全文获取类型
收费全文 | 549篇 |
免费 | 36篇 |
国内免费 | 7篇 |
专业分类
电工技术 | 13篇 |
综合类 | 2篇 |
化学工业 | 150篇 |
金属工艺 | 23篇 |
机械仪表 | 23篇 |
建筑科学 | 35篇 |
矿业工程 | 3篇 |
能源动力 | 37篇 |
轻工业 | 23篇 |
水利工程 | 7篇 |
石油天然气 | 7篇 |
无线电 | 54篇 |
一般工业技术 | 104篇 |
冶金工业 | 35篇 |
原子能技术 | 2篇 |
自动化技术 | 74篇 |
出版年
2024年 | 1篇 |
2023年 | 8篇 |
2022年 | 18篇 |
2021年 | 35篇 |
2020年 | 27篇 |
2019年 | 35篇 |
2018年 | 41篇 |
2017年 | 39篇 |
2016年 | 31篇 |
2015年 | 32篇 |
2014年 | 30篇 |
2013年 | 60篇 |
2012年 | 39篇 |
2011年 | 34篇 |
2010年 | 24篇 |
2009年 | 27篇 |
2008年 | 16篇 |
2007年 | 11篇 |
2006年 | 7篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 4篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 12篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 6篇 |
1992年 | 1篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1985年 | 2篇 |
1983年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1970年 | 2篇 |
1969年 | 1篇 |
排序方式: 共有592条查询结果,搜索用时 15 毫秒
61.
The enantiomers of five racemic anaesthetic drugs were resolved with cyclodextrins using capillary zone electrophoresis. Parameters which affected the chiral resolution, such as type and concentration of cyclodextrin, temperature, and addition of organic modifier were investigated. The results show that the enantiomeric discrimination of the solutes is influenced by the structural shape of the solute molecules, separation temperature, and type of cyclodextrin. It was found that alpha-cyclodextrin was the best enantioselector for resolution of prilocaine and ketamine, while the enantiomers of mepivacaine, ropivacaine, and bupivacaine were resolved with beta-cyclodextrin and/or modified beta-cyclodextrins, i.e., methyl- and 2-hydroxypropyl-beta-cyclodextrin, as chiral selectors. The length of the alkyl chain on the amino group of the drug molecule had a strong effect on the enantioresolution of mepivacaine, ropivacaine, and bupivacaine. Baseline separation of racemic ketamine was achieved with alpha- and methyl-beta-cyclodextrin at 15 degrees C. Addition of 5 M urea to the running buffer containing beta-cyclodextrin at high concentrations resulted in the enantioseparation of prilocaine, mepivacaine, and ketamine. Enantioresolution was improved upon the addition of 10% methanol to the buffer containing urea and beta-cyclodextrin. Generally, the complex formed between the S-enantiomers and modified beta-cyclodextrins was stronger than the corresponding R-forms. An exception was prilocaine where the R-form gave a more stable complex both with alpha- and beta-cyclodextrin. 相似文献
62.
TW McCloskey S Bakshi S Than P Arman S Pahwa 《Canadian Metallurgical Quarterly》1998,92(11):4230-4237
Lymphocytes of human immunodeficiency virus (HIV)-infected individuals undergo accelerated apoptosis in vitro, but the subsets of cells affected have not been clearly defined. This study examined the relationship between lymphocyte phenotype and apoptotic cell death in HIV-infected children by flow cytometry. Direct examination of the phenotype of apoptotic lymphocytes was accomplished using a combination of surface antigen labeling performed simultaneously with the Tdt mediated Utp nick end-labeling (TUNEL) assay. In comparison to live cells, apoptotic lymphocytes displayed an overrepresentation of CD45RO and HLA-DR expressing cells, while CD28 and CD95 expressing cells were underrepresented. Lymphocytes expressing CD4, CD8, and CD38 were equally represented in apoptotic and live populations. When percent lymphocyte apoptosis follow- ing culture was examined independently with lymphocyte subsets in fresh blood, apoptosis was negatively correlated with the percentage of CD4 cells, but not with specific CD4 T-cell subsets. Although not correlated with the percentage of total CD8 cells, apoptosis was positively correlated with specific CD8 T-cell subsets expressing CD45RO and CD95 and negatively correlated for CD8 T cells expressing CD45RA. These results provide direct evidence that a population of activated lymphocytes with the memory phenotype lacking the costimulatory molecule CD28 are especially prone to undergo apoptosis. The findings related to CD95 expression in fresh and apoptotic cells implicate Fas-dependent and Fas-independent pathways of apoptosis in HIV disease in children. 相似文献
63.
