The Water-Soluble Peripheral Substituted Phthalocyanines as Corrosion Inhibitors for Copper in 0.1 N HCl: Gravimetric,Electrochemical, SEM-EDS,and Quantum Chemical Calculations

Protection of Metals and Physical Chemistry of Surfaces - Corrosion inhibition effects of water-soluble peripheral substituted cobalt, copper and zinc metallophthalocyanines (CoPc (1), CuPc (2) and...     

Continuous models in nonlinear thermomechanics of binary systems

We study some general problems connected with the construction of thermodynamic models in the mechanics of two-component elastic bodies. Principal relations of the model are established on the basis of fundamental concepts and approaches of nonlinear continuum mechanics and nonequilibrium thermodynamics. We also demonstrate that systems of this sort can be described without using chemical potentials in the explicit form.Center of Mathematical Simulation. Pidstryhach Institute for Applied Problems in Mathematics and Mechanics, Ukrainian Academy of Sciences, L'viv. Translated from Fiziko-Khimicheskaya Mekhanika Materialov, Vol. 31, No. 4, pp. 7–15, July – August, 1995.     

Generalized squirming motion of a sphere

A number of swimming microorganisms, such as ciliates (Opalina) and multicellular colonies of flagellates (Volvox), are approximately spherical in shape and swim using beating arrays of cilia or short flagella covering their surfaces. Their physical actuation on the fluid may be mathematically modeled as the generation of surface velocities on a continuous spherical surface—a model known in the literature as squirming, which has been used to address various aspects of the biological physics of locomotion. Previous analyses of squirming assumed axisymmetric fluid motion and hence required all swimming kinematics to take place along a line. In this paper we generalize squirming to three spatial dimensions. We derive analytically the flow field surrounding a spherical squirmer with arbitrary surface motion and use it to derive its three-dimensional translational and rotational swimming kinematics. We then use our results to physically interpret the flow field induced by the swimmer in terms of fundamental flow singularities up to terms decaying spatially as \({\sim } 1/r^3\) . Our results will make it possible to develop new models in biological physics, in particular in the area of hydrodynamic interactions and collective locomotion.     

On the lateral instability of a thin beam under periodic bending loads

The lateral instability of a thin beam under periodic bending loads was investigated. Physical evidences of the instability were observed previously by experiments. But an analytical study has not been reported. The object of this study is to demonstrate the nature and existence of dynamic lateral instability. The harmonic balance method is applied to bifurcation modes which result from the stability change of torsional mode of a beam and then compared with numerical simulations. It is found, in a certain frequency range, that a small bending load results in the lateral instability when damping is small. Inha University     

Evaluation of electromagnetic loads on various design options of the ITER diagnostic upper port plug during plasma disruptions

Electromagnetic (EM) loads due to eddy current and halo current during plasma disruptions are evaluated for the ITER diagnostic upper port plug. To reduce strong EM loads acting on the port plug fixed to the vacuum vessel like a cantilever beam, three design options have been considered: removal of the diagnostic first wall, slitting of the diagnostic shield module and recess of the port plug. The main focus of the present study is to examine the efficacy of these options in terms of EM loads on the upper port plug. It is found that making slits is more effective than removing the first wall. It is also shown that the upper port plug needs to be recessed to reduce the EM load induced by halo current.     

Human discrimination of the rate of motion in the frontal approach of a sound source]

The folic acid antagonists, methotrexate and aminopterin, are known to be teratogenic in humans. The critical period for their teratogenecity is suspected to be between 6 to 8 weeks post-conception. Fetal exposure from 10 to 32 weeks weeks post-conception to methotrexate alone or in combination with other anti-cancer drugs has not resulted in obvious teratogenic effects. Methotrexate is often used to treat cancers but is occasionally used as an abortifacient. The long-term outcome of the fetal aminopterin syndrome has been published in only four adults. We report on a 28-year-old man with fetal methotrexate syndrome and two children with mild manifestations of the syndrome. One child was inadvertently exposed to methotrexate from 7 1/2 through 30 weeks post-conception because his mother was receiving it for treatment of breast cancer. The other was exposed from 11 weeks and 5 days through 25 weeks in an attempt to induce abortion. The 28-year-old man has craniofacial and digital anomalies, growth retardation but normal intelligence as noted in the previously reported cases. These cases remind us of the teratogenicity of methotrexate and should serve as a warning that if methotrexate is used as an abortifaciant and an abortion does not ensue, there is a teratogenic risk.     

Thermodynamical,economical and environmental evaluation of high efficiency gas turbine cogeneration systems

The paper evaluates the thermodynamical, economical and environmental characteristics of a cogeneration system composed of a gas turbine and a waste heat boiler (system A). Two other systems for increasing power generating efficiency are also evaluated, namely systems B and C, which are constructed by incorporating a regenerative cycle and a dual fluid cycle, respectively, into system A. It has been estimated that system C satisfies an environmental constraint that the nitrogen oxide density exhausted should be less than 100 parts in 10⁶, and that systems A and B also satisfy this constraint if a small amount of steam is injected into the combustor. The power generating efficiencies of systems A and B, in this case, and that of system C have been estimated to be 33.5%, 38.5% and 41.2%, respectively; i.e. the efficiencies of systems B and C can be improved noticeably compared with that of system A. The economics of these systems have also been evaluated based on the value of a profit index, and the systems are all estimated to be economically viable under the conditions assumed. As a result, it has been shown that it is possible to construct cogeneration systems with satisfactory characteristics of both environmental protection and profitability if system A is used in districts where the heat demand is large, system C in districts where the heat demand is small, and system B in districts with intermediate heat demand.