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排序方式: 共有453条查询结果,搜索用时 15 毫秒
31.
Vilmos Galamb Sang Chul Shim Fazle Sibtain Howard Alper 《Israel journal of chemistry》1985,26(3):216-218
The intermediates mentioned in the title are probably involved in the hydrogenation of olefins and dienes; bidentate phosphine and arsine cobalt complexes are useful reagents for these reactions. 相似文献
32.
A series of poly(styrene-co-p-stearoyl styrene) copolymers as novel polymeric solid–solid phase-change materials (SSPCMs) were synthesized by the modification of polystyrene with stearoyl chloride. The chemical structure and crystalline morphology of the synthesized copolymers were determined with Fourier transform infrared spectroscopy and polarized optical microscopy, respectively. The thermal energy storage properties and thermal stability of the SSPCMs were investigated with differential scanning calorimetry and thermogravimetric analysis, respectively. In addition, the thermal conductivity of the SSPCMs was measured with a thermal property analyzer. Moreover, thermal cycling tests showed that the copolymers had good thermal reliability and chemical stability after being subjected to 5000 heating/cooling cycles. The synthesized poly(styrene-co-stearoyl styrene) copolymers as novel SSPCMs have considerable potential for thermal energy storage and temperature-control applications. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
33.
Berk Ozsayin Emre Yilmaz Medine Ispir Hasan Ozkaynak Ercan Yuksel Alper Ilki 《Construction and Building Materials》2011,25(10):4017-4024
The mechanical characteristics of infill walls retrofitted with carbon fiber reinforced polymer (CFRP) sheets are really important for the realistic prediction of seismic performance of the vulnerable reinforced concrete (RC) frames retrofitted through CFRP strengthened infill walls. In this study, 36 hollow brick wall specimens were tested either under uniaxial compression or diagonal tension before and after retrofitting externally with CFRP sheets. The test parameters are the dimensions of the walls, the orientation of holes of bricks, the type of mortar, the amount of CFRP sheets and the details of strengthening application. At the end of the tests, a significant contribution of CFRP sheets on the mechanical characteristics of hollow brick walls was observed in terms of several important structural design parameters such as Young and shears moduli, axial and shears strengths as well as the deformation capacity. Finally, the strength and deformability characteristics of the walls and frames retrofitted with CFRP sheets were predicted analytically. The predictions were in good agreement with the experimental data. 相似文献
34.
Cohen Sheldon; Alper Cuneyt M.; Doyle William J.; Adler Nancy; Treanor John J.; Turner Ronald B. 《Canadian Metallurgical Quarterly》2008,27(2):268
Objective: We ask whether subjective socioeconomic status (SES) predicts who develops a common cold when exposed to a cold virus. Design: 193 healthy men and women ages 21-55 years were assessed for subjective (perceived rank) and objective SES, cognitive, affective and social dispositions, and health practices. Subsequently, they were exposed by nasal drops to a rhinovirus or influenza virus and monitored in quarantine for objective signs of illness and self-reported symptoms. Main Outcome Measures: Infection, signs and symptoms of the common cold, and clinical illness (infection and significant objective signs of illness). Results: Increased subjective SES was associated with decreased risk for developing a cold for both viruses. This association was independent of objective SES and of cognitive, affective and social disposition that might provide alternative spurious (third factor) explanations for the association. Poorer sleep among those with lesser subjective SES may partly mediate the association between subjective SES and colds. Conclusions: Increased Subjective SES is associated with less susceptibility to upper respiratory infection, and this association is independent of objective SES, suggesting the importance of perceived relative rank to health. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
35.
Alper Yılmaz 《International Journal of Heat and Mass Transfer》2008,51(13-14):3478-3485
Maximum heat transfer per cross-sectional area of a tube with smooth wall in turbulent flow at constant wall temperature is determined for a given pressure loss. The dimensionless tube length is determined dependent on the pressure Reynolds number, Prandtl number and inlet local pressure loss coefficient. Limiting cases for short and long tubes are separately investigated. Semi-empirical equations are derived for both optimum dimensionless tube length and dimensionless maximum heat flow per cross-sectional area using numerically obtained values with a maximum deviation of ±6.6% and with a RMSE of 3.5%. The results can also be applied to the channels with non-circular cross-sectional area. 相似文献
36.
A major source of inaccuracy in CNC machines is unwanted vibrations induced by the frequency spectra of reference motion trajectory. This paper presents a novel approach where instead of filtering techniques, axis motion commands are generated with optimal frequency spectra in the first place. Tangential feedrate profile is defined as parametric spline, and its frequency spectrum is optimized with respect to structural dynamics of the machine. The optimization problem is solved efficiently using Quadratic Programming. Experimental results confirm that proposed technique can greatly improve surface finish during machining spline tool-paths without sacrificing from cycle time and contouring performance. 相似文献
37.
