System Identification of Base-Isolated Building using Seismic Response Data

Due to the complex nature of the excitation, and the inherent dynamics characteristics of restoring force of the base isolation systems, the response of base-isolated structures subject to strong earthquakes often experiences excursion into the inelastic range. Therefore, in designing base-isolated structures, the nonlinear hysteretic restoring force model of the base isolation system is frequently used to predict structural response and to evaluate structural safety. In this paper, the prediction error method system identification technique is used in conjunction with nonlinear state-space models for identification of a base-isolated structure. Using a variety of nonlinear restoring force models and bidirectional recorded seismic responses, several identification runs are conducted to evaluate the accuracy of the selected models. Several nonlinear restoring force models are utilized for the base-isolation system, including a multiple shear spring (MSS) model. Among all models used, results indicate that the trilinear hysteretic MSS model closely matches the actual hysteretic restoring force profile and time histories obtained directly from the observed data.     

Diverting Electron Fluxes to Hydrogen in Mixed Anaerobic Communities Fed with Glucose and Unsaturated C18 Long Chain Fatty Acids

Hydrogen (H2) production was maximized and methane (CH4) formation was minimized in a mixed anaerobic culture which was maintained at 21°C and fed glucose plus unsaturated long chain fatty acids (LCFAs). The initial pH in the batch reactors was 7.8±0.2. The two LCFAs under consideration included linoleic acid (LA) (two C=C bonds) and oleic acid (OA) (one C=C bond). Hydrogen production was observed when glucose was injected on Day 0 and again after Day 4. The H2 yield in cultures fed LA was less than those receiving OA. The H2 yield reached a maximum of approximately 1.1?mol?H2?mol?1 glucose when the LA level was 2,000?mg?L?1. In the case of OA, a maximum yield of 1.3?mol?H2?mol?1 glucose was attained with 2,000?mg?L?1. The inhibition caused by the addition of LA or OA diverted a fraction of electrons toward proton reduction. Under maximum H2 production conditions in the LA fed cultures the acetate production pathway was repressed, while in cultures fed OA the acetate pathway was dominant. The amount of CH4 produced decreased with increasing H2 production and the major volatile fatty acids detected were acetate, propionate and butyrate. Small quantities of formate were detected only in cultures fed LA after the first glucose injection. As the LCFA concentration increased, the initial glucose degradation rate decreased.     

Pd(0)-<Emphasis Type="Italic">S</Emphasis>-methylisothiourea grafted onto mesoporous MCM-41 and its application as heterogeneous and reusable nanocatalyst for the Suzuki,Stille and Heck cross coupling reactions

In this project palladium (0) S-methylisothiourea was grafted into MCM-41 mesoporous silica. Palladium (0) S-methylisothiourea complex supported on MCM-41 (Pd(0)-SMT-MCM-41), as heterogeneous and reusable catalyst, was used in C–C bond formation between various aryl halides with sodium tetraphenylborate or phenylboronic acid (Suzuki reaction), aryl halides with triphenyltin chloride (Stille reaction), and aryl halides with styrene or n-butyl acrylate (Heck reaction). This catalyst was characterized by various physico-chemical techniques such as X-ray diffraction, transmission electron microscopy, scanning electron microscopy (SEM/EDX), thermal gravimetric analysis (TGA/DTA), fourier transform infrared spectroscopy and inductively coupled plasma. The results indicated that Pd(0)-SMT-MCM-41 catalyst could be easily recovered from reaction mixture for several consequence runs without significant loss of its catalytic activities.     

First-passage study and stationary response analysis of a BWB hysteresis model using quasi-conservative stochastic averaging method

The quasi-conservative stochastic averaging (QCSA) method is applied to a Bouc-Wen-Baber hysteretic system (BWB) under Gaussian white noise excitations. The stationary probability density of the system's response amplitude and energy is obtained for different excitation levels and different damping ratios. These results are compared with the studies presented by Cai and Lin in A New Solution Technique for Randomly Excited Hysteretic Structures, Technical Report on Grant No. NCEER-88-0012, State University of New York, Buffalo, NY, 1988. The first-passage time problem for the hysteretic system is also studied using the method of QCSA. The results for the expected time to failure as a function of the initial total energy are shown, for different excitation levels and for different threshold values of energy. The relationship between the expected time to failure when initial total energy is zero and excitation level is shown for a wide range of hysteresis shape parameters.     

