Dauerhaftigkeit und mechanische Stabilität von Terrassendielen bei erhöhter Temperatur – Ein Werkstoffvergleich: WPC,thermisch modifiziertes Holz und Massivholz

This article deals with the differences in the long-term durability and thermal stability under load of terrace deckings from various materials. The tested materials were deckings made of wood, thermally modified timber (TMT), and wood–polymer–composites (WPC). For the determination of the test temperatures for component testing according to EN 310, the surface temperatures of the decks during a normal hot summer day were measured. A cyclic test according to EN 321 was applied to all decking materials. Afterwards the component testing was repeated. All wooden samples reveal considerable cracks, some were twisted, and few were even broken. In particular regarding the optical appearance, wood decks show advantages against the TMT decks. Some WPC decks show very fine cracks on the face, which were additionally analyzed by means of X-ray computed tomography (CT). Except for the WPC deck with higher wood content, no WPC deck revealed significant changes after the cyclic test. The CT analysis was also suitable to find cracks inside the materials and illustrate them. Thus, the whole damage inside a sample could be characterized by calculating a kind of error pattern. No considerable cracks or failures could be observed on the WPC decks.     

Enzymatic Addition of Alcohols to Terpenes by Squalene Hopene Cyclase Variants

Squalene–hopene cyclases (SHCs) catalyze the polycyclization of squalene into a mixture of hopene and hopanol. Recently, amino-acid residues lining the catalytic cavity of the SHC from Alicyclobacillus acidocaldarius were replaced by small and large hydrophobic amino acids. The alteration of leucine 607 to phenylalanine resulted in increased enzymatic activity towards the formation of an intermolecular farnesyl–farnesyl ether product from farnesol. Furthermore, the addition of small-chain alcohols acting as nucleophiles led to the formation of non-natural ether-linked terpenoids and, thus, to significant alteration of the product pattern relative to that obtained with the wild type. It is proposed that the mutation of leucine at position 607 may facilitate premature quenching of the intermediate by small alcohol nucleophiles. This mutagenesis-based study opens the field for further intermolecular bond-forming reactions and the generation of non-natural products.     

Anonymous attestation with user-controlled linkability

This paper is motivated by the observation that existing security models for direct anonymous attestation (DAA) have problems to the extent that insecure protocols may be deemed secure when analysed under these models. This is particularly disturbing as DAA is one of the few complex cryptographic protocols resulting from recent theoretical advances actually deployed in real life. Moreover, standardization bodies are currently looking into designing the next generation of such protocols. Our first contribution is to identify issues in existing models for DAA and explain how these errors allow for proving security of insecure protocols. These issues are exhibited in all deployed and proposed DAA protocols (although they can often be easily fixed). Our second contribution is a new security model for a class of “pre-DAA scheme”, that is, DAA schemes where the computation on the user side takes place entirely on the trusted platform. Our model captures more accurately than any previous model the security properties demanded from DAA by the trusted computing group (TCG), the group that maintains the DAA standard. Extending the model from pre-DAA to full DAA is only a matter of refining the trust models on the parties involved. Finally, we present a generic construction of a DAA protocol from new building blocks tailored for anonymous attestation. Some of them are new variations on established ideas and may be of independent interest. We give instantiations for these building blocks that yield a DAA scheme more efficient than the one currently deployed, and as efficient as the one about to be standardized by the TCG which has no valid security proof.     

A socially aware caching mechanism for encounter networks

Managing community content in mobile communities is challenging, since informal groups may emerge spontaneously whenever opportunities exist. To deal with group dynamics, encounter based community support systems can be a solution. In encounter networks, peers exchange content whenever they physically meet, i.e., whenever peers are near to each other. To assure content availability within the community network, content needs to be replicated (cached) and continuously updated. A?well known drawback of this scheme is the fact that the resource usage can be quite high. In this paper we present new caching strategies based on sociological knowledge, aiming at improving the overall content quality. We derive mobility and connectivity aware cache policies and simulate their benefit for knowledge building with urban life simulations. Results show that context precision and recall can be greatly improved in comparison to traditional cache strategies applied in the majority of encounter networks.     

Privacy protection vs. utility in visual data

Multimedia Tools and Applications - Ubiquitous and networked sensors impose a huge challenge for privacy protection which has become an emerging problem of modern society. Protecting the privacy of...     

Experimentelle und simulative Untersuchungen zum Einfluss der Lageabweichungen im Nocken-Rollen-Kontakt auf die Ventiltriebskräfte

As part of a cooperation project, Daimler AG and the Institute of Machine Elements, Gears, and Transmissions (MEGT) at the Technische Universität Kaiserslautern are carrying out detailed investigations on a valve train with roller lever. The aim of the project is to develop a detailed simulation method that allows the secondary movement of the valve train to be modeled and thus represents an extension of the classic valve train dynamics simulation. This opens up the opportunity to evaluate the processes within the valve train in detail in the early stages of the product development process. This report introduces the validation of the methodology based on experimental results. First, the focus is placed on the cam-roller contact, which induces the secondary movement of the valve train. This movement takes place in the axial direction of the camshaft so that the validation takes place on the basis of the measured force in this direction. The force is dependent on the load, i.?e. the combination of speed and normal force, as well as the angular misalignments between cam and roller. Following the validation of the detailed modeling of the cam-roller contact, the gained knowledge is transferred into the extended valve train simulations. Finally the valve train simulation is validated.     

[2.2]Paracyclophane-Based TCN-201 Analogs as GluN2A-Selective NMDA Receptor Antagonists

Recent studies have shown the involvement of GluN2A subunit-containing NMDA receptors in various neurological and pathological disorders. In the X-ray crystal structure, TCN-201 ( 1 ) and analogous pyrazine derivatives 2 and 3 adopt a U-shape (hairpin) conformation within the binding site formed by the ligand binding domains of the GluN1 and GluN2A subunits. In order to mimic the resulting π/π-interactions of two aromatic rings in the binding site, a [2.2]paracyclophane system was designed to lock these aromatic rings in a parallel orientation. Acylation of [2.2]paracyclophane ( 5 ) with oxalyl chloride and chloroacetyl chloride and subsequent transformations led to the oxalamide 7 , triazole 10 and benzamides 12 . The GluN2A inhibitory activities of the paracyclophane derivatives were tested with two-electrode voltage clamp electrophysiology using Xenopus laevis oocytes expressing selectively functional NMDA receptors with GluN2A subunit. The o-iodobenzamide 12 b with the highest similarity to TCN-201 showed the highest GuN2A inhibitory activity of this series of compounds. At a concentration of 10 μM, 12 b reached 36 % of the inhibitory activity of TCN-201 ( 1 ). This result indicates that the [2.2]paracyclophane system is well accepted by the TCN-201 binding site.