Alper Uzun Volkan Ortalan Nigel D. Browning Bruce C. Gates 《Journal of Catalysis》2010,269(2):318-328
Supported mononuclear iridium complexes with ethene ligands were prepared by the reaction of Ir(C2H4)2(acac) (acac is CH3COCHCOCH3) with highly dehydroxylated MgO. Characterization of the supported species by extended X-ray absorption fine structure (EXAFS) and infrared (IR) spectroscopies showed that the resultant supported organometallic species were Ir(C2H4)2, formed by the dissociation of the acac ligand from Ir(C2H4)2(acac) and bonding of the Ir(C2H4)2 species to the MgO surface. Direct evidence of the site-isolation of these mononuclear complexes was obtained by aberration-corrected scanning transmission electron microscopy (STEM); the images demonstrate the presence of the iridium complexes in the absence of any clusters. When the iridium complexes were probed with CO, the resulting IR spectra demonstrated the formation of Ir(CO)2 complexes on the MgO surface. The breadth of the νCO bands demonstrates a substantial variation in the metal–support bonding, consistent with the heterogeneity of the MgO surface; the STEM images are not sufficient to characterize this heterogeneity. The supported iridium complexes catalyzed ethene hydrogenation at room temperature and atmospheric pressure in a flow reactor, and EXAFS spectra indicated that the mononuclear iridium species remained intact. STEM images of the used catalyst confirmed that almost all of the iridium complexes remained intact, but this method was sensitive enough to detect a small degree of aggregation of the iridium on the support. 相似文献
38.
Tuğçe P. Öztürk Onur B. Özdemir Ali Gelir Nahid A. Keshtiban Önder Yargı Selin Pıravadılı Mucur Alper Seçgin 《应用聚合物科学杂志》2024,141(4):e54854
Solid-state electrolytes such a further novel finding is going to have great importance because of the disadvantages of liquid electrolytes such as electrochemical instability, low ion selectivity, and interface contact. It is anticipated that the use of solid-state electrolytes including supercapacitors (SCs) will become widespread with decreasing self-leakage and environmental damage more than liquid electrolytes. In this study, SCs with graphene/PEDOT: PSS coated electrodes and binary PVA gel electrolytes with a conductive layer were designed and the electrochemical performance of the configurations was characterized. The effects of the conductive layer between binary electrolytes and the concentration of the KOH solution in the electrolytes were studied. It was observed that the conductive layer used between the gel electrolytes causes additional charging at the electrolyte/conductive layer interface and behaves like a serially connected capacitor to the double-layer capacitor. Interestingly, at a slow sweep rate (5 mV/s), the specific capacitance values of the assembled SCs decreased when a conductive layer was used but it increased when the sweep rate was fast (100 mV/s). 相似文献
39.
Carbon dioxide‐binding organic liquids (CO2BOL) are a new class of solvents with advantageous properties such as high boiling points, low specific heats, high absorption capacities, and easily reversible reactions. In order to implement these solvents in processes, the reaction characteristics must be determined a priori. This work presents an analysis of the rate constants and activation energies of the reaction between carbon dioxide and 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in 1‐hexanol and 1‐propanol. The reactions were found to comply with a termolecular reaction mechanism and exhibited pseudo‐first‐order behavior in the presence of excess DBU and 1‐alkanol. It was concluded that DBU‐based CO2BOL are environmentally friendly and easy‐to‐handle solvents that may provide great flexibility and improvements over conventional carbon dioxide absorption processes. 相似文献
40.
F. Melda Patan Alper Ahmet T. Ince Maria Aiordachioaiei 《International Journal of Thermophysics》2011,32(1-2):505-512
Calibration of thermometers in the temperature range from ?80 °C to 550 °C requires liquid baths; alcohol, water, silicon oil, salt baths and dry block furnaces. In this study, the use of salt baths outside of their usual range of 250 °C to 540 °C for calibrating thermometers in the range between 175 °C and 250 °C is proposed. The calibration range from 150 °C to 250 °C is usually covered by an oil bath, but utilizing a salt bath saves calibration time and resources, improves stability and homogeneity, allows longer term usage of the liquid, and reduces hazardous chemical vapors evaporated at temperatures above 175 °C. This proposal is based on a study of the uncertainty contributions at varying salt bath temperatures in the range from 175 °C to 540 °C which was carried out in this study. Results achieved and analyzed in this study indicate that the implementation of salt baths in this lower temperature range provides opportunities to calibrate reference and/or working thermometers with an uncertainty below 30 m°C, almost the same as the oil-bath uncertainty in the range of 175 °C to 250 °C. The main components of uncertainty contributed by a salt bath over this temperature range are discussed in this study. 相似文献