Objectionable vibrations have been experienced in modern tall buildings. To alleviate the vibrations one may increase the structural stiffness and damping or use a passive control device such as a ‘tuned mass damper’. The drawback of the above mentioned methods is the greatly increased cost. An alternative approach is to use active control devices providing control forces based on the feed back control theory. This paper presents a systematic approach of first reducing a multistorey structure to a simpler equivalent system. Then a pole placement method is developed to obtain the conrol forces. A successive approximation method is used to reduce the responses to permissible magnitudes. An example is presented to demonstrate the feasibility of the method. 相似文献
64.
Maryam Afsharpour Alireza Mahjoub Mostafa M. Amini 《Journal of Inorganic and Organometallic Polymers and Materials》2009,19(3):298-305
Novel layered materials based on molybdenum oxide have been synthesized using three amino-carboxylate ligands; terephetalic
acid, p-aminobezoic acid and diaminobenzene. On the basis of X-ray diffraction, scanning electron microscopy, thermogravimetry, and
infrared results, the insertion of organic ligands into the interlayer space of molybdenum oxide has been proposed. Moreover,
the influence of organic guests on the oxide structure and also their catalytic performance are discussed. Furthermore, fabrication
of the nanostructured molybdenum oxide is achieved by calcinations of these hybrid materials at 600 °C. Somewhat oriented
nanoplatelets are viewed with different catalytic activity. 相似文献
65.
Neda Hashemipour Javad Karimi-Sabet Kazem Motahari Saeed Mahruz Monfared Younes Amini Mohammad Ali Moosavian 《中国化学工程学报》2019,27(8):1745-1755
In this article,numerical simulations are performed to investigate the performance of the thermal diffusion column for the separation of n-heptane/benzene mixture.The present work tried to optimize column by analyzing significant parameters such as feed flow rate,temperature and cut.In order to obtain the hydrodynamic and temperature and mass distribution inside thermal diffusion column,computational fluid dynamic(CFD) method is applied to solve the Navier-Stocks equations.Numerical simulations are conducted to study the main parameters in both stationary and time-dependent conditions.By using the separation work unit as a function of cut,the optimal cut for maximum SWU occurs within a limited range of 0.47-0.5 for feed rate between 0.5 and 4 g min-1.Our findings reveal that the optimum feed rate in the range of optimum cut is about 1 g min~(-1).In transient study,results show that the best cut for reaching to steady-state condition is θ=0.5. 相似文献
66.
Ali Akbari Nasser Arsalani Bagher Eftekhari-Sis Mojtaba Amini Gholamreza Gohari Esmaiel Jabbari 《Frontiers of Chemical Science and Engineering》2019,13(3):563-573
Octavinyl polyhedral oligomeric silsesquioxane (POSS) was polymerized on the surface of Fe3O4 nanoparticles (NPs) and then the NPs were functionalized with carboxylic acid groups using thiol-ene click reactions with thioglycolic acid.The as-prepared Fe3O4@POSS-COOH magnetic hybrid NPs had mesoporous structures with an average particle diameter of 15 nm and a relatively high specific surface area of 447 m^2· g^-1.Experimental results showed that 4 mg of Fe3O4@POSS-COOH NPs efficiently adsorbed and removed methylene blue from water at 5 min.This is due to the presence of both carboxylic acid and pendant vinyl groups on the Fe3O4@POSS-COOH NPs.These NPs could be easily withdrawn from water within a few seconds under moderate magnetic field and showed high stability in acid and alkaline aqueous mediums. 相似文献
67.
