用失效的C－Pd催化剂生产氯化钯

介绍了用锌镁粉直接还原与处理失效废弃的Ｃ－Ｐｄ催化剂，并用自制混酸直接生产氯化钯的工艺。该工艺比传统的铝粉置换法更快捷，钯收率更高。     

霍多莫尔构造带湖底扇沉积特征及地质意义

综合岩芯、测井、录井、地震等资料,对霍多莫尔构造带湖底扇体的沉积特征及其油气地质意义进行了研究,发现本区湖底扇沉积共可划分为内扇、中扇、外扇三大类亚相以及内扇主沟道、中扇辫状沟道、外扇浊积岩等五类沉积微相。霍多莫尔构造带湖底扇沉积所在层系向下紧邻南屯组内最好的烃源岩层,油气从下方和侧面向湖底扇砂体内充注,通常受断层遮挡形成断层-岩性油气藏或直接被周围的泥岩封堵形成透镜体形式的岩性油气藏,油气成藏与否主要受控于储层的物性特征。实验分析表明,不同沉积微相的储集能力具有较大的差异,其中中扇辫状沟道微相是最有利的储集相带类型,内扇主沟道微相次之,为较有利储层。油气勘探实践同样证实,高产井多位于中扇辫状沟道微相内,勘探前景广阔。     

Oxidation Kinetics of an Amorphous Silicon Carbonitride Ceramic

The oxidation kinetics of amorphous silicon carbonitride (SiCN) was measured at 1350°C in ambient air. Two types of specimens were studied: one in the form of thin disks, the other as a powder. Both specimens contained open nanoscale porosity. The disk specimens exhibited weight gain that saturated exponentially with time, analogous to the oxidation behavior of reaction-bonded Si₃N₄. The saturation value of the weight gain increased linearly with specimen volume, suggesting the nanoscale pore surfaces oxidized uniformly throughout the specimen. This interpretation was confirmed by high-resolution electron microscopy and secondary ion mass spectroscopy. Experiments with the powders (having a particle size much larger than the scale of the nanopores) were also consistent with measurements of the disks. However, the powder specimens, having a high surface-to-volume ratio, continued to show measurable weight gain due to oxidation of the exterior surface. The wide range of values for the surface-to-volume ratio, which included all specimens, permitted a separation of the rate of oxidation of the free surface and the oxidation of the internal surfaces of the nanopores. Surface oxidation data were used to obtain the rate constant for parabolic growth of the oxidation scale. The values for the rate constant obtained for SiCN lay at the lower end of the spectrum of oxidation rates reported in the literature for several Si₃N₄ and SiC materials. Convergence in the behavior of SiCN and CVD-SiC is ascribed to the purity of both materials. Conversely, it is proposed that the high rates of oxidation of sintered polycrystalline silicon carbides and nitrides, as well as the high degree of variability of these rates, might be related to the impurities introduced by the sintering aids.     

双向人字槽液体润滑径向轴承动力性能

采用算子分裂法解广义雷诺方程。研究了双向人字槽液体润滑径向轴承的承载力和稳定性。计算结果和正转 (泵入型 )、反转 (泵出型 )的单向人字槽轴承进行比较。结果表明 ,双向人字槽轴承的承载力和稳定性稍差于正转的单向人字槽轴承 ,但优于反转时的单向人字槽轴承。本文还对双向人字槽润滑轴承在不同设计参数下 (螺旋角 ,槽深度 )油膜稳定性进行比较计算 ,得到合理的设计参数范围。双向人字槽轴承保持了在低偏心率时的良好稳定性 ,并适合在变向转动工况下使用。     

Growth of Gallium Nitride Films on Multilayer Graphene Template Using Plasma-Enhanced Atomic Layer Deposition

In this work,the GaN thin films were directly deposited on multilayer graphene(MLG) by plasma-enhanced atomic layer deposition.The deposition was carried out at a low temperature using triethylgallium(TEGa) precursor and Ar/N_2/H_2 plasma.Chemical properties of the bulk GaN and GaN-graphene interface were analyzed using X-ray photoelectron spectroscopy.The sharp interface between GaN and graphene was verified via X-ray reflectivity and transmission electron microscope.The microstructures and the nucleation behaviors of the GaN grown on graphene have been also studied.The results of grazing incidence X-ray diffraction and Raman spectrum indicate that the as-deposited sample is polycrystalline with wurtzite structure and has a weakly tensile stress.Optical properties of the sample were investigated by photoluminescence(PL) at room temperature.The successful growth of GaN on MLG at a low temperature opens up the possibility of ameliorating the performance of electronic and optical devices based on GaN/graphene heterojunction.     

高精度零件加工中的误差平均法原理及其应用

通过对高精度零件加工中研磨及刮研工艺过程的分析,探讨了该方法加工中误差减小的机理(即利用相互联系表面在作相对运动时微刃的微量切削,使零件表面的几何形状精度逐渐提高,随着精度的提高和表面粗糙度值的减小,其切削作用也逐渐减小,从而能达到很高的加工精度)。在分析车削对刀法的基础上给出了圆分度误差的封闭性原理,并推演了圆分度误差封闭性的数学关系式,即任何圆分度在一整圈内累积误差之和恒等于零。据此得出了圆分度误差真值的计算方法,该方法可用于实际加工误差的控制和补偿,达到高精度分度加工的目的。以上方法的实质都是通过误差平均来减小误差,在机床等高精度产品的零件加工中有重要作用。     

基于《生物化学技术》精品课程改革的课程评价

本文基于我校《生物化学技术》市级精品课程的改革,从课程评价的方面来论述此精品课程改革的成效,为进一步完善课程评价指标体系提供借鉴意义,也为后续精品课程的建设提供了参考。     

The role of Smart Grids to foster energy efficiency

The traditional electricity grid has remained the same for most of last century, without major architectural improvements. However, its requirements, guidelines and goals do have changed, especially during the last few years, driven by the sustainability in energy generation and energy efficiency principles. Thus, taking greenhouse gases emissions and CO₂ footprint reduction as key objectives and information and communications technologies as key enabler technologies, a novel and revolutionary electric grid paradigm, the so-called Smart Grid, is emerging, in which energy efficiency and renewable generation play a central role. This paper presents an overview on the main requirements and features of Smart Grids to integrate energy efficiency, on the work done and to be done, on the enabler technologies, as well as on the expected impacts and the main benefits Smart Grids will bring.     

边界不确定信息的处理—Fuzzy集和Vague集

Fuzzy集和Vague集都可用于边界不确定信息的处理。文章首先研究了这两种集合间的关系、性质,提出了Fuzzy集和Vague集的边界不确定性都可用犤0,1犦上的一个子区间来进行描述的思想。然后基于一些Vague集相似度量的思想,提出了一种求Fuzzy集和Vague集的相似性度量方法,并建立了基于Fuzzy集和Vague集度量方法的统一模型,该模型在这两种集合相似性度量上是等价的,并给出了该模型满足的性质。