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611.
Reactions of dicyclohexylmethane‐4,4′‐diisocyanate (H12MDI) with 1‐ or 2‐butanol in N,N‐dimethylformamide using dibutyltin dilaurate (DBTDL), stannous octoate (SnOct), or triethylamine (TEA) as catalyst were conducted in stirred reactors at 40°C. Reactor contents were circulated through an external loop containing a temperature‐controlled FTIR transmission cell; reaction progress was monitored by observing decrease in height of the isocyanate peak at 2266 cm−1. Catalyzed reactions were second order as indicated by linear 1/[NCO] plots; uncatalyzed reactions yielded nonlinear plots. In all cases, the reaction with a primary alcohol was faster than that with a secondary alcohol. DBTDL dramatically increased the reaction rate with both primary and secondary alcohols. For [DBTDL] = 5.3 × 10−5 mol/L (300 ppm Sn) the second‐order rate constant, k, was 5.9 × 10−4 (primary OH) and 1.8 × 10−4 L/(mol s) (secondary OH); for both alcohols, this represents an increase in initial reaction rate on the order of 2 × 101 when compared with the uncatalyzed reactions. The second‐order rate constant was observed to increase linearly with DBTDL concentration in the range 100–700 ppm Sn. SnOct and TEA showed little to no catalytic activity with the primary alcohol and only a slight increase in reaction rate with the secondary alcohol. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
612.
Given a set of candidate sites, the capacitated location problem consists of finding a most economical subset of facilities to be located. This paper works with aweak formulation of the problem, having in mind the application in an economic sector with partially decentralized decision-making. The model considers the activities of production, transportation and export, looking for facility locations and distribution alternatives that satisfy the domestic demands, while minimizing the total cost. We have shown improved criteria to locate facilities, assured their optimality and given computational results. We introduce clear economic interpretation of such criteria for the decentralized behavior of the production and distribution agents, based on a pricing system associated with dual variables. Some insight is also given on the possibility of analyzing a location algorithm as a competitive and adaptive process of searching for maximal profit. Within such context, an attempt is made to define the role of government in handling the indivisibility of the production resources, in order to assure stability at an optimal solution. 相似文献
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