The Fenno-Skan HVDC link commissioning

The commissioning of the Fenno-Skan HVDC link between Finland and Sweden, with the longest submarine DC cable in the world, is described. The main pre-commissioning activities, important for an efficient commissioning, are discussed together with time schedules and suitable organisation forms. The procedures to test special control features, such as subsynchronous oscillation (SSO) damping control are presented. The full scale network interaction tests which are an important part of the commissioning are also discussed. These tests succeeded very well and provided a lot of information about the system behaviour for future operation and planning purposes     

Effects of airway obstruction on transmural pulmonary artery pressure in exercising horses

OBJECTIVE: To determine whether laryngeal hemiplegia would increase transmural pulmonary artery pressure (TPAP). ANIMALS: 6 horses. DESIGN: Horses were studied under 5 conditions: control conditions, after induction of left laryngeal hemiplegia, during obstruction of the left nostril, after placement of an instrumented tracheostomy, and after placement of an open tracheostomy. Horses were evaluated after being given saline solution and after being given furosemide. PROCEDURES: Horses were exercised on a high speed treadmill, using a maximum speed of 13 m/s. During each exercise, airway pressures, airflow, esophageal and pulmonary artery pressures, and blood gas partial pressures were measured. RESULTS: When adjusted for horse, speed, and obstruction condition, mean TPAP (pulmonary artery pressure-esophageal pressure) and minimum TPAP were significantly lower after administration of furosemide than after administration of saline solution. In horses given saline solution, respiratory obstruction that increased intrapleural pressure significantly increased mean TPAP, and respiratory obstruction that decreased intrapleural pressure significantly decreased minimum TPAP. CONCLUSIONS: Changes in intrapleural pressure appear to play an important role in pulmonary artery pressure and TPAP. CLINICAL RELEVANCE: Because induction of laryngeal hemiplegia did not increase TPAP, laryngeal hemiplegia is unlikely to contribute to development of exercise-induced pulmonary hemorrhage.     

Some effects at ion beam modification of polymethyl methacrylate

Measurements of the sensitivity of polymethyl methacrylate to ion irradiation are presented. The results of these studies show for ion energies (40 keV—1.8 MeV) and for the heavier ions (He⁺, Ar⁺) a higher sensitivity of the resist than in H⁺, electron or X-ray exposures. The measured sensitivity shows a dependence on electronic stopping power. In order to understand this relation an electron excitation spike mechanism is suggested. This mechanism is in accordance with investigations of sputtering rate of PMMA during ion bombardment. The effects of low energy ion induced nuclear reactions in the polymer layer and in masks and wafer are also discussed.     

ZSM-5/TiO<Subscript>2</Subscript> Hybrid Photocatalysts: Influence of the Preparation Method and Synergistic Effect

In this work, the influence of the preparation method of ZSM-5/TiO₂ hybrids on the photocatalytic performance for removal of formaldehyde (HCHO) or trichloroethylene (C₂HCl₃) in gas phase was analyzed. For this purpose, two methods for the synthesis of the hybrids, the incipient wetness impregnation (I) and the mechanical mixing method (M), were selected. The photocatalysts were characterized by N₂ adsorption–desorption, TEM, UV–Vis spectroscopy, XRD and electrophoretic migration. Also, the adsorption ability of the individual materials and hybrids was analyzed. ZSM-5/TiO₂ hybrids showed higher photocatalytic activity than bare TiO₂, independently of the preparation method selected. Mechanical mixing is a simple and easily scalable method to prepare highly active photocatalyst with high amounts of titania. The internal diffusion processes of the reactants to the active sites could be improved due to the micro–mesoporous structure developed on these hybrids. Incipient wetness impregnation method leads to photocatalysts with higher photodegradation rates per active site. The hybrids synthetized by this method show TiO₂ nanoparticles homogeneously dispersed on the ZSM-5 phase. The fraction of TiO₂ exposed on the surface ca. 75 mol% was similar for materials prepared by both methods, explaining the similar adsorption and photocatalytic properties, independently of the TiO₂ content. The nature of the pollutant has an important role in the adsorption and photocatalytic properties of the composites. Finally, the effect of the incorporation of the zeolite in the photocatalytic system was analyzed. For this purpose, the influence of the zeolite and titania arrangement in the sample holder on the photodegradation rate was analyzed. Although the incorporation of the zeolite induces a positive effect on the photocatalytic performance, independently of the position on the sample holder, a clear synergistic effect when both phases were in intimate contact such as in the ZSM-5/TiO₂ hybrid was observed.     

