AZ31镁合金棒材拉矫残余挠度及残余应力场数值模拟

以AZ31镁合金棒材为研究对象,分别测量了AZ31镁合金棒材在不同温度下的应力应变曲线及不同温度、不同残余拉伸应变下的残余挠度.建立有限元模型,模拟了上述试样拉伸矫直后的残余挠度和残余应力场,并将模拟的不同温度、不同残余拉伸应变下的残余挠度和测量结果进行了比较,二者吻合较好,证明所建立的模型是有效的.在此基础上,分析了拉伸矫直残余应力场,随拉伸应变、拉伸温度的变化规律,研究表明在矫直温度220℃、残余拉伸应变为2%时进行拉伸矫直,夹持部位不易打滑、且在夹持端的残余应力最小及残余应力影响区最小,并可采用小拉伸量、多次拉伸的方式进一步减小其残余挠度.     

Characteristics of Ni-Ir and Pt-Ir hard coatings surface treated by pulsed Nd:YAG laser

The subjects of the presented paper are to develop a laser surface treatment technology for the protective coatings of glass-molding dies and to better understand the interaction between laser beam and materials coated on the die surface. A variety of alloy films, including Ir-25 at.% Pt, Ir-50 at.% Pt, Ir-75 at.% Pt, Ir-25 at.% Ni, Ir-50 at.% Ni, and Ir-75 at.% Ni compositions are deposited by the ion source assisted magnetron sputtering system (ISAMSS). A Cr layer that functioned as a buffer layer is deposited between the alloy film and die surface. After an alloy film and the buffer Cr layer were sequentially coated on tungsten carbide (WC) surface, Nd:YAG laser was directly applied in the writing process. The temperature profile of the film stack structure is simulated by ANSYS software. The surface roughness was analyzed by atomic force microscopy (AFM) to compare the coating surface roughness before and after the laser surface treatments. The treated coatings for oxidation prevention test were examined by energy dispersive x-ray spectrometry (EDS). Nanoindentation instrument was performed to evaluate microhardness and reduced modulus of the coatings. The cross-sectional structures between the hard coating layer and buffer layer were also inspected by a scanning electron microscope (SEM). The Pt-Ir and Ni-Ir film coatings are unable to withstand the working temperature over 1500 °C, which is considered for quartz molding process and hot embossing process. The films showed high roughness, low microhardness and low reduced modulus because the film oxidation occurred in a high working temperature process.     

The effect of molybdenum on the corrosion behaviour of the high-entropy alloys Co1.5CrFeNi1.5Ti0.5Mox in aqueous environments

The purpose of this study is to investigate the electrochemical properties of the Co_1.5CrFeNi_1.5Ti_0.5Mo_x high-entropy alloys in three aqueous environments which simulate acidic, marine, and basic environments at ambient temperature (∼25 °C). The potentiodynamic polarisation curves of the Co_1.5CrFeNi_1.5Ti_0.5Mo_x alloys, obtained in aqueous solutions of H₂SO₄ and NaOH, clearly revealed that the corrosion resistance of the Mo-free alloy was superior to that of the Mo-containing alloys. On the other hand, the lack of hysteresis in cyclic polarisation tests and SEM micrographs confirmed that the Mo-containing alloys are not susceptible to pitting corrosion in NaCl solution.     

Structural and electrical properties of La2−xBaxMo2O9−x/2 (x = 0-0.18)

La_2−xBa_xMo₂O_9−x/2 (x ≤ 0.18) have been prepared by solid state reaction method. The lattice parameter of La_2−xBa_xMo₂O_9−x/2 (x ≤ 0.18) determined by XRD data refinement shows a linear dependence on the dopant Ba content x. For the specimen with a La/Ba molar ratio of 0.18-0.2, additional reflection of secondary phase exists in the XRD pattern, so the value of solubility limit for Ba in La₂Mo₂O₉ is defined in range of 0.18 < x < 0.2. As the replacement degree of La³⁺ by Ba²⁺ increases, the bulk conductivity of La_2−xBa_xMo₂O_9−x/2 (x ≤ 0.18) decreases initially and then increases, a minimum value at La_1.9Ba_0.1Mo₂O_8.95 exists. Hebb-Wagner studies in argon atmosphere, which use an oxide-ion blocking electrode, show that La_2−xBa_xMo₂O_9−x/2 (x ≤ 0.18) are predominantly oxide-ion conducting in the temperature ranging from 773 to 1173 K. The average thermal expansion coefficient of La_1.84Ba_0.16Mo₂O_8.92 determined by high-temperature XRD was deduced as great as 17.5 × 10⁻⁶ K⁻¹ between 298 and 1173 K.     

