全文获取类型
收费全文 | 2375篇 |
免费 | 185篇 |
专业分类
电工技术 | 12篇 |
化学工业 | 840篇 |
金属工艺 | 12篇 |
机械仪表 | 27篇 |
建筑科学 | 87篇 |
矿业工程 | 3篇 |
能源动力 | 43篇 |
轻工业 | 886篇 |
水利工程 | 13篇 |
石油天然气 | 24篇 |
无线电 | 88篇 |
一般工业技术 | 269篇 |
冶金工业 | 92篇 |
原子能技术 | 1篇 |
自动化技术 | 163篇 |
出版年
2024年 | 6篇 |
2023年 | 17篇 |
2022年 | 92篇 |
2021年 | 134篇 |
2020年 | 56篇 |
2019年 | 59篇 |
2018年 | 74篇 |
2017年 | 71篇 |
2016年 | 87篇 |
2015年 | 81篇 |
2014年 | 98篇 |
2013年 | 181篇 |
2012年 | 161篇 |
2011年 | 200篇 |
2010年 | 122篇 |
2009年 | 146篇 |
2008年 | 133篇 |
2007年 | 127篇 |
2006年 | 97篇 |
2005年 | 78篇 |
2004年 | 71篇 |
2003年 | 47篇 |
2002年 | 53篇 |
2001年 | 33篇 |
2000年 | 31篇 |
1999年 | 34篇 |
1998年 | 37篇 |
1997年 | 37篇 |
1996年 | 28篇 |
1995年 | 22篇 |
1994年 | 14篇 |
1993年 | 20篇 |
1992年 | 21篇 |
1991年 | 10篇 |
1990年 | 13篇 |
1989年 | 16篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1957年 | 1篇 |
排序方式: 共有2560条查询结果,搜索用时 566 毫秒
71.
Carmen Martinez-Cruz Ignacio J. Blanco M. Amparo Vila 《Artificial Intelligence Review》2012,38(4):271-290
Two main data models are currently used for representing knowledge and information in computer systems. Database models, especially relational databases, have been the leader in last few decades, enabling information to be efficiently stored and queried. On the other hand, ontologies have appeared as an alternative to databases in applications that require a more ‘enriched’ meaning. However, there is controversy regarding the best information modeling technique, as both models present similar characteristics. In this paper, we present a review of how ontologies and databases are related, of what their main differences are and of the mechanisms used to communicate with each other. 相似文献
72.
73.
Maria Cazacu Carmen Racles Mihaela Alexandru Aurelia Ioanid Angelica Vlad 《Polymer International》2009,58(6):697-702
BACKGROUND: It is well known that, due to their extremely low polarity, polysiloxanes are incompatible with almost any organic system. This incompatibility leads to phase separation in mixed siloxane–organic systems. RESULTS: Three siloxane–organic copolymers, poly[(5,5′‐methylene‐bis‐salicylaldehyde)‐imine‐(1,3‐bis(propylene)tetramethyldisiloxane)] (Paz1), poly[(2,5‐dihydroxy‐1,4‐benzoquinone)‐imine‐(1,3‐bis(propylene)tetramethyldisiloxane)] (Paz2) and poly[1,3‐bis(propylene)tetramethyldisiloxane diamide] (Pam), were prepared by the reaction of 1,3‐bis(3‐aminopropyl)tetramethyldisiloxane with appropriate organic partners (5,5′‐methylene‐bis‐salicylaldehyde, 2,5‐dihydroxy‐1,4‐benzoquinone and oxalyl chloride, respectively). The morphologies dictated by the incompatibility between siloxane and polar organic moieties were investigated using differential scanning calorimetry and scanning electron microscopy. The surface activity of the copolymers and water vapour sorption capacity were also measured. CONCLUSION: Even though the polar sequences are very short ones, the highly flexible siloxane‐containing sequence permits the self‐assembly of these into more or less polar domains. Such an organization influences the properties of the resulting materials, an important place being occupied by the surface properties. Copyright © 2009 Society of Chemical Industry 相似文献
74.
