Introducing the energy efficiency map of lithium‐ion batteries

The charge, discharge, and total energy efficiencies of lithium‐ion batteries (LIBs) are formulated based on the irreversible heat generated in LIBs, and the basics of the energy efficiency map of these batteries are established. This map consists of several constant energy efficiency curves in a graph, where the x‐axis is the battery capacity and the y‐axis is the battery charge/discharge rate (C‐rate). In order to introduce the energy efficiency map, the efficiency maps of typical LIB families with graphite/LiCoO₂, graphite/LiFePO₄, and graphite/LiMn₂O₄ anode/cathode are generated and illustrated in this paper. The methods of usage and applications of the developed efficiency map are also described. To show the application of the efficiency map, the effects of fast charging, nominal capacity, and chemistry of typical LIB families on their energy efficiency are studied using the generated maps. It is shown how energy saving can be achieved via energy efficiency maps. Overall, the energy efficiency map is introduced as a useful tool for engineers and researchers to choose LIBs with higher energy efficiency for any targeted applications. The developed map can be also used by energy systems designers to obtain accurate efficiency of LIBs when they incorporate these batteries into their energy systems.     

Optimization of Split Keyboard Design for Touchscreen Devices

While many large touchscreen devices have a split keyboard option to enable two-thumb typing, there are significant differences in the design which affect users’ text entry rate. A mixed-integer programming model is developed to optimize key-to-thumb assignment with the objective of minimizing the expected time to type a character. Computer simulations are conducted to determine the optimal key dimension under different values of the Fitts’ law’s slope coefficient, typing error rate, and alternate-hand advantage phenomenon. The results show that text entry rate and the optimal key-to-thumb assignment depend on key dimensions, user’s speed-accuracy profile, and the level of alternate-hand advantage. The optimal keyboard is proposed. To validate the analytical findings, an empirical study is conducted with eighteen users and six different keyboards in terms of key dimensions and typing zone. Empirical results report between 7% and 18% improvement in the text entry rate over the other split keyboards tested.     

A DASH-based HEVC multi-view video streaming system

Recent advancement in cameras and image processing technology has generated a paradigm shift from traditional 2D and 3D video to multi-view video (MVV) technology, while at the same time improving video quality and compression through standards such as high efficiency video coding (HEVC). In multi-view, cameras are placed in predetermined positions to capture the video from various views. Delivering such views with high quality over the Internet is a challenging prospect, as MVV traffic is several times larger than traditional video, since it consists of multiple video sequences, each captured from a different angle, requiring more bandwidth than single-view video to transmit MVV. In addition, the Internet is known to be prone to packet loss, delay, and bandwidth variation, which adversely affect MVV transmission. Another challenge is that end users’ devices have different capabilities in terms of computing power, display, and access link capacity, requiring MVV to be adapted to each user’s context. In this paper, we propose an HEVC multi-view system using Dynamic Adaptive Streaming over HTTP to overcome the above-mentioned challenges. Our system uses an adaptive mechanism to adjust the video bit rate to the variations of bandwidth in best effort networks. We also propose a novel scalable way for the multi-view video and depth content for 3D video in terms of the number of transmitted views. Our objective measurements show that our method of transmitting MVV content can maximize the perceptual quality of virtual views after the rendering and hence increase the user’s quality of experience.     

A population game approach for dynamic resource allocation problems

We consider a water distribution system as an example of resource allocation, and investigate the use of a population game for its control. We use a game-theoretic approach based on two evolutionary dynamics, the Brown–von Neumann–Nash and the Smith dynamics. We show that the closed-loop feedback interconnection of the water distribution system and the game-theoretic-based controller has a Nash equilibrium as an asymptotically stable equilibrium point. The stability analysis is performed based on passivity concepts and the Lyapunov stability theorem. An additional control subsystem is considered for disturbance rejection. We verify the effectiveness of the method by simulations under different scenarios.     

Fibril density reduction in keratoconic corneas

This study aims to estimate the reduction in collagen fibril density within the central 6 mm radius of keratoconic corneas through the processing of microstructure and videokeratography data. Collagen fibril distribution maps and topography maps were obtained for seven keratoconic and six healthy corneas, and topographic features were assessed to detect and calculate the area of the cone in each keratoconic eye. The reduction in collagen fibril density within the cone area was estimated with reference to the same region in the characteristic collagen fibril maps of healthy corneas. Together with minimum thickness and mean central corneal refractive power, the cone area was correlated with the reduction in the cone collagen fibrils. For the corneas considered, the mean area of keratoconic cones was 3.30 ± 1.90 mm². Compared with healthy corneas, fibril density in the cones of keratoconic corneas was lower by as much as 35%, and the mean reduction was 17 ± 10%. A linear approximation was developed to relate the magnitude of reduction to the refractive power, minimum corneal thickness and cone area (R² = 0.95, p < 0.001). Outside the cone area, there was no significant difference between fibril arrangement in healthy and keratoconic corneas. The presented method can predict the mean fibril density in the keratoconic eye''s cone area. The technique can be applied in microstructure-based finite-element models of the eye to regulate its stiffness level and the stiffness distribution within the areas affected by keratoconus.     

Preparation of low-platinum-loading electrocatalysts using electroless deposition method for proton exchange membrane fuel cell systems

One promising preparative method that offers the potential for improved platinum (Pt) dispersion of electrocatalysts is electroless deposition (ED). In this study, the effects of multiwalled carbon nanotubes (MWCNTs) pretreatment and synthesis procedure on properties of the four catalysts, synthesized by ED method, have been considered. The results of energy-dispersive X-ray spectroscopy (EDS), X-ray dot-mapping, X-ray fluorescence (XRF) and cyclic voltammetry (CV) analyses showed that using palladium (Pd) precursor during two-step sensitization-activation coating procedure gives uniform Pt particles distribution on MWCNTs with low aggregation and high specific surface area (∼80 m² g⁻¹). In addition, to investigate the performance of the synthesized catalysts in experimental fuel cell system, thin-film method was used to fabricate the membrane electrode assemblies (MEAs). Obtaining the polarization curves for the fabricated MEAs (Pt loading ∼0.4 mg cm⁻²) and a commercial MEA (ElectroChem, Pt loading ∼1 mg cm⁻²) demonstrated that the catalyst prepared by two-step sensitization-activation coating procedure possesses a good performance despite of its lower Pt content.     

Palladium(II)‐Catalyzed Decarboxylative Heck Arylations of Acyclic Electron‐Rich Olefins with Internal Selectivity

Despite the recent emergence of decarboxylative C C bond forming reactions, methodologies providing internally arylated electron‐rich olefins are still lacking. We herein report on palladium(II)‐catalyzed decarboxylative Heck arylations of linear electron‐rich olefins with excellent selectivity for the internal position. The method allows a variety of electron‐rich linear olefins to undergo arylation with ortho‐functionalized aromatic carboxylic acids, including heterocycles. The reaction mechanism has been explored with ESI‐MS studies to confirm previous findings, and to reveal the formation of a highly stable palladium complex as a result of the Heck product reacting with the catalyst.