An optimum selection strategy of reflective cracking mitigation methods for an asphalt concrete overlay over flexible pavements

Reflective Cracking (RC) has been a daunting challenge in pavement maintenance and rehabilitation (M&R), yet, still, after several decades of research, no exclusive solution prevails. Moreover, RC mitigation methods have shown significant variation in in situ performance. Therefore, a technique tailored to select an effective RC mitigation method is essential for the success of pavement M&R. In this study, a life cycle cost (LCC) and multi-criteria decision-making (MCDM) analyses were conducted to evaluate the effectiveness of currently available RC mitigation methods and to select the optimal method for an asphalt concrete overlay above flexible pavements. The MCDM includes three components: LCC, performance, and materials (recyclability). These criteria determine the selection ranking of each RC mitigation method. In addition, the effects of the priority level including cost, performance, and recyclability on the final decision were evaluated by conducting a series of sensitivity analysis under multiple scenarios; therefore, weight combination of the three criteria were recorded to define the measurements affecting the final decision.     

Effect of Zataria multiflora Boiss. essential oil and nisin on Salmonella typhimurium and Staphylococcus aureus in a food model system and on the bacterial cell membranes

The effects of different concentrations of Zataria multiflora Boiss. essential oil (EO: 0, 5, 15 and 30 μl 100 ml⁻¹) and nisin (N: 0, 0.25 and 0.5 μg ml⁻¹), temperatures (T: 25 and 8 °C), and storage times (up to 21 days) on growth of Salmonella typhimurium and Staphylococcus aureus in a commercial barley soup were evaluated in a factorial design study. The growth of S. typhimurium was significantly (P < 0.05) decreased by EO concentrations and their combinations with N concentrations at 8 °C. For S. aureus, the viable count was significantly (P < 0.05) inhibited by EO and N concentrations and their combinations, incubated at both storage temperatures. The mechanism of the antimicrobial action of EO, N, and their combinations against cell membranes of the tested organisms were also studied by measurement of the release of cell constituents and by the electronic microscopy observations of the cells. The significant increase of the cell constituents’ release of both organisms was observed as a result of treatments with EO and EO in combination with N. Electronic microscopy observations revealed that the cell membranes of S. typhimurium treated by EO and EO in combination with N were significantly damaged, while cells treated with only N looked similar to untreated cells. The electron micrographs of treated cells of S. aureus with EO, N, and their combination also showed important morphological damages and disrupted membranes.     

Characterization of semipurified enterocins produced by Enterococcus faecium strains isolated from raw camel milk

Food safety has become an issue of great interest worldwide. Listeria monocytogenes is a food-borne pathogen that causes listeriosis and is difficult to control in the dairy industry. The use of lactic acid bacteria (LAB) and their antimicrobial substances against Listeria is promising in food applications. Here, we report the isolation from raw camel milk of LAB displaying antilisterial activity. Two isolates were selected for their secretion of bacteriocin(s) and identified by 16S rRNA sequencing as Enterococcus faecium S6 and R9. The produced bacteriocins were partially purified by ammonium sulfate precipitation and then biochemically characterized. Antimicrobial activity was estimated to be 6,400 and 400 AU (arbitrary units)/mL for E. faecium S6 and R9, respectively. The proteinaceous nature of the bacteriocins was confirmed via enzymatic reactions. Moreover, lipolytic and glycolytic enzymes completely inactivated the antimicrobial effect of the bacteriocins. These bacteriocins were heat-resistant and stable over a wide range of pH (2.0 to 10.0). To confirm its inactivation by lipolytic and glycolytic enzymes, the bacteriocin of E. faecium S6 was further purified by gel filtration, which suggested the existence of carbohydrate and lipid moieties. In addition, enterocin-coding genes were identified by PCR, showing DNA fragments corresponding in size to enterocins A, B, and P for E. faecium S6 and to enterocins B and P for E. faecium R9. In conclusion, these results indicate that partially purified bacteriocins from E. faecium S6 and R9 may be beneficial in controlling Listeria in the dairy industry.