Jorge L. Chávez-Servín Ana I. Castellote Manel Martín Ricard Chifré M. Carmen López-Sabater 《Food chemistry》2009
The medical community recommends that infant formulae should mimic human milk as far as possible, particularly in regards to long-chain polyunsaturated fatty acids (LC-PUFA). These include arachidonic acid (AA) and docosahexaenoic acid (DHA), both of which provide biochemical and functional benefits to neonates. However, LC-PUFAs are highly susceptible to oxidation and the composition of formulae must be carefully controlled. In this study, the stability of two types of LC-PUFA-supplemented milk-based powdered infant formula was evaluated over the course of 18 months storage at 25 °C and 40 °C. One contained egg yolk phospholipids (IF-EPL) and the other contained triacylglycerides (DHA and AA) synthesized by single cell oils (IF-SCO). The following parameters were monitored: peroxide values, volatile content (propanal, pentanal and hexanal), fatty acid profiles, and potential and free furfural content (5-hydroxymethyl-2-furaldehyde and 2-furaldehyde). In addition, these formulae were subjected to sensory evaluations by a panel of experts. The parameters studied revealed acceptable lipid stability in both types of formula, with better results for IF-EPL. At the end of the study period, significant deficits (p < 0.05) in linoleic acid were noted in both formulae. However, no significant decreases were observed in the other fatty acids, including AA and DHA. In regards to furfural content, both formulae exhibited a similar increase, indicative of the typical Maillard reaction characteristic of products stored for long periods. 相似文献
75.
Climate change benefits and energy supply benefits as determinants of acceptance of nuclear power stations: Investigating an explanatory model 总被引:1,自引:0,他引:1
Several countries are currently discussing whether they will rebuild their nuclear power stations in order to continue this type of energy production in the future. The public, with its own opinion about nuclear power stations, has an influential voice in this discussion. As a result, policy makers and nuclear scientists are interested in the public's perception of nuclear power and in what determines this perception. We therefore examined an explanatory model of the public's acceptance of nuclear power based on a telephone survey among a representative sample in Switzerland. The model included such factors as risk perception, benefit perception, affective feelings, and social trust. Moreover, we distinguished between two types of benefit perception: benefit for the climate and a secure energy supply. The model fitted very well to our data and explained acceptance very well. Acceptance was mainly influenced by perceived benefits for a secure energy supply and, to a lesser extent, both by perceived benefits for the climate and by risk perception. Affective feelings about nuclear power appeared to be a central factor in the model. Implications for communication about nuclear power stations and for further research are discussed. 相似文献
76.
Metallopolymers based on a polyazomethine ligand containing rigid oxadiazole and flexible tetramethyldisiloxane units
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Mirela‐Fernanda Zaltariov Maria Cazacu Carmen Racles Valentina Musteata Angelica Vlad Anton Airinei 《应用聚合物科学杂志》2015,132(11)
Soluble, easily processable polymer–metal complexes with improved optical and dielectric properties for optoelectronic functional materials were obtained. For this, a new polyazomethine (PAZ2) was prepared by the reaction of a siloxane dialdehyde and bis(formyl‐p‐phenoxymethyl) tetramethyldisiloxane with 2,5‐bis(p‐aminophenyl)‐1,3,4‐oxadiazole, and it was used as a ligand for Cu(II), Co(II), and Zn(II) ions on the basis of the presence of the electron‐donor nitrogen atoms from the azomethine group and oxadiazole ring. The structure of the PAZ2 was determined by spectral [Fourier transform infrared (FTIR) and 1H‐NMR spectroscopy] techniques. The metal complexation was proven by FTIR spectroscopy, and the silicon‐to‐metal ratios in the complexes were established by energy‐dispersive X‐ray fluorescence. The new materials were characterized by gel permeation chromatography, thermogravimetric analysis, and differential scanning calorimetry. The optical properties of PAZ2 and the derived metal complexes were studied by ultraviolet–visible and fluorescence spectroscopies. PAZ2 shows fluorescence emission, and it was significantly enhanced by metal complexation. The emission was enhanced by protonation; this behavior is useful, especially for sensors. The electrical properties were investigated by dielectric spectroscopy at various frequencies and temperatures, and this emphasized the existence of dipolar relaxations. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41631. 相似文献
77.
