Appropriate energy efficient building envelope technologies for social housing in the Irish climate

Extensive dynamic thermal simulation parametric analyses have been undertaken of energy efficient fabric alterations to social housing in Northern Ireland culminating in priorities for deployment. Five ȁ8basecaseȁ9 simulation models were used to represent the predominant characteristics of the existing social housing stock. The majority of technologies studied provided annual space-heating energy savings of more than 10%. The variation of energy savings and economic performance across the basecases highlights the value of a dwelling specific approach to selecting energy efficient building envelope technology solutions for energy rehabilitation programmes. The paper further outlines a framework for prioritising appropriate energy efficient building envelope technological solutions for a large regional building stock, i.e. existing social housing stock in Northern Ireland, highlighting influential parameters. An energy efficient building envelope inter-technology ranking approach provides a method of comparison across the various different dwellings in the regional housing stock. Airtightness ranked consistently highest across the dwellings studied with some solar technologies performing better than more technologically mature solutions such as insulation.     

Testing the credit view with pooled data: dynamic links among state bank health, investment-oriented bank loans, and economic performance

This paper focuses on the “credit view” theory at the state level, which suggests that state-level banking sector health influences state-level real economic performance. Specifically, we extend typical analysis of the credit view theory, applying relevant state-level economic variables to consider whether the health of a state’s banking system affects capital investment loans and, in turn, whether growth of these loans affects a state’s economic performance. We develop a two-equation state-level model, use more refined measures of capital investment loans, and apply advanced dynamic pooled estimators to our panel of state data for the 1984–1993 period. Regression results support dynamic links among state bank health, state investment-oriented bank loans, and state economic performance, thus supporting existence of a state-level credit channel effect.

Surface Temperatures Generated by Friction with Ceramic Materials

For tribological applications of ceramics, surface temperatures and thermal effects produced in frictional processes are important not only in influencing possible mechanisms of friction, wear, and lubricant film failure but also in initiating protective film formation, e.g., as in tribopolymerization. As part of a continuing combined experimental and theoretical study of surface temperatures generated by friction, the fundamental Greens function approach has been applied to a number of ceramics including those used in tribological applications such as bearings and advanced low heat-rejection ceramic engines. The ceramics examined consisted of (a) alumina, Al₂O₃, (b) single crystal sapphire, Al₂O₃, (c) partially stabilized zirconia, ZrO₂, (d) tungsten carbide, WC, (e) silicon carbide, SiC, and (f) silicon nitride, Si₃N₄. In addition, three forms each of silicon carbide and silicon nitride were included in this study, i.e., sintered, hot-pressed, and reaction-bonded.

Assuming a single area of real contact, calculated ratios of average surface temperature rise to coefficient of friction plotted against area of contact, velocity, and load on a logarithmic scale are presented for all the above ceramics for A-on-A (self-mating) contact as well as an example of a ceramic in sliding contact against steel. The results show that as expected, very high surface temperatures can be generated by some ceramics, particularly those having very low thermal conductivity (e.g., zirconia), high hardness, or a combination of both. However, not all ceramic combinations produce high temperatures. It is suggested that the information developed may be useful in understanding the wear behavior of ceramics as well as in designing novel anti-wear approaches for ceramic lubrication.     

Continuous precipitation of ceria nanoparticles from a continuous flow micromixer

Cerium oxide nanoparticles were continuously precipitated from a solution of cerium(III) nitrate and ammonium hydroxide using a static microchannel T-mixer. T-mixer synthesis results were compared with synthesis results from batch precipitation. Findings show that the method of mixing is important in the ceria precipitation process. Uniform porous film structures and nanorods were produced when the particle chemistry was synthesized using T-mixing followed by spin coating. Batch mixing, when using higher NH₄OH feed concentrations followed by spin coating, was characterized by the heavy agglomeration of nanoparticles. Similar, high aspect ratio nanorods were produced when feed conditions in both batch mixing and T-mixing were identical demonstrating that the momentum effects of continuous microchannel T-mixing did not impact the synthesis process. In addition, it was found that the micromixing approach reduced the exposure of the Ce(OH)₃ precipitates to oxygen, yielding hydroxide precipitates in place of CeO₂ precipitates. The key advantage of the micro-scale T-mixing approach is higher throughput which is important for the scaling of ceria nanoparticle production.     

The influence of latex blend composition on crosslinking and mechanical properties

Model reactive latices were synthesized by semicontinuous emulsion copolymerization of n‐butyl methacrylate and acetoacetoxyethyl methacrylate or dimethylaminoethyl methacrylate. The two functional latices were then blended in various ratios to study the influence of blend composition on crosslinking and mechanical properties of the resulting films. Crosslinking was quantified through swelling measurements. It was found that the crosslink density increased with increasing amounts of acetoacetoxy‐functional polymer. In addition, the crosslink density exhibited two maxima, at 30/70 and 70/30 (acetoacetoxy‐functional latex/amino‐functional latex) blend compositions. The mechanical properties of the films were quantified by dynamic mechanical analysis (DMA). It was shown that optimal mechanical properties occurred when the particles packed most efficiently at the 30/70 and 70/30 blend compositions. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 3774–3779, 2007     

