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61.
Carbon fiber reinforced polymers(CFRPs) are known to be difficult to cut due to the abrasive nature of carbon fibers and the low thermal conductivity of the polymer matrix.Polycrystalline diamond(PCD) drills are commonly employed in CFRP drilling to satisfy hole quality conditions with an acceptable tool life.Drill geometry is known to be influential on the hole quality and productivity of the process.Considering the variety of CFRP laminates and available PCD drills on the market,selecting the suitable drill design and process parameters for the CFRP material being machined is usually performed through trial and error.In this study,machining performances of four different PCD drills are investigated.A mechanistic model of drilling is used to reveal trade-offs in drill designs and it is shown that it can be used to select suitable feed rate for a given CFRP drilling process.  相似文献   
62.
The effect of heat input from laser beam welding (LBW) on the microstructural evolution of superalloy Inconel 718 was investigated. LBW was carried out on 1.6-mm-thick sheets with an average grain size of 13 μm (ASTM # 9.5), and four different heat inputs in the range of 74.5 mm−1 to 126.6 J mm−1 were used. Full penetration was achieved in all weld experiments. Microstructures of the welds were evaluated using an optical microscope and a field emission scanning electron microscope. Increasing the heat input changed the resulting weld shape from a wine glass shape to a stemless glass shape with wider surface bead widths, and the measured average dendrite arm spacing was increased from 1.06 μm to 2.30 μm, indicating the corresponding solidification rate in the range of 1.75 × 105 K s−1 (°C s−1) to 3.5 × 106 K s−1 (°C s−1). The welds also were free from microfissuring even at the lowest heat input trials. The Nb concentration of Laves phase for the current LBW samples was ≈20.0 wt pct. The coefficients of partition and distribution for Nb were determined to be approximately 3.40 and 0.50, respectively.  相似文献   
63.
Although generally the ruthenium based homogeneous catalysts are used to initiate metathesis reactions, immobilization of homogeneous ruthenium metathesis catalysts on various solid supports has attracted a lot of interest from the scientific community in recent years. In this article, the synthesis and applications of highly active polyHIPE-supported N-heterocyclic carbene ligand (NHC)-bearing ruthenium alkylidene metathesis catalysts were described. Open-celled porous polyHIPE foams having surface area of 575 m2/g were synthesized by polymerization of the continuous phase of w/o high internal phase emulsions. Then RuCl2(PCy3)(H2IMes)(=CHPh) complex was attached to porous polyHIPE solid supports via alkylidene exchange reactions to obtain new olefin metathesis catalysts. The amount of initiator loadings was determined by ruthenium analysis via ICP-OES and found to be 0.0336–0.0514 mmol/g. Subsequently, the activity of new catalysts was tested in ring opening metathesis polymerization of norbornene and a series of its derivatives.

Graphical Abstract

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64.
In this study, an efficient numerical method is proposed for unifying the structured and unstructured grid approaches for solving the potential flows. The new method, named as the “alternating cell directions implicit - ACDI”, solves for the structured and unstructured grid configurations equally well. The new method in effect applies a line implicit method similar to the Line Gauss Seidel scheme for complex unstructured grids including mixed type quadrilateral and triangle cells. To this end, designated alternating directions are taken along chains of contiguous cells, i.e. ‘cell directions’, and an ADI-like sweeping is made to update these cells using a Line Gauss Seidel like scheme. The algorithm makes sure that the entire flow field is updated by traversing each cell twice at each time step for unstructured quadrilateral grids that may contain triangular cells. In this study, a cell-centered finite volume formulation of the ACDI method is demonstrated. The solutions are obtained for incompressible potential flows around a circular cylinder and a forward step. The results are compared with the analytical solutions and numerical solutions using the implicit ADI and the explicit Runge-Kutta methods on single-and multi-block structured and unstructured grids. The results demonstrate that the present ACDI method is unconditionally stable, easy to use and has the same computational performance in terms of convergence, accuracy and run times for both the structured and unstructured grids.  相似文献   
65.
Due to fluctuating weather conditions, estimating wind energy potential is still a significant problem. Artificial neural networks (ANNs) have been commonly used in short-term and just-in-time modeling of wind power generation systems based on main weather parameters such as wind speed, temperature, and humidity. Two different datasets called hourly main weather data (MWD) and daily sub-data (DSD) are used to estimate a wind turbine power generation in this study. MWD are based on historically observed wind speed, wind direction, air temperature, and pressure parameters. Besides, DSD created with statistical terms of MWD consist of maximum, minimum, mean, standard deviation, skewness, and kurtosis values. The main purpose of this study in particular was to develop a multilinear model representing the relationship between the DSD with the calculated minimum (P min) and maximum (P max) power generation values as well as the total power generation (P sum) produced in a day by a wind turbine based on the MWD. While simulation values of the turbine, P min, P max, and P sum, were used as the separately dependent parameters, DSD were determined as independent parameters in the estimation models. Stepwise regression was used to determine efficient independent parameters on the dependent parameters and to remove the inefficient parameters in the exploratory phase of study. These efficient parameters and simulated power generation values were used for training and testing the developed ANN models. Accuracy test results show that interoperability framework models based on stepwise regression and the neural network models are more accurate and more reliable than a linear approach.  相似文献   
66.
