Atmospheric-pressure dielectric barrier discharge generation by a full-bridge flying capacitor multilevel inverter

A new configuration of a resonant full-bridge flying capacitor multicell inverter has been designed and constructed with the aim of achieving an extended output voltage frequency range with low harmonic distortion and reduced semiconductor commutation losses. This configuration was tested as a power supply for two different coaxial dielectric barrier discharge reactors, one of them employed for electric characterization and the other one for inorganic compound elimination in an aqueous solution. Two different gas mixtures, 90% Ar–10% O_2 and80% Ar–20% O_2, were individually supplied during the experiments; the results showed a highefficiency removal of meta-cresol(m-cresol) to the order of 98%, which was obtained by adding more oxygen to the plasma gas mixture.     

Influence of very long aging on the relaxation behavior of flame‐retardant printed circuit board epoxy composites under mechatronic conditions

Very long aging times, up to 15,100 h (629 days) at 110°C, were achieved on flame‐retardant printed circuit board laminates commonly used in automotive design. This composite was fabricated from glass fibers embedded in an epoxy resin. Aging was performed in an oven under an air atmosphere at a temperature lower than the glass‐transition temperature. Temperature‐modulated differential scanning calorimetric analysis was used to investigate the influence of such aging on the glass‐transition phenomena. A new amorphous phase appeared during aging. By extending the analysis to samples collected at different thicknesses, we demonstrated the existence of a time‐dependent gradient of the properties. A skin–core structure was evidenced, and this slowed down oxidation and allowed physical aging to occur in the bulk sample. An exponential law described the variations of the glass‐transition of the new external compound. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 786‐792, 2013     

Synergistic photoluminescent interaction of Si and CdTe quantum dots

Microsystem Technologies - We report the synergistic photoluminescent effect observed in heterogeneous colloidal solutions comprising different volumetric concentrations of Si and CdTe quantum dots...     

The topographic normalization of hyperspectral data: implications for the selection of spectral end members and lithologic mapping

Compact Airborne Spectrographic Imager (CASI) hyperspectral data is used to investigate the effects of topography on the selection of spectral end members, and to assess whether the topographic correction improves the discrimination of rock units for lithologic mapping. A publicly available Digital Elevation Model (DEM), at a scale of 1:50,000, is used to model the radiance variation of the scene as a function of topography, assuming a Lambertian surface. Skylight is estimated and removed from the airborne data using a dark object correction. The CASI data is corrected on a pixel-by-pixel basis to normalize the scene to a uniform solar illumination and viewing geometry. The results show that topography has the effect of expanding end member clusters at times resulting in the overlap of clusters and that the correction process can effectively reduce the variation in detected radiance due to changes in local illumination. When topographic effects are embedded in the hyperspectral data, methods typically used for the selection of end members, such as the convex hull method, can miss end members or result in the selection of nonrepresentative pixels as end members. Thus, end members selected by some conventional methods are very likely “incomplete” or “nonrepresentative” if the topographic effect is embedded in the data. As shown in this study, the topographic correction can reveal hidden end members and achieve a better representation of end members via the statistical center of isolated clusters.     

Phenylvinilbisquinolines as fluorescent markers in functionalized polypropylene films

Polymer Bulletin - In this work, polypropylene films (PP) and maleic anhydride graft polypropylene (PPgMA) at different concentrations of a photoluminescent dye 2,2′-(1,4-phenylenedivinylene)...     

Periodic-like words, periodicity, and boxes

We introduce the notion of periodic-like word. It is a word whose longest repeated prefix is not right special. Some different characterizations of this concept are given. In particular, we show that a word w is periodic-like if and only if it has a period not larger than , where is the least non-negative integer such that any prefix of w of length $\geq R'_{w}$ is not right special. We derive that if a word w has two periods , then also the greatest common divisor of p andq is a period ofw. This result is, in fact, an improvement of the theorem of Fine and Wilf. We also prove that the minimal period of a word w is equal to the sum of the minimal periods of its components in a suitable canonical decomposition in periodic-like subwords. Moreover, we characterize periodic-like words having the same set of proper boxes, in terms of the important notion of root-conjugacy. Finally, some new uniqueness conditions for words, related to the maximal box theorem are given. Received: 10 July 2000 / Accepted: 24 January 2001     

Numerical Investigation of Engineering Systems: Analysis of Accuracy Reduction Due to Model Oversimplification

When faced with the mathematical modeling of any engineering system, whether for design, performance assessment, optimization, or control, the engineer has to determine the level of accuracy versus the simplicity of the mathematical formulation. Although it is universally accepted that the more complex the formulation, the more accurate the results will be, these usually come at the expense of larger CPU times, a substantial amount of computer resources, and are generally limited by the capacity of computers and computing power, which most times precludes their use in favor of simpler models. Many times, however, engineers do not realize the potential risk that oversimplification of a problem generates in terms of accuracy of the results; that is, the model solution does not resemble the system behavior. Through a demonstrative example, the present study addresses the issue of oversimplification of the resulting mathematical model and the corresponding accuracy of its solution. After constructing three sets of models of the physical system, each with a different level of detail, the solutions are then compared to experimental data. The results show that the accuracy of the numerical approximation depends directly on the level of complexity of the mathematical model used, and that oversimplification may result in up to a ninefold degradation of the results. In addition, minor changes in the inlet boundary condition and geometry result in significant changes in the flow pattern, up to a fivefold difference between different models in the recirculation bubble relative error. This information is fundamental for engineering professionals to consider during the modeling process in applications.     

Optimization by lumped control of reactors with langmuir-hinshelwood catalyst deactivation

A method is proposed for solving the problem of temperature optimal control in tubular fixed-bed reactors with reaction systems described by Langmuir-Hinshelwood-Hougen-Watson kinetic equations. The optimization problem is formulated by N state differential equations corresponding to the N differential fixed-bed reactors in which the integral reactor is divided. It is solved using the control vector parameterization computational technique. The proposed method when applied to a simple reaction system reported previously in the literature gives analogous results, and thus validates the theory. This theory is applied to the dehydrogenation of benzyl alcohol to benzaldehyde. An analysis of optimality problem shows a strong influence of the temperature dependence of the ratio of reaction rate to deactivation reaction rate on the optimal policy.     

CO-gasification of pelletized wood residues

A pelletization process was designed which produces cylindrical pellets ∼8 mm in length and 4 mm in diameter. These ones were manufactured using a blend of Pinus Patula and Cypress sawdust and coal in proportions of 0%, 5%, 10%, 20%, and 30% v/v of coal of rank sub-bituminous extracted from the Nechí mine (Amagá-Antioquia). For this procedure, sodium carboxymethyl cellulose (CMC) was used as binder at three different concentrations. The co-gasification experiments were carried out with two kinds of mixtures, the first one was composed of granular coal and pellets of 100% wood and the second one was composed of pulverized wood and granular coal pellets. All samples were co-gasified with steam by using an electrical heated fluidized-bed reactor, operating in batches, at 850 °C. The main components of the gaseous product were H₂, CO, CO₂, CH₄, and N₂ with approximate quantities of 59%, 6.0%, 20%, 5.0%, and 9.0% v/v, respectively, and the higher heating values ranged from between 7.1 and 9.5 MJ/Nm³.