Experimental Simulation of the Reactor Section of Fluid Cokers: Comparison of FCC and Fluid Coke Particles

The hydrodynamics of fluid cokers were studied in a pressurized fully cylindrical cold model of diameter 483 mm, geometrically and dynamically scaled down by a factor of ～20 from commercial units. Differential pressure fluctuations, voidage distributions, solids momentum flux distributions and steady state gas mixing behaviour in the reactor section are compared for the same operating conditions with two kinds of particles, FCC and fluid coke. The voidage distributions and core‐annular flow structures in the reactor section were similar enough that either FCC or fluid coke particles can be used for cold modelling of fluid cokers.     

Effects of foaming and antifoaming agents on the performance of a wet flue gas desulfurization pilot plant

Foaming is a common phenomenon in industrial processes, including wet flue gas desulfurization (FGD) plants. A systemic investigation of the influence of two foaming agents, sodium dodecyl sulphate (SDS) and egg white albumin (protein), and two commercial antifoams on a wet FGD pilot plant operation has been carried out. Foaming caused by 0.03 g SDS/(L slurry) reduced the desulfurization degree from 84 to 74% and the solids and limestone concentrations of the slurry from 58 to 48 g/(L slurry) and from 1.4 to 1.0 g/(L slurry), respectively. These effects were attributed to the foaming transferring small particles to the foam layer present on top of the slurry in the holding tank. The addition of 0.03 g antifoams/(L slurry) to SDS foam eliminated the foam, but the desulfurization degree remained low. Potential mechanisms for the observed behavior are analyzed. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2382–2388, 2014     

PMMA composites of single‐walled carbon nanotubes‐graft‐PMMA

To facilitate the dispersion of single‐walled carbon nanotubes (SWCNT) into poly(methyl methacrylate) (PMMA), SWCNT were functionalized with a RAFT chain transfer agent, and PMMA was grafted from the SWCNT by reversible addition–fragmentation transfer (RAFT) polymerization to give SWCNT‐g‐PMMA containing 6 wt % PMMA. SWCNT‐g‐PMMA in the form of small bundles was dispersed into PMMA matrices. The SWCNT‐g‐PMMA filler increased the glass transition temperature (T_g) of the composite when the matrix molecular weight M_n was less than the graft molecular weight, but not when the matrix M_n was equal to or greater than the graft M_n. The threshold of electrical conductivity of the composites as a function of weight percent SWCNT increased from 0.2% when matrix M_n was less than graft M_n to about 1% when matrix M_n was greater than graft M_n. Dynamic mechanical analyses of the composites having graft M_n less than or equal to matrix M_n showed broader rubbery plateaus with increased SWCNT content but no significant differences between samples with different grafted PMMAs. The results indicate that lower M_n matrix wets the SWCNT‐g‐PMMA whereas higher M_n matrix does not wet the SWCNT‐g‐PMMA. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39884.     

Identification of optically clear regions of ternary polymer blends using a novel rapid screening method

The application of a rapid screening method for the construction of ternary phase diagrams is described for the first time, providing detailed visualization of phase boundaries in solvent‐mediated blends. Our new approach rapidly identifies ternary blend compositions that afford optically clear materials, useful for applications where transparent films are necessary. The use of 96‐well plates and a scanning plate reader has enabled rapid optical characterization to be carried out by transmission spectrophotometry (450 nm), whilst the nature and extent of crystallinity was examined subsequently by wide angle X‐ray scattering (WAXS). The moderating effect of cellulose acetate butyrate can be visualized as driving the position of the phase boundaries in poly(l ‐lactic acid)/polycaprolactone (PLLA/PCL) blends. More surprisingly, the boundaries are critically dependent on the molecular weight of the crystallizable PLLA and PCL, with higher molecular weight polymers leading to blends with reduced phase separation. On the other hand, the propensity to crystallize was more evident in shorter chains. WAXS provides a convenient way of characterizing the contribution of the individual blend components to the crystalline regions across the range of blend compositions.© 2013 Society of Chemical Industry     

Achieving precision and reproducibility for writing patterns of n-alkanethiol self-assembled monolayers with automated nanografting

Nanografting is a high-precision approach for scanning probe lithography, which provides unique advantages and capabilities for rapidly writing arrays of nanopatterns of thiol self-assembled monolayers (SAMs). Nanografting is accomplished by force- induced displacement of molecules of a matrix SAM, followed immediately by the self-assembly of n-alkanethiol ink molecules from solution. The feedback loop used to control the atomic force microscope tip position and displacement enables exquisite control of forces applied to the surface, ranging from pico to nanonewtons. To achieve high-resolution writing at the nanoscale, the writing speed, direction, and applied force need to be optimized. There are strategies for programing the tip translation, which will improve the uniformity, alignment, and geometries of nanopatterns written using open-loop feedback control. This article addresses the mechanics of automated nanografting and demonstrates results for various writing strategies when nanografting patterns of n-alkanethiol SAMs.