Condensed tannins derived from Pinus radiata bark have been esterified and added to biodegradable plastics as extrusion compounded functional plastic additives. The presence of longer alkyl chain hexanoate esters promoted tannin miscibility in the commercial polyesters Bionolle? and Biopol? whereas short chain acetate esters tended to remain as discrete domains, acting as fillers in the processed plastics. In the aliphatic polyester Bionolle the presence of tannin esters at typical plastic additive loadings did not alter plastic mechanical properties whereas at 5% content in Biopol the tannin‐additives reduced both flexural and tensile properties. Similarly tannin esters do not alter the melt or glass transition temperatures of the polyesters, but tannin hexanoate at 5% can influence the crystallization temperatures. Artificially aging plastics realized the functionality these plant extracts can impart to plastics in acting to reduce ultraviolet (UV)‐induced plastic degradation. Results indicate the tannin‐additives likely provide a stabilising role through inhibiting UV penetration into the plastic, with color analysis suggesting the tannin moiety itself was sacrificial and preferentially degrading. The imparted UV stability was linked to the dissolution of tannin esters in the plastic with longer chain esters providing greater protection against UV degradation. Tannin esters showed potential as functional additives for biodegradable polymers enhancing the UV stability of the plastic. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41626. 相似文献
78.
79.
Carmen Carney Clifford Leslie Eric Jones 《International Journal of Applied Ceramic Technology》2016,13(2):295-301
Ceramic matrix composites with SylramicTM and CG NicalonTM SiC fibers and SiC‐HfB2 matrices derived from a combination of polymer‐derived SiC ceramic and HfB2 particulate slurries were prepared. The composites were tested for oxidation resistance by laser heating at 2 MW/m2 to achieve temperatures near 1600°C. The oxidation resistance was compared between uncoated CG NicalonTM and BN‐coated SylramicTM fiber‐based composites. Oxidation resulted in precipitated nano‐sized HfO2 independent of the fibers and fiber coatings. 相似文献
80.
Sigal Meirovitch Zvi Shtein Tal Ben-Shalom Shaul Lapidot Carmen Tamburu Xiao Hu Jonathan A. Kluge Uri Raviv David L. Kaplan Oded Shoseyov 《International journal of molecular sciences》2016,17(9)
The fabrication of cellulose-spider silk bio-nanocomposites comprised of cellulose nanocrystals (CNCs) and recombinant spider silk protein fused to a cellulose binding domain (CBD) is described. Silk-CBD successfully binds cellulose, and unlike recombinant silk alone, silk-CBD self-assembles into microfibrils even in the absence of CNCs. Silk-CBD-CNC composite sponges and films show changes in internal structure and CNC alignment related to the addition of silk-CBD. The silk-CBD sponges exhibit improved thermal and structural characteristics in comparison to control recombinant spider silk sponges. The glass transition temperature (Tg) of the silk-CBD sponge was higher than the control silk sponge and similar to native dragline spider silk fibers. Gel filtration analysis, dynamic light scattering (DLS), small angle X-ray scattering (SAXS) and cryo-transmission electron microscopy (TEM) indicated that silk-CBD, but not the recombinant silk control, formed a nematic liquid crystalline phase similar to that observed in native spider silk during the silk spinning process. Silk-CBD microfibrils spontaneously formed in solution upon ultrasonication. We suggest a model for silk-CBD assembly that implicates CBD in the central role of driving the dimerization of spider silk monomers, a process essential to the molecular assembly of spider-silk nanofibers and silk-CNC composites. 相似文献