The pH sensing characteristics of the extended-gate field-effect transistors of multi-walled carbon-nanotube thin film using low-temperature ultrasonic spray method

A novel, simple and low-temperature ultrasonic spray method was developed to fabricate the multi-walled carbon-nanotubes (MWCNTs) based extended-gate field-effect transistors (EGFETs) as the pH sensor. With an acid-treated process, the chemically functionalized two-dimensional MWCNT network could provide plenty of functional groups which exhibit hydrophilic property and serve as hydrogen sensing sites. For the first time, the EGFET using a MWCNT structure could achieve a wide sensing rage from pH = 1 to pH = 13. Furthermore, the pH sensitivity and linearity values of the CNT pH-EGFET devices were enhanced to 51.74 mV/pH and 0.9948 from pH = 1 to pH = 13 while the sprayed deposition reached 50 times. The sensing properties of hydrogen and hydroxyl ions show significantly dependent on the sprayed deposition times, morphologies, crystalline and chemical bonding of acid-treated MWCNT. These results demonstrate that the MWCNT-EGFETs are very promising for the applications in the pH and biomedical sensors.     

DEM simulation of oblique shocks in gravity-driven granular flows with wedge obstacles

Deflecting wedge obstacles are often built to divert hazardous flows away from residential areas that are in the way of harm. When a rapid avalanche flow is deflected by an obstacle, this usually causes abrupt changes in the flow thickness and velocity and exhibits characteristics like oblique shock waves in the aerodynamic system or oblique hydraulic jumps in the open channel flows. In this study, the Discrete Element Method (DEM) is employed to simulate the motion of granular materials impinging on a wedge obstacle in an adjustable inclination chute. We use chutes with four different inclined angles combined with wedge obstacles having different angles to investigate the overall flow behavior. Both the flow velocity and the flow depth are obtained by averaging the numerical simulation data, and then the granular temperature and the shock angle are calculated. The results of the DEM simulation are compared with that of the classical oblique shock theory. We find that there is good agreement between the classical oblique granular shock theoretical calculations and the DEM simulation results. Moreover, the microdynamic variables related to flow structure such as the packing density and the coordination number are also discussed in the present study.     

Correlation between the magnetic imaging of cobalt nanoconstrictions and their magnetoresistance response

Scanning transmission x-ray microscopy (STXM) and magnetoresistance (MR) measurements are used to investigate the magnetic behavior of a nanoconstriction joining two micrometric electrodes (a pad and a wire). The reversal of the magnetization under variable external static magnetic fields is imaged. By means of a detailed analysis of the STXM images at the nanocontact area, the MR is calculated, based on diffusive anisotropic-MR. This MR agrees well with that obtained from electrical transport measurements, allowing a direct correlation between the MR signal and the magnetic reversal of the system. The magnetization behavior depends on the sample thickness and constriction dimensions. In 40 nm-thick samples, with 20 × 175 nm(2) contact areas, the magnetization at the two sides of the constriction forms a net angle of 90°, with a progressive evolution of the magnetization structure between the electrodes during switching. The MR in those cases has a more peaked shape than with 20 nm-thick electrodes and 10 × 80 nm(2) contact areas, where the magnetization forms 180° between them, with a wide domain wall pinned at the constriction. As a consequence of this configuration, a plateau in the MR is observed for about 20 Oe.     

Hybrid passivated colloidal quantum dot solids

Colloidal quantum dot (CQD) films allow large-area solution processing and bandgap tuning through the quantum size effect. However, the high ratio of surface area to volume makes CQD films prone to high trap state densities if surfaces are imperfectly passivated, promoting recombination of charge carriers that is detrimental to device performance. Recent advances have replaced the long insulating ligands that enable colloidal stability following synthesis with shorter organic linkers or halide anions, leading to improved passivation and higher packing densities. Although this substitution has been performed using solid-state ligand exchange, a solution-based approach is preferable because it enables increased control over the balance of charges on the surface of the quantum dot, which is essential for eliminating midgap trap states. Furthermore, the solution-based approach leverages recent progress in metal:chalcogen chemistry in the liquid phase. Here, we quantify the density of midgap trap states in CQD solids and show that the performance of CQD-based photovoltaics is now limited by electron-hole recombination due to these states. Next, using density functional theory and optoelectronic device modelling, we show that to improve this performance it is essential to bind a suitable ligand to each potential trap site on the surface of the quantum dot. We then develop a robust hybrid passivation scheme that involves introducing halide anions during the end stages of the synthesis process, which can passivate trap sites that are inaccessible to much larger organic ligands. An organic crosslinking strategy is then used to form the film. Finally, we use our hybrid passivated CQD solid to fabricate a solar cell with a certified efficiency of 7.0%, which is a record for a CQD photovoltaic device.     

Major bridge development in Hong Kong,China—past,present and future

The first “modern” type of vehicular bridge was built in Hong Kong China in the 1920s. The need for an efficient transportation system to cope with population growth and enable economic development has demanded the construction of more and more bridges since the middle of the 20th century. By 2007, Hong Kong had a total of about 1300 vehicular bridges. Four of these bridges, including the Tsing Ma Bridge, Kap Shui Mun Bridge, Ting Kau Bridge, and the cable-stayed bridge on the Hong Kong- Shenzhen Western Corridor, are considered to be major bridges supported by cables. Currently, the Stonecutters Bridge on Route No. 8 is under construction and is expected to be completed in late 2009. At the same time, the Hong Kong-Zhuhai-Macao Bridge will be in its detailed design stage soon. While efforts have been made by bridge builders to construct these giant structures, the upkeeping of these valuable assets at a high standard and ensuring their continuous functioning and performance during their intended lifespans will be another important task for bridge engineers. Wind and structural health monitoring system (WASHMS) will play a key role in this respect.     