67.
A new magnetic fusion reactor design, called APEX uses a liquid wall between fusion plasma and solid first wall to reach high neutron wall loads and eliminate the replacement of the first wall structure during the reactor’s operation due to the radiation damage. In this paper, radiation damage behavior of the inboard and outboard first walls made of a ferritic steel, 9Cr-2WVTa, in the APEX blanket using various thorium molten salts, 75% LiF-25% ThF4, 75% LiF-24% ThF4-1% 233UF4 and 75% LiF-23% ThF4-2% 233UF4 was investigated. Furthermore, tritium breeding potential of these salts in such a blanket was also examined. Computations were carried out using the code Scale 4.3 by solving Boltzmann neutron transport equation. Numerical results brought out that only the liquid wall containing the molten salt, 75% LiF-23% ThF4-2% 233UF4 and having a thickness of ≥38 cm would be suitable to be used in the APEX reactor with respect to radiation damage criteria for the first wall structures and tritium self-sufficiency for the (DT) fusion driver.  相似文献   
68.
Four novel divalent transitional metal succinates (suc) with nicotinamide (nia), {[M(μ-suc)(H2O)2(nia)2]·2H2O} n [M = Mn (1), Ni (2)], [Cu(suc)(nia)2] (3) and [Ni(H2O)4(nia)2](suc)·(H2suc) (4), have been synthesized and characterized by elemental analyses, IR and TG-DTA. X-ray analyses of 2 and 4 reveal that they crystallize in a triclinic space group P[`1]. P\bar{1}. Complex 2 is a 1-D coordination polymer, in which the metal(II) ions exhibit an octahedral geometry with two suc, two nia and two aqua ligands. The nia ligand is N-bonded, while the suc ligand bridges the metal centres through the carboxylate groups. 4 contains the [Ni(H2O)4(nia)2]2+ complex cations, uncoordinated suc and H2suc species, which are connected into a two-dimensional layered structure by the combination of N–H⋯O and OW–H⋯O hydrogen bonds. This is one of the scarce examples encountered in coordination chemistry, which contains uncoordinated suc and H2suc at the same time. The spectroscopic and structural analysis, luminescent and magnetic properties and the antimicrobial activities of the synthesized complexes were investigated.  相似文献   
69.
In-situ diffraction experiments were performed with high-energy synchrotron X-rays to measure strains in crystalline reinforcing particles (5 and 10 vol. pct W or 5 vol. pct Ta) of bulk metallic glass composites. As the composites were subjected to multiple uniaxial tensile load/unload cycles up to applied stresses of 1650 MPa, load transfer from the matrix to the stiffer particles was observed. At low applied loads, where the particles are elastic, agreement with Eshelby elastic predictions for stress partitioning between matrix and particles is found, indicating good bonding between the phases. At high applied loads, departure from the elastic stress partitioning is observed when the particles reach the von Mises yield criterion, as expected when plasticity occurs in the particles. Multiple mechanical excursions in the particle plastic region lead to strain hardening in the particles, as well as evolution in the residual strain state of the unloaded composite.  相似文献   
70.
Auditory brainstem response (ABR) has become a routine clinical tool in neurological and audiological assessment. ABR measurement process with ensemble averaging is very time-consuming and uncomfortable for subjects due to the more repetition of single trials. This condition also restricts the wide usability of ABR in clinical applications. Therefore, the reduction in repetitions has a great importance in ABR measurements. In this study, 488 ABR responses are used for creating two different data sets. The first set is created conventionally by ensemble averaging of 1,024 single trials for each ABR pattern. The second set is obtained from the first estimated 64 single trials of the same records for each ABRs. Estimation is realized by using a nonlinear adaptive filtering algorithm. In classification stage, a powerful classifier integrated with a feature selection algorithm is performed for each data set. In result, the classification performance for estimated ABR data with 64 repetitions is better than the classification performance of the ensemble averaged data with 1,024 repetitions. The proposed system is resulted in an accuracy of 96% for estimated ABRs. So, the proposed system can effectively be used for threshold detection in auditory assessment providing a high accuracy. While the obtained results contribute to the practical ABR usage in clinics, the great significance of it arises from the reduction in repetitions via estimation of ABRs.  相似文献   
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