Copolymerization of caprolactam with polyoxybutylene diamine

Nylon 6-polyoxybutylene block copolymers were prepared by reacting polyoxybutylene diamine with caprolactam in the presence of phosphoric acid. The copolymerization was carried out in a Helicone-type reactor and the effect of time, temperature, and caprolactam concentration on the properties of the products was recorded. Differential Scanning Calorimetry studies of the products suggest the presence of both the ABA and AB types of sequences, where A and B represent nylon 6 and polyether blocks, respectively. Dynamic mechanical measurements of typical copolymers revealed the presence of at least two different nylon moieties. The melt rheology data reflect a general increase in the pseudoplasticity of the copolymer with the increase of the polyether content. Increases of the polyether content in the copolymer result in an increased elongation and a decreased tensile strength and modulus.     

Use of solution crystallization analysis by laser light scattering for studying the solution crystallization of various Ziegler–Natta‐catalysed polypropylenes

Solution crystallization analysis by laser light scattering (SCALLS) involves the observation of the scattering of diode mercury laser lamp light after it passes through a polymer solution. An increase in turbidity occurs when the hot polymer solution is cooled and the polymer starts to crystallize out of solution. This causes a decrease in the amount of laser light that can pass through the solution and an increase in the amount of scattered light. The reverse of this process leads to the turbidity decreasing with an increase in temperature. According to this concept, it is possible to follow the solution crystallization of various polypropylenes under controlled cooling. In this study, SCALLS was able to differentiate between different isotactic and syndiotactic polypropylenes with similar chemical structures, but different tacticity and molecular weights. Furthermore, SCALLS provided good crystallization information that is similar to that from crystallization analysis fractionation and temperature rising elution fractionation. In addition, SCALLS can be used as a quantitative tool for the measurement of weight fractions during dissolution. © 2014 Society of Chemical Industry     

Exploring the fitness landscape and the run-time behaviour of an iterated local search algorithm for cost-based abduction

Cost-based abduction (CBA) is an important problem in reasoning under uncertainty, and can be considered a generalization of belief revision. CBA is known to be NP-hard and has been a subject of considerable research over the past decade. In this paper, we investigate the fitness landscape for CBA, by looking at fitness–distance correlation for local minima and at landscape ruggedness. Our results indicate that stochastic local search techniques would be promising on this problem. We go on to present an iterated local search algorithm based on hill-climbing, tabu search, and simulated annealing. We compare the performance of our algorithm to simulated annealing, and to Santos' integer linear programming method for CBA.     

Interfacial hybridization kinetics of oligonucleotides immobilized onto fused silica surfaces

Fused silica optical fibers have been used in an intrinsic mode optical configuration as biosensors for fluorescence based detection of hybridization of nucleic acids. In this work, the kinetics of hybridization of single-stranded oligonucleotides that were covalently immobilized were studied. The probe DNA was dT₂₀, and the target was Fluorescein-labeled non-complementary (dT₂₀) or complementary (dA₂₀) oligonucleotide. Chronofluorimetric monitoring of the adsorption and hybridization processes was used to investigate oligonucleotide films of different density, in different salt concentrations, at temperatures of 25 and 40 °C, with the concentration of the target DNA being 0.005–0.1 μM. Mathematical models based on first- and second-order Langmuir adsorption have been examined to describe both the adsorption and the hybridization processes. Experimental data were processed using the models, and the hybridization kinetics were calculated. Hybridization kinetics on these optical fiber DNA sensors was found to be up to three orders faster than results presented for a number of other experiments using different immobilization chemistries.     

Understanding the behavior of compiler optimizations

Compiler optimizations are difficult to implement and add complexity to a compiler. For this reason, compiler writers are selective about implementing them: they implement only the ones that they believe will be beneficial. To support compiler writers in this, we describe a method for measuring the cost and benefits of compiler optimizations, both individually and in synergy with other optimizations. We demonstrate our method by presenting results for the optimizations implemented in the Jikes Research Virtual Machine on the PowerPC and IA32 platforms. Copyright © 2006 John Wiley & Sons, Ltd.     

Performance evaluation for DRED discrete-time queueing network analytical model

Due to the rapid development in computer networks, congestion becomes a critical issue. Congestion usually occurs when the connection demands on network resources, i.e. buffer spaces, exceed the available ones. We propose in this paper a new discrete-time queueing network analytical model based on dynamic random early drop (DRED) algorithm to control the congestion in early stages. We apply our analytical model on two-queue nodes queueing network. Furthermore, we compare between the proposed analytical model and three known active queue management (AQM) algorithms, including DRED, random early detection (RED) and adaptive RED, in order to figure out which of them offers better quality of service (QoS). We also experimentally compare the queue nodes of the proposed analytical model and the three AQM methods in terms of different performance measures, including, average queue length, average queueing delay, throughput, packet loss probability, etc., aiming to determine the queue node that offers better performance.     

Performance measurement of product returns with recovery for sustainable manufacturing

Today's lifecycle of new and emerging products, increase in labour costs in developed countries and user's expectations or behaviours including frequently upgrading items with latest features, influence the growth rate of product disposal to landfill. To reduce the negative impact on the environment, global manufacturers need to take responsibility for designing sustainable products and implementing cleaner production systems for 3R operations (3R–Reuse/Remanufacture/Recycle). Nevertheless, there is still a lack of comprehensive measures for assessing product returns with recovery settings. In this paper, a framework for performance evaluation using design for six sigma methodology is developed to estimate utilisation value of a manufactured product with recovery settings, which accounts for total recovery cost, manufacturing lead-time, minimisation for landfill waste and quality characteristic. Finally, a numerical example based on these performance attributes to assess product utilisation value is presented.     

A Generative System for Mamluk Madrasa Form-Making

In this paper, a parametric shape grammar for the derivation of the floor plans of educational buildings (madrasas) in Mamluk architecture is presented. The grammar is constructed using a corpus of sixteen Mamluk madrasas that were built in Egypt, Syria, and Palestine during the Mamluk period. Based on an epistemological premise of structuralism, the morphology of Mamluk madrasas is analyzed to deduce commonalities of the formal and compositional aspects among them. The set of underlying common lexical and syntactic elements that are shared by the study cases is listed. The shape rule schemata to derive Mamluk madrasa floor plans are formulated. The sets of lexical elements and syntactic rules are systematized to form a linguistic framework. The theoretical framework for the formal language of Mamluk architecture is structured to establish a basis for a computerized model for the automatic derivation of Mamluk madrasa floor plans.     

Effect of the Te/Si ratio on the electrical characteristics of the amorphous chalcogenide switches

The effect of composition on amorphous chalcogenide threshold switches of the system Si _x Te_60-x As₃₀Ge₁₀, wherex = 5, 10, 12 and 20, has been studied. The compositionx = 5 shows the best switching characteristics, e.g. the smallest holding voltage (V _h = 0.4V), the highest ON state current (I _h = 45A) and smallest threshold voltage (V _s = 1.5V). Applying the three mechanisms of conductance of Mottet al. (Phil. Mag. 37 (1975) 961), it is found that for a particular composition ₂ < ₁ < ₀ (the pre-exponential factors) andW ₂ < (E _a –E ₁ +W ₁) < (E _c –E _f) (whereE _a,E _c andE _e = activation energies at band edge, fermi level and conduction band;W ₁ andW ₂ = activation energy for hopping). It was found that the density of states at the fermi levelN(E _f) increases with the decrease of silicon content. The results provided further evidence against thermal interpretations and thereby support electronic models of threshold switching for these glass systems.