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101.
Native cassava starch was modified by dry heating treatment, and sodic montmorillonite was modified using an alkylpolyglucoside biosurfactant to produce a novel montmorillonite-filled starch bionanocomposites with improved performance. The bionanocomposites were produced in two extrusion steps using a co-rotating twin-screw extruder. The structural properties of the bionanocomposites were studied by X-ray diffraction. The reinforcement effect and material performance were evaluated by hydrophobicity, solubility, opacity, barrier, thermal and mechanical properties. In general, the dispersion of the nanofillers resulted in bionanocomposites with intercalated structures and improved properties compared with unfilled bioplastics. The main results exhibited that modified montmorillonite showed better compatibility with starch, improving nanofiller dispersion and interaction than the native one. As a result, it increased the hydrophobicity and reduced solubility, water, and oxygen permeabilities in comparison with bionanocomposites based on native starch by 36%, 48%, and 68%, respectively. Also, the tensile strength and Young modulus increased from 0.60 to 2.56 MPa and from 2.99 to 15.68 MPa, respectively. In conclusion, modification of MMT by the biosurfactant is a good approach to enhance dispersion/interaction with the starch matrix. 相似文献
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Tommaso Palomba Giusy Tassone Carmine Vacca Matteo Bartalucci Aurora Valeri Cecilia Pozzi Simon Cross Lydia Siragusa Jenny Desantis 《International journal of molecular sciences》2022,23(22)
The field of targeted protein degradation, through the control of the ubiquitin–proteasome system (UPS), is progressing considerably; to exploit this new therapeutic modality, the proteolysis targeting chimera (PROTAC) technology was born. The opportunity to use PROTACs engaging of new E3 ligases that can hijack and control the UPS system could greatly extend the applicability of degrading molecules. To this end, here we show a potential application of the ELIOT (E3 LIgase pocketOme navigaTor) platform, previously published by this group, for a scaffold-repurposing strategy to identify new ligands for a novel E3 ligase, such as TRIM33. Starting from ELIOT, a case study of the cross-relationship using GRID Molecular Interaction Field (MIF) similarities between TRIM24 and TRIM33 binding sites was selected. Based on the assumption that similar pockets could bind similar ligands and considering that TRIM24 has 12 known co-crystalised ligands, we applied a scaffold-repurposing strategy for the identification of TRIM33 ligands exploiting the scaffold of TRIM24 ligands. We performed a deeper computational analysis to identify pocket similarities and differences, followed by docking and water analysis; selected ligands were synthesised and subsequently tested against TRIM33 via HTRF binding assay, and we obtained the first-ever X-ray crystallographic complexes of TRIM33α with three of the selected compounds. 相似文献
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Comparison of MCNPX-C90 and TRIPOLI-4-D for fuel depletion calculations of a Gas-cooled Fast Reactor
Ricardo Reyes-Ramírez Cecilia Martín-del-Campo Juan-Luis François Emeric Brun Eric Dumonteil Fausto Malvagi 《Annals of Nuclear Energy》2010
The Gas-cooled Fast Reactor is one of the reactor concepts selected by the Generation IV International Forum for the next generation of innovative nuclear energy systems. Several fuel design concepts are being investigated. Burnup depletion of mixed fuel of uranium and plutonium, cooled with gas in a fast neutron energy spectrum must be simulated. Various codes are being developed and/or adapted to improve the quality of the results, and also to reduce the computing time required for the simulations. 相似文献
105.
Yiling Lee Yu Zhang Serene Lay Geok Ng Fransiska Cecilia Kartawidjaja John Wang 《Journal of the American Ceramic Society》2009,92(9):1940-1945
Vertically aligned, single crystalline ZnO nanorods with a high packing density and diameter of ∼60 nm have been successfully synthesized via a low-temperature hydrothermal route on glass substrates pre-deposited with a ZnO seeding layer. The seeding layer exhibits an epitaxial effect on the growth and alignment of the ZnO nanorods. This epitaxial effect can arise from two considerations, namely the crystalline orientation and surface roughness of the seeding layer, which can be controlled by the curing temperature. The ZnO seeding layer that was cured at 350°C exhibited a preferred (0002) crystalline orientation of wurtzite hexagonal structure and a low surface roughness. It was demonstrated to promote the vertical growth of ZnO nanorods. The ZnO nanorods grew in an almost linear relationship with hydrothermal time up to 8 h, but thereafter started to dissolve as the reaction time extended beyond 8 h, due to competition from the homogeneous nucleation of ZnO microparticles in the solution. 相似文献
106.
An investigation was made on whether the optimal number of tubes in a dry-expansion evaporator, for a given area or a given cost, will change when R22 is replaced with the non-azeotropic mixture R407C. A comprehensive computer program was used to simulate the tube-and-shell evaporator, under several sets of conditions. The simulations show that there are only small differences between R22 and R407C in the optimal number of tubes. However, the results indicate that one can allow a somewhat higher pressure drop for R407C, and that the number of tubes for a given area therefore can be smaller when R407C is used. For both fluids, the evaporator performance is more sensitive to the optimization for a given cost than for a given area. 相似文献
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In 1974 a new approach to breast cancer screening was introduced--the single view mammography method. An urban nonselected population of 6845 women of more than 34 years of age were screened with one roentgenogram of each breast. By this method it has been possible to reduce the radiation dose, while the patient flow is increased and the costs are decreased to an acceptable level. Forty cases of breast carcinoma were detected (6.7/1000). Twenty cases were preclinical. 相似文献