Stefan Panglisch Arman Kouchaki Shalmani Martin Weber Oliver Gronwald Peter Berg Martin Heijnen Michaela Krug Marcel Koti Andreas Nahrstedt Volker Abetz Ulrich A. Handge Lara Grünig Mathias Ulbricht Inga Stratmann 《化学,工程师,技术》2019,91(8):1162-1167
Within the framework of the MABMEM research project, new high‐performance membranes are being developed for sustainable water management. The performance of the membranes will be evaluated in comparative and standardized fouling tests as well as in terms of the removal of trace impurities on a laboratory scale. Seven candidates are currently being tested in demonstrator trials with real‐water matrix in a waterworks for the direct treatment of dam water without prior coagulation over a period of 6 months. Subsequently, the new membrane materials will be operated with the effluent of a wastewater treatment plant. 相似文献
68.
Gholam Hossein Majzoobi Shahab H. Amini Nejad Seyed Ali Reza Sabet 《Polymer Engineering and Science》2019,59(8):1636-1647
Strain rate has significant effect on mechanical behavior of the thermoset polymers. The rate sensitivity is more complicated for thermoset nanocomposites, which compose of two quite different types of materials. Nanofiller‐reinforced epoxy resin is widely used in the industry. In the present work, epoxy resin is reinforced by 0.05 to 0.7 wt% nanographene oxide (GO). The strain rate sensitivity of the fabricated nanocomposites is investigated through compressive test carried out at the strain rates of 0.001–1,900 s?1. The stress–strain curves of the nanocomposites indicated considerable difference between the low‐strain and high‐strain‐rate responses of the specimens. The results showed that the compressive strength of the nanocomposites was improved by more than 100% at high strain rates with respect to the low strain rates. Also, the addition of nano‐GO had influence on compressive strength enhancement but not as significant as the effect of strain rate. It was observed that the effect of GO was less important for higher strain rates. The experimental compressive strength and modulus of elasticity of the nanocomposites were casted in empirical relations for low and high strain rates for various filler weight percentages. Scanning electron microscopy was also used to examine the quality of GO dispersion. POLYM. ENG. SCI., 59:1636–1647 2019. © 2019 Society of Plastics Engineers 相似文献
69.
Amini M Abbaspour KC Berg M Winkel L Hug SJ Hoehn E Yang H Johnson CA 《Environmental science & technology》2008,42(10):3669-3675
Contamination of groundwaters with geogenic arsenic poses a major health risk to millions of people. Although the main geochemical mechanisms of arsenic mobilization are well understood, the worldwide scale of affected regions is still unknown. In this study we used a large database of measured arsenic concentration in groundwaters (around 20,000 data points) from around the world as well as digital maps of physical characteristics such as soil, geology, climate, and elevation to model probability maps of global arsenic contamination. A novel rule-based statistical procedure was used to combine the physical data and expert knowledge to delineate two process regions for arsenic mobilization: "reducing" and "high-pH/ oxidizing". Arsenic concentrations were modeled in each region using regression analysis and adaptive neuro-fuzzy inferencing followed by Latin hypercube sampling for uncertainty propagation to produce probability maps. The derived global arsenic models could benefit from more accurate geologic information and aquifer chemical/physical information. Using some proxy surface information, however, the models explained 77% of arsenic variation in reducing regions and 68% of arsenic variation in high-pH/oxidizing regions. The probability maps based on the above models correspond well with the known contaminated regions around the world and delineate new untested areas that have a high probability of arsenic contamination. Notable among these regions are South East and North West of China in Asia, Central Australia, New Zealand, Northern Afghanistan, and Northern Mali and Zambia in Africa. 相似文献
70.
A new, sensitive, and low cost solid-phase extraction method using pyridine-functionalized MCM-48 mesoporous silica for the extraction, pre-concentration, and electrothermal atomic absorption spectrometric determination of nickel and lead in food samples at ng mL−1 levels is described herein. The levels of nickel and lead in different types of vegetables grow in Shiraz–Iran and Rafsanjan–Iran were determined by electrothermal atomic absorption spectrometry. The use of two standard reference materials and also comparing the results to a standard reference procedure ensured the accuracy of this method. Factors, such as flow rate of extraction, and the type, pH, concentration, and volume of eluent, were appraised. The effect of various ions on recovery was also investigated. Detection limits of 0.11 and 0.14 ng mL−1 were obtained for lead and nickel, respectively. 相似文献