Low bandgap carbazole copolymers containing an electron-withdrawing side chain for solar cell applications

A new series of low bandgap carbazole copolymers containing an electron-withdrawing moiety as a side chain, via Suzuki, Yamamoto, and Stille polymerization reactions has been synthesized. Their bandgaps and molecular energy levels can be tuned by copolymerizing with different conjugated electron-donating units. The resulting copolymers have low optical and electrochemical bandgaps. The optical bandgaps of the copolymers range from 1.79 to 1.24 eV. In order to investigate their photovoltaic properties, polymer solar cell devices based on low bandgap copolymers were fabricated with a structure of ITO/PEDOT:PSS/copolymers:PCBM/Al, under the illumination of AM 1.5 G, 100 mW/cm². The power conversion efficiencies (PCE) of the polymer solar cells based on these low bandgap copolymers were measured. The best performance was obtained by using PC-CARB as the electron donor and 6,6-phenyl C₇₁-butyric acid methyl ester (PC₇₁BM) as the electron acceptor. The PCE of the solar cell based on PC-CARB/P₇₁CBM (1:4) was 1.27% with an open-circuit voltage (V_oc) of 0.65 V, and a short-circuit current (J_sc) of 6.69 mA/cm².     

Collection and Analysis of Critical Infrastructure Interdependency Relationships

Critical infrastructure represents important national assets for producing or distributing continuous flows of essential goods or services. When one aspect of the critical infrastructure shuts down due to an external disruption, other portions of the system that need those goods or services are likely to stop shortly thereafter, thus exacerbating the damage caused by the external disruption. Literature on critical infrastructure interdependency (CII) shows a need for analyzing failure records with time information from different types of critical infrastructure. This paper presents a knowledge discovery process for CII to extract records of frequent patterns of critical infrastructure failure that are directly or indirectly triggered by external disruptions. The knowledge discovery process, including integration of critical infrastructure failure records and their transformation into the data format needed by a data mining algorithm, is described. The paper includes a discussion on a disaster mitigation approach that could be used to stop CII-related failure events, and it includes the analysis of the results of sample critical infrastructure failure records. Disaster mitigation officials can employ the proposed approach to explore CII and to design countermeasures when a disaster hits.     

Near UV LEDs made with in situ doped p-n homojunction ZnO nanowire arrays

Catalyst-free p-n homojunction ZnO nanowire (NW) arrays in which the phosphorus (P) and zinc (Zn) served as p- and n-type dopants, respectively, have been synthesized for the first time by a controlled in situ doping process for fabricating efficient ultraviolet light-emitting devices. The doping transition region defined as the width for P atoms gradually occupying Zn sites along the growth direction can be narrowed down to sub-50 nm. The cathodoluminescence emission peak at 340 nm emitted from n-type ZnO:Zn NW arrays is likely due to the Burstein-Moss effect in the high electron carrier concentration regime. Further, the electroluminescence spectra from the p-n ZnO NW arrays distinctively exhibit the short-wavelength emission at 342 nm and the blue shift from 342 to 325 nm is observed as the operating voltage further increasing. The ZnO NW p-n homojunctions comprising p-type segment with high electron concentration are promising building blocks for short-wavelength lighting device and photoelectronics.     

Damage characterization of 3D braided composites using carbon nanotube-based in situ sensing

Carbon nanotubes (CNTs) were used as an in situ sensor to detect the initiation of micro-cracks and their accumulation in fiber-reinforced polymer composites. The breakage of the electrically conductive networks formed by CNTs throughout the polymer matrix when dispersed in composites enables the micro-cracks to be sensed. This methodology was applied to three-dimensional (3D) braided composites with the aim of investigating the feasibility of detecting their matrix failure and analyzing their damage behavior. Tensile specimens were prepared using 3D braided ultra-high molecular weight polyethylene (UHMWPE) preforms and vinyl ester containing multi-walled CNTs (0.5 wt%) via vacuum-assisted resin transfer molding (VARTM). The electrical resistance of the composites was then measured during tensile testing, while their internal structures were analyzed using X-ray computer tomography (CT), demonstrating that the CNTs dispersed in the matrix enable micro-cracks to be sensed and the damage modes of the 3D braided composites to be analyzed. Finally, four critical strain levels that can classify the damage modes were identified from the change of the electrical resistance of the 3D braided composites.     

AZ31镁合金棒材拉矫残余挠度及残余应力场数值模拟

以AZ31镁合金棒材为研究对象,分别测量了AZ31镁合金棒材在不同温度下的应力应变曲线及不同温度、不同残余拉伸应变下的残余挠度.建立有限元模型,模拟了上述试样拉伸矫直后的残余挠度和残余应力场,并将模拟的不同温度、不同残余拉伸应变下的残余挠度和测量结果进行了比较,二者吻合较好,证明所建立的模型是有效的.在此基础上,分析了拉伸矫直残余应力场,随拉伸应变、拉伸温度的变化规律,研究表明在矫直温度220℃、残余拉伸应变为2%时进行拉伸矫直,夹持部位不易打滑、且在夹持端的残余应力最小及残余应力影响区最小,并可采用小拉伸量、多次拉伸的方式进一步减小其残余挠度.