes, C6 alcohols, C5 alcohols and C5 carbonyls) was detected. An opposite trend was observed for the green C6 esters. As a result, the global analytical quality, flavour, aroma and shelf‐life of the oils were negatively affected. The oil yield increased substantially up to 45 min of paste malaxation times. Beyond 60 min, the yields tended to decrease. 相似文献
15.
Milton Jimenez-Francisco Jose Gonzalo Carrillo Luis Alfonso Garcia-Cerda 《应用聚合物科学杂志》2021,138(1):49628
Mechanochemical degradation by planetary ball milling (PM) is used for postpolymerization modification of styrene homopolymers (PS). A complete factorial design was chosen to study the effect of radical scavengers, milling time, initial molecular weight, and revolution radius (Rp), on the shape of molecular weight distributions (MWDs) of PS. Size-exclusion chromatography analysis shows the feasibility of fine-tuning MWD of PS at up to 40% conversion. Distributions ranged from unimodal to bimodal in a PM with Rp = 150 mm at different stage of milling, whereas in a PM with Rp of 60.8 mm the adjustment of unimodal distributions is achieved. Initial polydispersity is more important to develop bimodal distributions when compared with initial molecular weight. Fourier transform infrared and X-ray electron spectrometry analysis show some suppression of PS degradation and complete oxidation inhibition of macromolecular radicals with the incorporation of radical scavengers, which we considered as additional aids when adjusting the MWDs. 相似文献
16.
17.
18.
19.
Marco A. Loza-Mejía Rafael Castillo Alfonso Lira-Rocha 《Journal of molecular graphics & modelling》2009,27(8):55
Although 9-anilinoacridines are among the best studied antitumoral intercalators, there are few studies about the effect of isosteric substitution of a benzene moiety for a heterocycle ring in the acridine framework. According to these studies, this approach may lead to effective cytotoxic agents, but good cytotoxic activity depends on structural requirements in the aniline ring which differ from those in 9-anilinoacridines. The present paper deals with molecular modeling studies of some 9-anilino substituted tricyclic compounds and their intercalation complexes (in various DNA sequences) resulting from docking the compounds into various DNA sequences. As expected, the isosteric substitution in 9-anilinoacridines influences the LUMO energy values and orbital distribution, the dipole moment, electrostatic charges and the conformation of the anilino ring. Other important differences are observed during the docking studies, for example, changes in the spatial arrangement of the tricyclic nucleus and the anilino ring at the intercalation site. Semiempirical calculations of the intercalation complexes show that the isosteric replacement of a benzene ring in the acridine nucleus affects not only DNA affinity but also base pair selectivity. These findings explain, at least partially, the different structural requirements observed in several 9-anilino substituted tricyclic compounds for cytotoxic activity. Thus, the data presented here may guide the rational design of new agents with different DNA binding properties and/or a cytotoxic profile by isosteric substitution of known intercalators. 相似文献
20.
Alfonso Sepúlveda Jan Speulmanns Philippe M. Vereecken 《Science and Technology of Advanced Materials》2018,19(1):454-464
The growing demand of flexible electronic devices is increasing the requirements of their power sources. The effect of bending in thin-film batteries is still not well understood. Here, we successfully developed a high active area flexible all-solid-state battery as a model system that consists of thin-film layers of Li4Ti5O12, LiPON, and Lithium deposited on a novel flexible ceramic substrate. A systematic study on the bending state and performance of the battery is presented. The battery withstands bending radii of at least 14 mm achieving 70% of the theoretical capacity. Here, we reveal that convex bending has a positive effect on battery capacity showing an average increase of 5.5%, whereas concave bending decreases the capacity by 4% in contrast with recent studies. We show that the change in capacity upon bending may well be associated to the Li-ion diffusion kinetic change through the electrode when different external forces are applied. Finally, an encapsulation scheme is presented allowing sufficient bending of the device and operation for at least 500 cycles in air. The results are meant to improve the understanding of the phenomena present in thin-film batteries while undergoing bending rather than showing improvements in battery performance and lifetime. 相似文献