An anomaly in the necking behavior of polyethylene,part 4

It is shown that the annealing of a high molecular weight, high density polyethylene at different temperatures ranging from 393.2 to 405.2 K influences the density of the material, the lamellar structure as studied by differential scanning calorimetry and transmission electron microscopy, and the necking and fracture behavior at constant uniaxial tensile loading in air at 313 K. In previous reports, a marked transition in the necking and fracture behavior of high density, high molecular weight polyethylene under constant uniaxial tensile loading has been reported. The nominal stress and the maximum strain rate of this transition show minima for polyethylenes annealed at temperatures of about 401 K. By combining these data with data for the lamellar structure a hypothesis that explains the necking/fracture behavior is set up. The heat treatment at temperatures from 393.2 to 403.2 K of the original non-equilibrium lamellar structure causes a molecular fractionation preferentially of low molecular weight and branched material. These segregated parts may then act as fracture initiators and thus lower the resistance towards fracture. Other structural effects such as those proposed by McCready and co-workers may also be of importance. The fracture curves at nominal stresses below transition of the materials annealed at 396.7 and 401.2 K for 24 h are shifted to shorter times in comparison with that of the non-annealed material and this can also be explained by molecular fractionation. The time to necking at 14 MPa nominal stress seems to be related to the lamellar thickness of the samples.     

Application of the trickle tower to problems of pollution control. II. The direct and indirect oxidation of cyanide

The direct and indirect oxidation of cyanide at concentrations typical of those found in plating wash water have been investigated in a bipolar trickle-tower reactor. It has been found that the oxidation by hypochlorite generatedin situ was faster than direct oxidation or oxidation in the presence of base, but that the CN^? concentration was easily reduced by any of these methods. Scaling-up experiments were performed by using different numbers of layers of bipoles, different electrolyte flow rates and different applied voltages. It is shown that the overall rate is determined by the mass-transport-limited generation of oxidant.     

Application of the trickle tower to problems of pollution control. III. Heavy-metal cyanide solutions

The destruction of CN^– and co-deposition of copper, cadmium, nickel, zinc and lead, both as simple solutions and as mixtures, have been investigated in a number of trickle towers with from 8 to 49 layers of cells. Specific chemical effects due to the formation of cyano-complexes of some of the metals are evident, and it has been found that copper, nickel and cadmium accelerate the destruction of CN^–, at least initially. For simple solutions a previously proposed scaling law is adequate.Nomenclature a length of bipolar element (cm) - c concentration (ppm) - c ⁰ initial concentration (ppm) - K mass transfer coefficient (cm s^–1) - K=K _L effective mass transfer coefficient (cm s^–1) - L wetted perimeter per layer of packing (cm) - p number of layers of cells - t time (s) - v _o volumetric flow rate (cm³ s^–1) - V inventory of solution (cm³) - _L fractional active length - _s reversible potential with respect to main counter reaction (V) - _s ^T potential applied across an element with respect to main counter reaction (V)     

Chain orientation in sheared molten poly(ethylene oxide) fractions by measurement of infrared dichroism

Rheo-infrared spectroscopy was used to study the development of orientation of molten narrow molar mass fractions of poly(ethylene oxide) [molar masses between 18,000 and 120,000 g/mol] during non-Newtonian shear flow at shear rates between 2 and 270 s^?1 and temperatures between 75 and 100°C. The steady state degree of orientation [expressed as the Hermans orientation function (f_ss)] reached a saturation level with increasing shear rate; f_ss increased with increasing molar mass (M) according to f_ss = C₁ ? C₂/M (C₁ and C₂ are coefficients; the latter depended on shear rate and temperature). The coefficient C₁ (f_ss) for a polymer with infinite molar mass took a universal value close to 0.05 for the temperatures and shear rates used. Under large shear stresses, the relationship between stress and orientation deviated markedly from linearity. The time to establish a steady state level of orientation was proportional to M^1/2. The recovery of the isotropic state after the cessation of shear could initially be described by a simple exponential relaxation law: f ∝ e, where τ_ρ is the relaxation time. The latter showed a weak molar mass dependence according to τ_r ∝ M^0.6 and an Arrhenius temperature dependence with an activation energy of ～60 kJ/mol. The relaxation of the shear stress after the cessation of shear was more rapid than the recovery of the isotropic state.     

A collection operator for graph transformation

Algebraic graph transformation has a wellestablished theory and associated tools that can be used to perform model transformations. However, the lack of a construct to match and transform collections of similar subgraphs makes graph transformation complex or even impractical to use in a number of transformation cases. This is addressed in this paper, by defining a collection operator which is powerful, yet simple to model and understand. A rule can contain multiple collection operators, each with lower and upper bound cardinalities, and the collection operators can be nested. An associated matching process dynamically builds a collection free rule that enables us to reuse the existing graph transformation apparatus. We present model transformation examples from different modeling domains to illustrate the benefit of the approach.