Temperature variation of magnetic aftereffect

The paper analyzes the anomalous behavior of the magnetic aftereffect decay coefficient with temperature, which has been established experimentally from a thermodynamic point of view. The Arrhenius law, which has often been used to model magnetic aftereffect, is based on the Maxwell-Boltzmann (MB) statistics. At low temperatures, however, magnons obey Bose-Einstein (BE) statistics, which have a different energy spectrum. MB statistics are a good approximation to BE statistics in the temperature range in which most devices operate. The variation in temperature, governed by chemical potential that is essentially linear, has a negative slope and is zero below a low but finite temperature. Other explanations for this anomalous behavior would predict an incorrect type of temperature dependence. This new interpretation of magnetic aftereffect may have profound implications on accelerated testing to determine life expectancy of recordings     

Affine-permutation invariance of 2-D shapes.

Shapes provide a rich set of clues on the identity and topological properties of an object. In many imaging environments, however, the same object appears to have different shapes due to distortions such as translation, rotation, reflection, scaling, or skewing. Further, the order by which the object's feature points are scanned changes, i.e., the order of the pixels may be permuted. Relating two-dimensional shapes of the same object distorted by different affine and permutation transformations is a challenge. We introduce a shape invariant that we refer to as the intrinsic shape of an object and describe an algorithm, BLAISER, to recover it. The intrinsic shape is invariant to affine-permutation distortions. It is a uniquely defined representative of the equivalence class of all affine-permutation distortions of the same object. BLAISER computes the intrinsic shape from any arbitrarily affine-permutation distorted image of the object, without prior knowledge regarding the distortions or the undistorted shape of the object. The critical step of BLAISER is the determination of the shape orientation and we provide a detailed discussion on this topic. The operations of BLAISER are based on low-order moments of the input shape and, thus, robust to error and noise. Examples illustrate the performance of the algorithm.     

Influence of Rheological Behavior of Purely Viscous Fluids on Analytical Residence Time Distribution in Straight Tubes

In an effort to better understand the homogeneity of heat treatment of foodstuffs in holding tubes, the cumulative residence time distribution function is derived for a Herschel‐Bulkley fluid from fully developed laminar flow in a straight circular tube under isothermal conditions when diffusional effects are negligible. The proposed analytical solution can be reduced to solutions for Newtonian, shear‐thinning, dilatant, Bingham fluids by setting particular rheological parameters, and consequently, it is possible to successfully explain the dependence of residence time distribution on fluid properties for almost all of the rheological models used for time‐independent purely viscous fluids.     

RNA Relics and Origin of Life

A number of small RNA sequences, located in different non-coding sequences and highly preserved across the tree of life, have been suggested to be molecular fossils, of ancient (and possibly primordial) origin. On the other hand, recent years have revealed the existence of ubiquitous roles for small RNA sequences in modern organisms, in functions ranging from cell regulation to antiviral activity. We propose that a single thread can be followed from the beginning of life in RNA structures selected only for stability reasons through the RNA relics and up to the current coevolution of RNA sequences; such an understanding would shed light both on the history and on the present development of the RNA machinery and interactions. After presenting the evidence (by comparing their sequences) that points toward a common thread, we discuss a scenario of genome coevolution (with emphasis on viral infectious processes) and finally propose a plan for the reevaluation of the stereochemical theory of the genetic code; we claim that it may still be relevant, and not only for understanding the origin of life, but also for a comprehensive picture of regulation in present-day cells.     

Electrochemical and morphological characterization of poly(12-pyrrol-1′-yl dodecanoic acid)

12-Pyrrol-1′-yl dodecanoic acid was prepared and electrochemically polymerized on ITO electrodes by three different methods. The electrochemical and morphological properties of poly(12-pyrrol-1′-yl dodecanoic acid) films were investigated by cyclic voltammetry, galvanostatic charge–discharge curves and AFM, which characteristics varied as function of deposition method. Films deposited by potentiodynamic and galvanostatic methods showed capacitive properties and are promising for application in polymeric capacitors.     

Palladium and Molybdenum Mono and Bimetallic Catalysts on Modernite for Direct NO Decomposition Reaction

Palladium and/or molybdenum catalysts supported on mordenite were prepared and characterized by XRD, UV–vis, DRS, textural properties analysis, TPR, TPD and chemical analysis. The Mo-catalyst rapidly deactivated after the first minutes reaction. The Pd-catalysts were active in the NO decomposition reactions. The incorporation of Mo in the Pd-catalysts improved their catalytic properties.     

Computer-based automation of concentration measurements with ion-selective electrodes

An integrated computer system consisting of an expandable ionanalyzer and a PC has been used to automate concentration measurements with ion-selective electrodes (ISEs). The ionanalyzer determines ionic concentrations using a reference electrode coupled with an ISE. The measurements and calibrations are carried out in a thermostated sample changer equipped with a flow cell. The data obtained by the ionanalyzer are sent via a standard RS 232-C interface to a microcomputer. In this paper, we describe the automatic data acquisition system and the subsequent processing of the measurements. One program (Transorion) automatically collects the measurements carried out by the ionanalyzer, giving a real-time graphic representation of the measurement on the computer screen. A second program (Graforion) facilitates the management of the data stored by the first program, and listing and graphics of these can be obtained on the printer/plotter. The method has been used to study continuous concentration changes in an aqueous solution of potassium iodide.