MC(Mid-Century)催化氧化过程的研究进展

介绍了MC催化氧化过程规律；从催化荆体系的改进、新型溶剂体系的开发、反应器构型和配套设施的改进、富氧氧化技术的开发等方面综述了近年来MC技术的发展；探讨了MC液相催化氧化技术应用范围的拓展以及MC液相催化氧化过程的发展方向。     

Transitions from solid to liquid in isotactic polystyrene studied by thermal analysis and X-ray scattering

A three-phase model, comprising mobile amorphous fraction (MAF), rigid amorphous fraction (RAF) and crystalline fraction (C), has been applied to interpret the thermal transitions and structure of cold-crystallized isotactic polystyrene (iPS) from below the glass transition temperature, T_g, to above the melting point. Quenched amorphous iPS films were isothermally crystallized at different temperatures for 12 h. The fraction of crystalline phase, ?_c, was measured by differential scanning calorimetry (DSC), wide angle X-ray scattering and Fourier Transform infrared spectroscopy. The fraction of the mobile amorphous phase, ?_MAF, was obtained from the heat capacity increment at the glass transition temperature. In the three-phase model, the fraction of the rigid amorphous phase, ?_RAF, was found from 1−?_MAF−?_c. Specific heat capacity measurements by standard DSC confirm that the experimental baseline heat capacity conforms to a three-phase model for temperatures ranging from below T_g, up to the relaxation of RAF. The relaxation of RAF appears as a sigmoidal change in heat capacity accompanied by excess enthalpy, in which solid-like RAF is converted to an identical amount of liquid-like MAF.At temperatures above the relaxation of RAF, either one or two major crystal melting endotherms are observed in standard DSC, dependent upon crystallization temperature. However, using quasi-isothermal temperature modulated DSC, we always observed two reversing melting endotherms. The effects of annealing on iPS structure during the quasi-isothermal measurement were assessed using small angle X-ray scattering (SAXS). Combining the DSC and SAXS results, a model for the melting of iPS lamellae at low heating rates is presented.     

Crystallization behavior,mechanical properties,and environmental biodegradability of poly(β‐hydroxybutyrate)/cellulose acetate butyrate blends

The miscibility, crystallization behavior, tensile properties, and environmental biodegradability of poly(β‐hydroxybutyrate) (PHB)/cellulose acetate butyrate (CAB) blends were studied with differential scanning calorimetry, scanning electron microscopy, wide‐angle X‐ray diffraction, and polarizing optical microscopy. The results indicated that PHB and CAB were miscible in the melt state. With an increase in the CAB content, the degree of crystallinity and melting temperature of the PHB phase decreased, and this broadened the narrow processability window of PHB. As the elongation at break increased from 2.2 to 7.3%, the toughness and ductility of PHB improved. From the degradation test, it could be concluded that degradation occurred gradually from the surface to the inside and that the degradation rate could be adjusted by the addition of the CAB content. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2116–2122, 2003     

Augmented Online Sequential Quaternion Extreme Learning Machine

Neural Processing Letters - Online sequential extreme learning machine (OS-ELM) is one of the most popular real-time learning strategy for feedforward neural networks with single hidden layer due...     

Reaction mechanism and microstructure evolution of reaction sintered <Emphasis Type="Italic">h</Emphasis>-BN

Hexagonal boron nitride ceramic (h-BN) based on the nitridation of B powders was obtained by reaction sintering method. The effects of sintering temperature on the mechanical properties and microstructure of the resultant products were investigated and the reaction mechanism was discussed. Results showed that the reaction between B and N₂ occurred vigorously at temperatures ranging from 1 000 °C to 1 300 °C, which resulted in the generation of t-BN. When the temperature exceeded 1 450 °C, transformation from t-BN to h-BN began to occur. As the sintering temperature increased, the spherical particles of t-BN gradually transformed into fine sheet particles of h-BN. These particles subsequently displayed a compact arrangement to achieve a more uniform microstructure, thereby increasing the strength.     

自卸车驾驶室振动对标测试与分析

针对某厂商研制的无副梁自卸车,为验证其更换主梁后驾驶室舒适性是否有所改善,进行不同速度及路况下的驾驶室振动测试试验,并与有副梁原型自卸车进行对标,采用时域与频域数据处理方法对结果进行分析,结果显示扭曲路面下无副梁自卸车的驾驶室舒适性有所改善,但对于4Hz以下的振动,其车架的隔振效果较弱。在碎石路面与平坦路面下无副梁自卸车满载时,其车架的隔振效果要明显好于对标自卸车,但在碎石路面空载时,其隔振效果则较弱。     

基于脱钩模型的新疆碳排放与经济增长的关系研究

在共建丝绸之路经济带以及生态文明的大背景下,新疆作为丝路经济带的核心区与中国西部重要的桥头堡,其经济发展的速度与效益值得关注。尤其新疆是我国重要的能源资源储备区,如何协调好能源开发过程中的碳排放与经济增长之间的关系,是当前摆在我们眼前的一大课题。本文旨在通过脱钩模型分析新疆碳排放与经济增长之间的关系,得出新疆碳排放与经济增长总体上呈现弱脱钩的结论,据此分析弱脱钩状态产生的原因,并提出了有针对性的对策建议,以期促进新疆经济能更好的适应经济新常态。     

Simple Preparation of Crystal Co3（BTC）2·12H2O and Its Catalytic Activity in CO Oxidation Reaction

Crystalline metal-organic framework cobalt(Ⅱ) benzenetricarboxylate Co3(BTC)2?12H2O(MOF-Co) has been prepared using solvothermal method. The reaction of cobalt(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic(BTC) acid in a mixed solution of N,N-dimethylformamide(DMF)/C2H5OH/H2O(1:1:1, ν/ν) at low temperature for short reaction times produced this crystalline compound. Compared with traditional hydrothermal method, a mixed solution method for the synthesis of crystalline metal complex was found to be highly efficient. After water molecules were removed from this metal complex, its exposed nodes served as active sites. When this MOF-Co was employed in the oxidation of CO, it showed good catalytic properties causing 100% conversion of CO to CO2 at low temperature of 160 ℃.     

酒店暖通设计中的节能措施探讨

以巢湖半汤国际温泉假日酒店暖通设计为例,分别从空调系统的划分,冷热源及输配系统的选择,空调末端系统的选择,以及热回收技术等方面对酒店暖通设计中的节能策略进行了分析和探讨。