A study on dynamic rheological characterisation of electron beam crosslinked high vinyl styrene butadiene styrene block copolymer

Crosslinking of elastomers using electron beam radiation has several advantages over conventional method. It is accomplished much faster, in a more environmental friendly approach and in a much simpler manner. When fast moving electrons that are generated from electron accelerators are targeted on a polymer matrix, they primarily crosslink the polymer. However, in the process, some chain scission may also occur. In this work, a high vinyl (~50%) styrene–butadiene–styrene (S–B–S) block copolymer was used as the base polymer. Radiation doses were varied from 25 to 300 kGy. A detailed investigation was made to understand the effect of electron beam radiation on the rheological properties such as storage modulus, loss modulus, storage viscosity and complex viscosity of the block copolymer under strain and frequency sweeps performed in a Rubber Process Analyzer (RPA). Recyclability of the crosslinked S–B–S polymer was also explored by RPA and mechanical studies.     

Microfabrication and characterization of metal-embedded thin-film thermomechanical microsensors for applications in hostile manufacturing environments

Effective monitoring and diagnosis of manufacturing processes is of critical importance. If critical manufacturing process conditions are continuously monitored, problems can be detected and solved during the processing cycle. However, current technology still evidently lags behind practical needs. Microfabricated thin-film thermocouples and strain gauges are attractive for their small size and fast response. It is challenging to fabricate and embed these sensors into metallic components that are widely used in manufacturing. This paper investigates the fabrication, embedding, and characterization of metal embedded thin-film thermocouples and strain gauges. The materials (dielectric and metallic) constituting a complete microsensor were characterized and optimized. The results obtained from characterization and optimization of materials are presented and discussed. Thin-film thermocouples on stainless steel substrates (before and after embedding) were calibrated to elevated temperatures. The behavior of thin-film strain gauges was also studied. The metal embedded sensors demonstrated good accuracy, sensitivity, and linearity that matched the performance of commercial thermocouples and strain gauges well. The metal embedded microsensors are promising for in situ monitoring in hostile manufacturing environments.     

Application of the Feynman-Kac path integral method in finding excited states of quantum systems

Group theory considerations and properties of a continuous path are used to define a failure tree procedure for finding eigenvalues of the Schrödinger equation using stochastic methods. The procedure is used to calculate the lowest excited state eigenvalues of eigenfunctions possessing anti-symmetric nodal regions in configuration space using the Feynman-Kac path integral method. Within this method the solution of the imaginary time Schrödinger equation is approximated by random walk simulations on a discrete grid constrained only by symmetry considerations of the Hamiltonian. The required symmetry constraints on random walk simulations are associated with a given irreducible representation and are found by identifying the eigenvalues for the irreducible representation corresponding to symmetric or antisymmetric eigenfunctions for each group operator. The method provides exact eigenvalues of excited states in the limit of infinitesimal step size and infinite time. The numerical method is applied to compute the eigenvalues of the lowest excited states of the hydrogenic atom that transform as Γ² and Γ⁴ irreducible representations. Numerical results are compared with exact analytical results.     

A study of concurrency control in real-time, active databasesystems

Real-time active database systems (RTADBSs) have attracted a considerable amount of research attention in the past and a number of important applications have been identified for such systems, such as telecommunications network management, automated air traffic control, automated financial trading, process control and military command and control systems. In spite of the recognized importance of this area, very little research has been devoted to exploring the dynamics of transaction processing in RTADBSs. Concurrency control (CC) constitutes an integral part of any transaction processing strategy and, thus, deserves special attention. We study CC strategies in RTADBSs and postulate a number of CC algorithms. These algorithms exploit the special needs and features of RTADBSs and are shown to deliver substantially superior performance to conventional real-time CC algorithms     

Characterization of laser and laser/thermal annealed semiconducting iron silicide thin films

-FeSi₂ is an important semiconducting silicide which is being studied extensively. In this paper, we report our results of the effect of laser and laser-thermal annealing on the properties of -FeSi₂. 5N purity Fe was deposited on Si substrate and was subsequently irradiated by CW and pulsed laser separately followed by thermal annealing to reduce the laser induced damage. The samples were then characterized by sheet resistance, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), optical reflectance and absorption studies. Lastly, -FeSi₂/n-Si heterojunctions were fabricated and the effect of laser treatment on the junction ideality factor was investigated. All these characterizations indicated the formation of good quality -FeSi₂, particularly after pulsed laser followed by thermal treatment.     

Management Issues of a Mobile Agent-Based Service Environment

This paper introduces the concepts of a servicemanagement system for mobile agent-based services. Incontrast to several other approaches in whichagent-based applications are used to handletraditional network or service managementaspects, this paper describes a way to manage thedistributed agent environment itself. The proposedapproach was designed and developed by using OSI SystemsManagement concepts as a starting point, which are modified andadjusted in order to fulfill the new requirementsassociated with the mobile agent paradigm. However, thispaper does not cover integration or co-existence of the introduced agent management system (AMS)and traditional OSI management systems. Instead, theentire AMS environment is based on mobile agenttechnology. At present, this approach is validated inthe context of the European research project MobileAgent Environments in Intelligent Networks(MARINE).     

Scanning electron microscopy and ultrasonic studies of drawn polypropylenes

Ultrasonic measurements and scanning electron microscope studies are reported on a series of drawn samples of polypropylene. The ultrasonic measurements were performed over the frequency range 15 to 35 MHz and over a temperature range 283 to 343K. The scanning electron microscope observations confirmed the predictions from density data that the ‘void’ content initially increases on drawing and then decreases. The acoustic measurements on the samples with the highest draw ratios indicated that severe restriction of the motion of the polymer occurs when the fibrous structure is formed.