The Thermal Stability of R<Subscript>3</Subscript>Pt<Subscript>4</Subscript> Compounds

Alloys of the rare earths R (including La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Y, Ho, Er) with platinum, having the composition R₃Pt₄, have been synthesized and investigated by X-ray diffraction (XRD) and differential thermal analysis (DTA). At temperatures above about 900 °C and below 250 °C, all the single phases R₃Pt₄ are formed, which crystallize with the same structure of the rhombohedral Pu₃Pd₄ type. Over the temperature range of about 250 °C to 900 °C, they occur at an eutectoid decomposition into RPt and RPt₂ compounds neighboring in the corresponding phase diagram, R₃Pt₄ → RPt + RPt₂. The stability of these phases R₃Pt₄ may be restricted to a radius ratio r _R/r _Pt range of 1.27 to 1.35.     

Effect of interstitial boron and carbon on the hydrogenation properties of Ti25V35Cr40 alloy

Doping of interstitial elements B or C into a BCC-type Ti₂₅V₃₅Cr₄₀ alloy to raise effective desorption hydrogenation capacity was investigated. Ti₂₅V₃₅Cr₄₀M_x alloys (M = B or C and x = 0, 0.1, 1, or 5) were prepared by arc-melting followed by homogenization treatment. X-ray diffraction shows that the as-cast specimens have a BCC structure, but they contain some amount of precipitates that increases with the doping concentration of B and C. Doping-induced precipitates can be greatly eliminated by annealing treatment at 1200 °C, indicating that B or C might have been partially dissolved into the interstitial sites in the BCC lattice of matrix phase of specimens. With the doping of C, the second plateau pressure of annealed specimens in the PCI curves at T = 30 °C significantly increases with the amount of C, but the maximum hydrogenation capacity is reduced. On the other hand, the second plateau pressure and maximum hydrogenation capacity are only slightly affected by the B doping. Under optimum doping conditions, the effective hydrogen desorption capacities are increased from 0.80 H/M of the sample without doping to 0.86 H/M and 0.87 H/M for Ti₂₅V₃₅Cr₄₀B₁ and Ti₂₅V₃₅Cr₄₀C_0.1, respectively. The improvement might be ascribed to the increase in second plateau pressure caused by less stable hydrogen atoms at the lattice sites of Ti₂₅V₃₅Cr₄₀ containing interstitial B or C.     

Chemical Stresses Induced by Boundary Layer Diffusion in a Cylindrical Sandwich Composite

The chemical stresses developed in a cylindrical sandwich composite during radial boundary layer diffusion have been investigated. The system consists of a thin layer A of circular cross section sandwiched between two semi-infinite outer layers B, with the diffusivity of diffusant in A (D_A) being much greater than that in B (D_B). Two boundary conditions, the constant surface concentration and the instantaneous surface concentration, were considered. The concentration distributions were obtained by the Bessel-Laplace transform method. The stress functions were solved analytically based on the linear elasticity. Numerical computations were performed to illustrate the effects of the diffusivity ratio (D_A/D_B) and of the thickness of the central layer A on stress distributions. The results show that the induced stress in layer A increases as the diffusivity ratio, or its thickness, increases, in consistency with the general findings for composites of rectangular geometry.     

表层嵌贴预应力CFRP板条加固钢筋混凝土梁的应力传递行为

表层嵌贴预应力FRP板条加固钢筋混凝土结构技术可充分发挥FRP材料强度,且不需设置永久锚具,具有较大的潜力。以试验得到的嵌贴FRP混凝土粘结滑移关系为基础,建立了嵌贴预应力CFRP板条与混凝土的粘结应力微分方程,并根据边界条件推导了方程的解析解,得到了嵌贴预应力CFRP板条放张后界面粘结应力、CFRP拉伸应力的分析模型。与试验结果的比较表明,该模型得出的界面粘结应力及CFRP拉伸应力与试验结果吻合较好。在此基础上,考虑放张后CFRP混凝土界面不出现剥离的条件,分析了粘结界面能抵抗的最大容许预应力。